Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTVibrational investigations of polyoxometallates. 1. Valence force field of Mo6O192- based on total isotopic substitution (oxygen-18, molybdenum-92, molybdenum-100)Claude Rocchiccioli-Deltcheff, Rene Thouvenot, and Monique FouassierCite this: Inorg. Chem. 1982, 21, 1, 30–35Pu…
Structural, thermodynamic, and kinetic properties and phase diagrams of hydrogen in metals and alloys are presented in relation to materials development for the ‘hydrogen energy technology'. Among the materials considered special attention is paid to the hydrides of Li, Mg, Y, V, Nb, U, TiFe, and LaNi5. It is shown ho…
The growth of the snow crystal is an important example of crystal growth not attributable to the presence of screw dislocations. More than 400 years of study of the habits of these crystals culminated in the work of Nakaya establishing the complex and abrupt changes of crystal habit with temperature and humidity, and…
Quantitative phase analysis by powder diffractometry requires accurate measurement of the integrated intensities of the diffracted, lines. When lines are isolated and on simple backgrounds, count integration techniques work very well. However, when one or more lines overlap the line of interest, or a complex backgroun…
Crystal structures for the electron donor DBTTF and its charge-transfer salts with the acceptors TCNQ and 2,5-TCNQF2 are reported. Crystal data for the three systems are as follows: (a) neutral DBTTF; monoclinic, space group P21/c, a=12.082(2) Å, b=3.955(1) Å, c=14.553(2) Å, β=114.36(1)0, V=633.6 Å3; (b) DBTTF-TCNQ; t…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTemporary anion states of phosphabenzene, arsabenzene, and stibabenzene. Trends in the .pi. and .pi.* orbital energiesP. D. Burrow, A. J. Ashe III, D. J. Bellville, and K. D. JordanCite this: J. Am. Chem. Soc. 1982, 104, 2, 425–429Publication Date (Print):January 1, 1982Publ…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProperties of low molecular weight block copolymers. 1. Differential scanning calorimetry of styrene-dimethylsiloxane diblock copolymersSonja Krause, Magdy Iskandar, and Mohammad IqbalCite this: Macromolecules 1982, 15, 1, 105–111Publication Date (Print):January 1, 1982Publi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMechanisms for the photooxidation of protoporphyrin IX in solutionG. Sidney Cox and David G. WhittenCite this: J. Am. Chem. Soc. 1982, 104, 2, 516–521Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Published inissue 1 January 1982https:/…
A series of dimeric copper(II) co-ordination compounds with general formula [Cu2(tmbma)2(azolate)]X3 has been prepared and characterized, where tmbma is the tripodal benzimidazole-containing ligand tris(N-methylbenzimidazol-2-ylmethyl)amine, azolate is the anion of imidazole, benzimidazole, or benzotriazole, and X = N…
Mineralogical properties of tobelite, a new ammonium-dominant dioctahedral mica, found in the Ohgidani pottery stone deposit at Tobe, Ehime Prefecture, Japan, are described.This mineral, accompanied by quartz, occurs as a hydrothermal alteration product of a biotite andesite dyke. Wet chemical analysis gives a structu…
The phase transitions in {N(CH 3 ) 4 } 2 XBr 4 (X: Zn, Co, Cu) were stuided by dielectric measurements. A phase transition which accompanied with a break on the dielectric constant vs temperature curve was found at 13.5°C and 13.8°C for {N(CH 3 ) 4 } 2 ZnBr 4 and {N(CH 3 ) 4 } 2 CoBr 4 , respectively. In {N(CH 3 ) 4 }…
Nous présentons une nouvelle et remarquable séquence mésomorphe dans un produit pur : le 4-nitrobenzoyloxybenzoate de 4-nonyloxyphényle à la pression atmosphérique : K(SC2)S ?SA1NreSAd reNreSAd NI. Cette séquence comporte deux phases nématiques rentrantes (phénomène jamais observé à ce jour) et une phase smectique SAd…
Decomposition of the Martensite in Two-Phase Titanium Alloys.- The Investigation of the Titanium Structure after Shock Wave Loading.- Embrittlement and Spontaneous Cracking of a Hardened (?+?) Titanium Alloy during Aging.- Transformation in Unstable Beta-Titanium Alloys.- Internal Friction Studies in Stable and Metast…
Electrical conductivity of α quartz is ionic, the current being carried by alkali ions (M+) moving in channels parallel to the c axis. A study was made of conductivity σ of one natural and three synthetic crystals in order to better understand these ionic defects. ac measurements were made over a wide range of frequen…
The diffusion of rod-like molecules is studied in the case of high density. It is argued that when one goes to densities higher than those permitting rotational freedom for the rods, the diffusion of one rod will depend critically upon the cooperation of the others. A calculation of this effect using mean-field theory…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIsotactic polymerization of .alpha.-olefins: stereoregulation for different reactive chain endsA. Zambelli, M. C. Sacchi, P. Locatelli, and G. ZannoniCite this: Macromolecules 1982, 15, 1, 211–212Publication Date (Print):January 1, 1982Publication History Published online1 M…
Trente échantillons d'argiles kaoliniques provenant de Cornouailles anglaise et française, de Géorgie, des Charentes, ont été étudiés par analyses chimique, cristallographique, spectroscopique (I.R.), granulométrique, thermique différentielle et mesures des surfaces spécifiques. Le fer, sous forme d'oxydes ou hydroxyd…
In Escherichia coli, quinolinic acid, a precursor of NAD+, is synthesized from L-aspartate and dihydroxyacetone phosphate. This synthesis requires two enzymes, a FAD-containing "B protein" and an "A protein." The B protein has been purified 500-fold from E. coli cells. The enzyme behaves as an L-aspartate oxidase. In…
Hydrogen adsorption on high-surface-area alkaline-earth oxides has been studied by i.r. spectroscopy at 300 and 78 K. In the former case heterolytic dissociation of H2 molecules produces hydride and hydroxy groups which are partially reversible upon evacuation. Low-temperature hydrogen adsorption appears to be undisso…
This investigation has been aimed at a better understanding of epitaxy; particularly, but not exclusively, in monolayers. The description has been facilitated by the introduction of a configuration space γ, spanned by the parameters relevant to epitaxy, namely, lattice parameters, misorientation, bonding, etc. The rig…