Materials Literature
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We report on the nucleation and growth of tetracene in a thin liquid film which is continuously supersaturated by vapor deposition of molecules onto the film. In a first stage, nucleation and fast anisotropic two-dimensional dendritic growth occurs. In a second stage, the dendrites coarsen into pallet-shaped crystals.…
In this work, we investigated the mechanism involved in the photoinitiated cross-linking of the polyester poly(propylene fumarate) (PPF) using the initiator bis(2,4,6-trimethylbenzoyl) phenylphosphine oxide (BAPO). It was hypothesized that BAPO has the ability to cross-link PPF into solid polymer networks, without the…
This Communication reports a low-temperature diamond synthesis technique, in which diamonds (10-250 mum) can form at a temperature as low as 440 degrees C by reduction of dense CO2 with metallic Na. The X-ray diffraction pattern of a powder sample shows three reflection peaks, indexed with 111, 220, and 311, correspon…
Traditional pictures of optical properties in phenylacetylene dendrimers view the molecule as a collection of independent chromophores, linked by meta-substitution at the central phenyl ring. While this picture is reasonable for explaining the observed absorption trends, it breaks down in describing the emission behav…
We establish a strict correlation between the total photoelectron yield spectra and the surface conductivity of hydrogenated diamond. The decomposition of the yield spectra into electron and exciton derived contributions requires an upward surface band bending to accompany surface conductivity, while an essentially fl…
Fluorescent colloidal particles, fabricated by depositing a thin gold film on one side of the particle, show intensity fluctuation (blinking) under an optical microscope because of their rotational Brownian motion. Interactions between molecules immobilized on the surfaces of the particle and the solid substrate restr…
Medical ultrasound is a highly valuable diagnostic tool, especially when compared with other imaging modalities. It is a noninvasive, real-time, portable, extremely safe method compared with X-ray and inexpensive relative to magnetic resonance imaging. However, ultrasound is limited in its ability to distinguish betwe…
Collagen is the most abundant protein in animals. Natural collagen consists of a triple helix of (Xaa-Yaa-Gly)n chains, in which the Xaa and Yaa residues are often l-proline. Here, a (2S,4S)-4-fluoroproline (flp) residue is shown to be greatly stabilizing in the Xaa position (but destabilizing in the Yaa position). In…
Characteristic fluorescence properties of photochromic 1,2-bis(3-methyl-2-thienyl)perfluorocyclopentene were studied in solution as well as in the single-crystalline phase. When the concentration of 1,2-bis(3-methyl-2-thienyl)perfluorocyclopentene was increased in a 3-methylpentane solution, the fluorescence spectrum…
Polycrystalline samples of the partially filled skutterudites Nd x Co 4 Sb 12 have been prepared and characterized by x-ray powder diffraction and differential thermal analysis. The saturation limit of the Nd void filling in CoSb 3 was found to be around 13%. All samples decompose incongruently at a temperature of 114…
The electronic structure and optical properties of metallic nanoshells are investigated using a jellium model and the Time Dependent Local Density Approximation (TDLDA). An efficient numerical implementation enables applications to nanoshells of realistic size with up to a million electrons. We demonstrate how a frequ…
The ferromagnetic transition in a diluted magnetic semiconductor with localized charge carriers is inevitably a percolation transition. In this work we theoretically study the correlation between this magnetic percolation and transport properties of the sample, including the possibility of a simultaneous transport per…
We analyze solid-state phase transformations that occur in zinc-sulfide crystals during annealing using a random deformation-faulting mechanism with a very simple interaction between adjacent close-packed double layers. We show that, through annealing, infinite-range structures emerge from initially short-range crysta…
The exploitation of the spin in charge-based systems is opening revolutionary opportunities for device architecture. Surprisingly, room temperature electrical transport through magnetic nanowires is still an unresolved issue. Here, we show that ferromagnetic (Co) suspended atom chains spontaneously display an electron…
Using a set of evolution equations [J.G. Amar {\it et al}, Phys. Rev. Lett. {\bf 86}, 3092 (2001)] for the average gap-size between islands, we calculate analytically the asymptotic scaled capture-number distribution (CND) for one-dimensional irreversible submonolayer growth of point islands. The predicted asymptotic…
Long-lived photoinduced absorption and dichroism in the Ca_3Ga_{2-x}Mn_xGe_3O_{12} garnets with x < 0.06 were examined versus temperature and pumping intensity. Unusual features of the kinetics of photoinduced phenomena are indicative of the underlying electronic processes. The comparison with the case of Ca_3Mn_2Ge_3…
The Landau-Zener-Stueckelberg (LZS) effect in a model system of interacting tunneling particles is studied numerically and analytically. Each of N tunneling particles interacts with each of the others with the same coupling J. This problem maps onto that of the LZS effect for a large spin $S=N/2.$ The mean-field limit…
We propose a new direct mechanism for the pressure driven alpha-->omega martensitic transformation in pure titanium. A systematic algorithm enumerates all possible pathways whose energy barriers are evaluated. A new, homogeneous pathway emerges with a barrier at least 4 times lower than other pathways. The pathway is…
Spin dynamics in ferromagnetic $p$-(Ga,Mn)As ($x$ = 0.011, $T_{C}$ = 30 K) has been studied by carefully comparing the decay time of the photo-induced reflectivity change with the transient behavior of polar Kerr rotation induced by photo-generated carrier spins with a femtosecond light pulse of various polarizations.…
We have studied the relative adhesion (the wetting) of dislocation-free three-dimensional islands belonging to an array of islands to the wetting layer in Stranski-Krastanov growth mode. The array has been simulated as a chain of islands in 1+1 dimensions placed on top of a wetting layer. In addition to the critical s…