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Liquid crystalline polymer nanocomposites reinforced with in-situ reduced graphene oxide

Diego Pedrazzoli、Andrea Dorigato、Tiago G. Conti 等 6 位作者2015-01-01eXPRESS Polymer Letters

In this work liquid-crystalline polymer (LCP) nanocomposites reinforced with in-situ reduced graphene oxide are investigated. Graphene oxide (GO) was first synthesized by the Hummers method, and the kinetics of its thermal reduction was assessed. GO layers were then homogeneously dispersed in a thermotropic liquid cry…

Dielectric materials and actuatorsCarbon Nanotubes in CompositesGraphene research and applications

Targeted kinetic strategy for improving the thermal conductivity of epoxy composite containing percolating multi-layer graphene oxide chains

Tianle Zhou、Hirotaka Koga、Masaya Nogi 等 10 位作者2015-01-01eXPRESS Polymer Letters

By adding 2 wt% multi-layer graphene oxide (MGO) to an epoxy resin, the thermal conductivity of the composite reached a maximum, 2.03 times that of the epoxy. The presence of 2 wt%MGO percolating chains leads to an unprecedentedly sharp rise in energy barrier at final curing stage, but an increased epoxy curing degree…

Synthesis and properties of polymersGraphene research and applicationsThermal properties of materials

Effect of rubber polarity on selective wetting of carbon nanotubes in ternary blends

H. H. Le、M. Parsaker、M. N. Sriharish 等 10 位作者2015-01-01eXPRESS Polymer Letters

Based on atomic force microscopy (AFM) and Fourier transform infrared spectroscopy (FTIR) analysis of the rubber-filler gel (wetting concept) the kinetics of selective wetting of carbon nanotubes (CNTs) in ternary styrene butadiene rubber (SBR)/butadiene rubber (BR)/natural rubber (NR) blends was qualitatively and qua…

Carbon Nanotubes in CompositesTribology and Wear AnalysisPolymer Nanocomposites and Properties

Effects of benzoxazine resin on property enhancement of shape memory epoxy: A dual function of benzoxazine resin as a curing agent and a stable network segment

Thachanat Tanpitaksit、Chanchira Jubsilp、Sarawut Rimdusit2015-01-01eXPRESS Polymer Letters

An ability of bisphenol-A/aniline based benzoxazine resin (BA-a) to simultaneously acts as a curing agent and a stable or rigid network segment for shape memory epoxy, i.e. a two component system, is demonstrated. This significantly simplifies a formulation of present shape memory epoxy systems, i.e. a three or four c…

Photochromic and Fluorescence ChemistryEpoxy Resin Curing ProcessesPolymer composites and self-healing

A comparative investigation on strain induced crystallization for graphene and carbon nanotubes filled natural rubber composites

Dongying Fu、Yanhu Zhan、Ning Yan 等 4 位作者2015-01-01eXPRESS Polymer Letters

Natural rubber containing graphene and carbon nanotubes (CNTs) composites were prepared by ultrasonicallyassisted latex mixing. Natural rubber filled by both graphene and CNTs show significant enhanced tensile strength, while graphene exhibits a better reinforcing effect than CNTs. Strain-induced crystallization in na…

Polymer Nanocomposite Synthesis and IrradiationPolymer Nanocomposites and PropertiesCarbon Nanotubes in Composites

Influence of deformation temperature on structural variation and shape-memory effect of a thermoplastic semi-crystalline multiblock copolymer

Wei Yan、L. Fang、U. Noechel 等 5 位作者2015-01-01eXPRESS Polymer Letters

A multiblock copolymer termed as PCL-PIBMD, consisting of crystallizable poly(!-caprolactone) (PCL) segments and crystallizable poly(3S-isobutyl-morpholine-2,5-dione) (PIBMD) segments, has been reported as a material showing a thermally-induced shape-memory effect. While PIBMD crystalline domains act as netpoints to d…

Silicone and Siloxane ChemistryConducting polymers and applicationsPolymer composites and self-healing

Plant oil-based shape memory polymer using acrylic monolith

Takashi Tsujimoto、E. Ohta、Hiroshi Uyama2015-01-01eXPRESS Polymer Letters

This article deals with the synthesis of a plant oil-based material using acrylic monolith. An acrylic monolith bearing oxirane groups was prepared via simple technique that involved the dissolution of poly(glycidyl methacrylate-comethyl methacrylate) (PGMA) in ethanolic -aqueous solution by heating and subsequent coo…

Electrospun Nanofibers in Biomedical ApplicationsPolymer composites and self-healingSilicone and Siloxane Chemistry

Effect of annealing and UV-radiation time over micropore architecture of self-assembled block copolymer thin film

Guadalupe del C. Pizarro、Oscar G. Marambio、Manuel Jeria‐Orell 等 6 位作者2015-01-01eXPRESS Polymer Letters

Block copolymers have been recognized as versatile materials to prepare nanoporous polymer films or membranes, but their potential has not been completely explored. This study focuses on the formation and characterization of nanoporous polymer films based on poly(styrene)-block-(methylmethacrylate/methacrylic acid); (…

Nanofabrication and Lithography TechniquesAdvanced Polymer Synthesis and CharacterizationBlock Copolymer Self-Assembly

The influence of chain defects on the crystallisation behaviour of isotactic polypropylene

D.W. van der Meer、J. Varga、G. Julius Vancsó2015-01-01eXPRESS Polymer Letters

The crystallization characteristics of the !-, "-and #-phases of isotactic polypropylene were studied for welldefined and fully characterized polymers with varying amounts of stereo-and regio-defects. The specimens enabled us to study separately the influence of the type of chain defect and the concentration of defect…

biodegradable polymer synthesis and propertiesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Compositional Effects and Mechanical Parametric Analysis of Outwash Deposits Based on the Randomised Generation of Stone Blocks

Chong Shi、Jinzhou Bai2015-01-01Advances in Materials Science and Engineering

Based on the distribution of the stone blocks in outwash deposits, the paper present a modeling method for the random structure of outwash deposits, in which the long axis of the stone blocks is supposed obeying a lognormal distribution. Then numerical experiments of biaxial compression using the granular discrete ele…

Development of a New Type of Alkali-Free Liquid Accelerator for Wet Shotcrete in Coal Mine and Its Engineering Application

Gang Zhou、Weimin Cheng、Sen Cao2015-01-01Advances in Materials Science and Engineering

In order to address issues such as large rebound rate, high dust concentration, and low compressive strength of shotcrete when adding liquid accelerator during wet spraying, the factors influencing the efficiency of liquid accelerator were experimentally analyzed. The single-admixture, combination, and orthogonal test…

Obtaining Martensitic Structures during Thixoforming of Hypoeutectic Gray Cast Iron

Lucas Bertolino Ragazzo、Davi Munhoz Benati、Rodolfo Lopez Nadal 等 4 位作者2015-01-01Advances in Materials Science and Engineering

The control of parameters such as liquid fraction, holding time, and cooling rate during thixoforming can help control the final microstructure of the thixoformed part, thus improving its mechanical properties. This study intended to investigate conditions required to obtain martensite in hypoeutectic gray cast iron a…

Preparation and characterization of Protein A-immobilized PVDF and PES membranes

N. Akashi、S. Kuroda2015-01-01eXPRESS Polymer Letters

Polyvinylidene fluoride (PVDF) and polyether sulfone (PES) membranes were activated using low-temperature plasma at atmospheric pressure, and their surface characteristics were investigated. In the plasma-treated PVDF, the XPS data showed that defluorination and oxidation reactions proceeded to 18 and 31%, respectivel…

Influence of Tensile Speeds on the Failure Loads of the DP590 Spot Weld under Various Combined Loading Conditions

Jung Han Song、Hoon Huh2015-01-01Advances in Materials Science and Engineering

This paper is concerned with the evaluation of the dynamic failure load of the spot weld under combined axial and shear loading conditions. The testing fixture is designed to impose the combined axial and shear load on the spot weld. Using the proposed testing fixtures and specimens, quasi-static and dynamic failure t…

Stability of Three-Dimensional Slurry Trenches with Inclined Ground Surface: A Theoretical Study

Xiao-Fei Jin、Shu-ting Liang、Xiao-jun Zhu2015-01-01Advances in Materials Science and Engineering

Stability of slurry trenches is an important issue during the construction of the groundwater cutoff walls and diaphragm walls, and thus gradually draws attention. In this paper, a theoretical method for a three-dimensional trench model with an inclined ground was proposed. Based on the Coulomb-type force equilibrium,…

Numerical Studies on Mechanical Behavior of Adhesive Joints

Xiaocong He、Yue Zhang2015-01-01Advances in Materials Science and Engineering

This paper describes some finite element models for analyzing the mechanical behavior of adhesive joints. In these models five layers of solid elements were used across the adhesive layer in order to increase the accuracy of the results. The finite elements were refined gradually in steps from adherends to adhesive la…

Photocatalysis and Bandgap Engineering Using ZnO Nanocomposites

Muhammad Ali Johar、Rana Arslan Afzal、Abdulrahman Ali Alazba 等 4 位作者2015-01-01Advances in Materials Science and Engineering

Nanocomposites have a great potential to work as efficient, multifunctional materials for energy conversion and photoelectrochemical reactions. Nanocomposites may reveal more improved photocatalysis by implying the improvements of their electronic and structural properties than pure photocatalyst. This paper presents…

Prediction of the Service Life of a Reinforced Concrete Column under Chloride Environment

Mohammad K. Alkam、Maha Alqam2015-01-01Advances in Materials Science and Engineering

In the present investigation, service life of a reinforced concrete column exposed to chloride environment has been predicted. This study has been based on numerical simulation of chloride ion diffusion in a concrete column during its anticipated life span. The simulation process has included the concrete cover replac…

The Albedo of Pervious Cement Concrete Linearly Decreases with Porosity

Rui Zhang、Guosheng Jiang、Jia Liang2015-01-01Advances in Materials Science and Engineering

Pervious pavements have been advocated as a potential countermeasure to the urban heat island effect. To understand if pervious pavements stay cooler than conventional pavements, the albedo of the pervious concrete must be understood. This study measured the albedo of pervious concrete with different porosity. Four Po…