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Crystalline transition in Nylon 10 10

Yongjin Li、Deyue Yan、Xinyuan Zhu2000-12-01Macromolecular Rapid Communications

Variable-temperature X-ray diffraction was used to monitor the crystalline transition of Nylon 10 10. It could be found that the α-phase of the sample transforms into a γ-phase at about 135°C, if the sample is heated from room temperature to a high temperature, which is the so-called Brill transition of Nylon 10 10. I…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Prediction of air permeability of needle-punched nonwoven fabrics using artificial neural network and empirical models

Sanjoy Debnath、M. Madhusoothanan、V. R. Srinivasamoorthy2000-12-01OpenAlex

The artiticial neural network (ANN) and empirical models have been developed to predict the air permeability of needled fabrics with varying jute and polypropylene blend ratio, fabric weight and needling density. The fabrics were produced as per a statistical factorial design. The efficiency of prediction of the two m…

Textile materials and evaluations

Non-Enzymatic Transcription of an IsoG·IsoC Base Pair

John C. Chaput、Christopher Switzer2000-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTNon-Enzymatic Transcription of an IsoG·IsoC Base PairJohn C. Chaput and Christopher SwitzerView Author Information Department of Chemistry University of California Riverside, California 92521 Cite this: J. Am. Chem. Soc. 2000, 122, 51, 12866–12867Publication Date (Web)…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

Dielectric cracking produced by electromigration in microelectronic interconnects

S. Chiras、David R. Clarke2000-12-01Journal of Applied Physics

The development of stress during electromigration along Al lines, constrained within a dielectric in a coplanar test configuration, is measured. It is shown that, above a certain threshold current density, cracking of the dielectric is induced in the vicinity of the anode. Cracking of the dielectric leads to loss of m…

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

A Study of Corrosion of Mild Steel in Mixtures of Petroleum Distillates and Electrolytes

Alec Groysman、Natasha Erdman2000-12-01CORROSION

Petroleum distillates are not corrosive unless water and some other species are contained in them at particular concentrations. It was not found in the literature what water concentration and which species result in high corrosiveness of light petroleum distillates. The purpose of this study was to determine minimal (…

Material Properties and ApplicationsEngineering Diagnostics and ReliabilityMaterial Properties and Failure Mechanisms

Synthesis and Crystal Structure of Europium(II) Tartrate Tetrahydrate, [Eu(C4H4O6)(H2O)2](H2O)2

Przemysław Starynowicz、Gerd Meyer2000-12-01Zeitschrift für anorganische und allgemeine Chemie

Single crystals of [Eu(C4H4O6)(H2O)2](H2O)2 were obtained from the combination of solutions of EuCl2, previously obtained by electrolysis of an aqueous solution of EuCl3, and tartraric acid, neutralized by LiOH. The crystal structure (orthorhombic, P212121, Z = 4, a = 948.9(1), b = 954.6(1), c = 1098.4(1) pm; R(F) = 0…

Crystal structures of chemical compoundsLanthanide and Transition Metal ComplexesThermal and Kinetic Analysis

Poly(arylene ether)s via Nitro Displacement Reaction: Synthesis of Poly(biphenylene oxide)s Containing Trifluoromethyl Groups from AB Type Monomers

Im Sik Chung、Sang Youl Kim2000-12-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTPoly(arylene ether)s via Nitro Displacement Reaction: Synthesis of Poly(biphenylene oxide)s Containing Trifluoromethyl Groups from AB Type MonomersIm Sik Chung and Sang Youl KimView Author Information Center for Advanced Functional…

Catalytic Cross-Coupling ReactionsSynthesis and properties of polymersSilicone and Siloxane Chemistry

Homeotropic polar anchoring energy of a nematic liquid crystal using the fully leaky waveguide technique

Fuzi Yang、Lizhen Ruan、J. R. Sambles2000-12-01Journal of Applied Physics

Optical excitation of a series of fully leaky guided modes has been used to explore the director distortion of a hybrid-aligned nematic liquid crystal with a negative dielectric anisotropy (Merck-BDH, MLC 6608) under application of an ac electric field. Hybrid alignment is realized by the use of a lecithin film on the…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPlant Reproductive Biology

Über den H- und A-Typ von La2[Si2O7]

Helge Müller‐Bunz、Thomas Schleid2000-12-01Zeitschrift für anorganische und allgemeine Chemie

Beim thermischen Abbau von La3F3[Si3O9] bei 700 °C im CsCl-Flux wurden Einkristalle einer neuen Form von La2[Si2O7] gefunden und in Fortsetzung der Felsche'schen Nomenklatur als H-Typ (triklin, P1; a = 681,13(4), b = 686,64(4), c = 1250,23(8) pm, α = 82,529(7), β = 88,027(6), γ = 88,959(6)°; Vm = 87,223(9) cm3/mol, Dx…

Crystal Structures and PropertiesInorganic Chemistry and MaterialsInorganic Fluorides and Related Compounds

The crystal structures of NaNO3 at 100 K, 120 K and 563 K

G. Gonschorek、H. Weitzel、G. Miehe 等 5 位作者2000-12-01Zeitschrift für Kristallographie - Crystalline Materials

NaNO 3 , Synchrotron X-ray diffraction at 100 K: λ = 0.56Å, R -3c, a = 5.0655(5) Å, c = 16.577(3) Å, V = 368.4 Å 3 , Z = 6, F(000) = 78e, refinement on | F |. Anharmonic motion of N and O up to the fourth order of a Gram-Charlier expansion and multipoles for all ions were refined. R = 0.029, w R = 0.028, S 2 = 3.539,…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

A Convenient and Effective Synthesis of Tris-Bridged Tricationic Azolophanes

Yi Yuan、Zong‐Lin Jiang、Jiaming Yan 等 6 位作者2000-12-01Synthetic Communications

Two new macrobicyclic imidazolium and benzimidazolium phanes were synthesized by direct quaternization of the corresponding tripodal azacycles with tribromide under high dilution condition in excellent yields. The cyclophanes were identified by 1H-NMR, 13C-NMR, FAB-MS, IR, elemental analysis and X-ray diffraction anal…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Thin Films of Carbon Nanocapsules and Onion-Like Graphitic Particles Prepared by the Cosputtering Method

Osamu Mamezaki Osamu Mamezaki、Hiroaki Adachi、Satoshi Tomita 等 5 位作者2000-12-01Japanese Journal of Applied Physics

A method for fabricating thin films of carbon nanocapsules and onion-like graphitic particles was reported. The method consists of cosputtering Ni and graphite, and subsequent thermal annealing in vacuum. Transmission electron microscopic and Raman studies revealed that the films were composed of Ni-filled carbon nano…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchFullerene Chemistry and Applications

Hollow Yarn in Friction Spinning

Ali Akbar Merati、Masaaki Okamura2000-12-01Textile Research Journal

"Hollow" yams have been created to improve cotton yam properties, to increase the entrapped air in the yam, and to gain a stronger yam for spinning and weaving processes. Hollow yams are spun by introducing PVA filaments into the yam-forming zone of an experimental friction spinning apparatus. A 61/18-denier (6.8 tex)…

Textile materials and evaluationsStructural Analysis and Optimization

Quantum Dots in Carbon Nanotubes

Koji Ishibashi、Tetsuya Ida、Masaki Suzuki 等 5 位作者2000-12-01Japanese Journal of Applied Physics

A technology to fabricate electrical contacts on individual single-wall carbon nanotubes has been developed, and electrical measurements are carried out below 4.2 Kelvin. The electrical transport property at low temperatures has basically been characterized as a quantum dot with a pronounced Coulomb blockade effect an…

Carbon Nanotubes in CompositesGraphene research and applicationsChemical and Physical Properties of Materials

Second- and higher-order resonant gratings with gain or loss-Part 1: Green's function analysis

A.M. Shams-Zadeh-Amiri、Jin Hong、Xun Li 等 4 位作者2000-12-01IEEE Journal of Quantum Electronics

We describe a systematic method for obtaining the coupling coefficients due to diffraction orders less than the grating order of second- and higher order resonant complex gratings in a multilayer structure. This method is based on an improved Green's function, and its distinguishing feature is its use of the transfer…

Photonic and Optical DevicesPhotorefractive and Nonlinear OpticsOptical Coatings and Gratings

Transition Metal Complexes as Photosensitizers for Near-Infrared Lanthanide Luminescence

Stephen I. Klink、Henk Keizer、Frank C. J. M. van Veggel2000-12-01Angewandte Chemie

Sensibilisierte Nah-Infrarot-Lumineszenz (NIR-Lum.) wurde bei Lanthanoiden (Ln) erstmals beobachtet (siehe Schema; Exc.=Anregung). Ermöglicht wurde dies durch Energietransfer (ET) von Ferrocen- oder Tris(bipyridin)ruthenium-funktionalisierten lichtsammelnden Einheiten. Dank der Luminszenz des Triplettzustands des Ru-D…

Magnetism in coordination complexesLuminescence and Fluorescent MaterialsLanthanide and Transition Metal Complexes

An Analysis of the Thermal Motion in the Negative Thermal Expansion Material Sc2(WO4)3 Using Isotopes in Neutron Diffraction

Mark T. Weller、Paul F. Henry、Chick C. Wilson2000-12-01The Journal of Physical Chemistry B

A full analysis of thermal motion has been carried out for the negative thermal expansion material Sc 2 (WO 4 ) 3 over the temperature range 50−823 K. By obtaining neutron diffraction data from isotopically pure samples of the compositions Sc 2 ( 184 WO 4 ) 3, Sc 2 ( 186 WO 4 ) 3 and natural Sc 2 (WO 4 ) 3, coupled wi…

Advanced Battery Materials and TechnologiesThermal Expansion and Ionic ConductivityThermodynamic and Structural Properties of Metals and Alloys

Oxidation Behavior of Si‐C‐O Fibers (Nicalon) under Oxygen Partial Pressures from 10 2 to 10 5 Pa at 1773 k

Toshio Shimoo、Yoshiaki Morisada、Kiyohito Okamura2000-12-01Journal of the American Ceramic Society

Polycarbosilane‐derived SiC fibers (Nicalon) were oxidized at 1773 K under oxygen partial pressures from 10 2 to 10 5 Pa. The effect of oxygen partial pressure on the oxidation behavior of the Nicalon fibers was investigated by examining mass change, surface composition, crystal phase, morphology, and tensile strength…

Advanced ceramic materials synthesisDiamond and Carbon-based Materials ResearchAdvanced materials and composites

Synergistic effect of thiourea derivatives and non‐ionic surfactants on the inhibition of corrosion of carbon steel in acid environments

D. Gopi、N. Bhuvaneswaran、S. Rajeswarai 等 4 位作者2000-12-01Anti-Corrosion Methods and Materials

Some thiourea derivatives, non‐ionic surfactants and their synergism when used simultaneously were evaluated for their efficiency as corrosion inhibitors for mild steel in 1N H 2 SO 4 solution at different temperatures (303, 313 and 323K). A marked inhibition synergism occurred within an optimum concentration range ev…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Current and Potential Fluctuation Characteristics in Intergranular Stress Corrosion Cracking Processes of Stainless Steels

Yutaka Watanabe、Tatsuo KONDO2000-12-01CORROSION

Electrochemical noise behavior of Type 304 austenitic stainless steel (UNS S30400) with various degrees of sensitization was investigated under slow strain rate tensile (SSRT) conditions in a dilute sodium thiosulfate (Na2S2O3) solution. Fluctuations in short-circuit current between a SSRT specimen and a counter elect…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms