Materials Literature
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Abstract Vulcanization kinetics for a SBR compound was studied by using both curemeter and DSC methods by a kinetic approach. A simplified but realistic model reaction scheme was used to simulate both induction and curing periods simultaneously. Model parameters were extracted from isothermal curemeter experiments. Th…
Abstract Sulfur-cured SBR vulcanizates are devulcanized by high power ultrasonic irradiation in a continuous process under various processing conditions. Crosslink density and gel fraction of devulcanized rubber are measured. The unique dependence of crosslink density on gel fraction of devulcanized samples obtained a…
Calcined (Ba 0.8 Sr 0.2 )(Ti 0.9 Zr 0.1 )O 3 (BSTZ) with added CuO is used as an improved material with which to fabricate surface (or reduction-reoxidation) barrier layer capacitors (BLCs). The CuO-containing BSTZ appears to have less temperature, frequency, and bias dependence of the dielectric characteristics and a…
A new powder diffractometer for synchrotron radiation with six detector arms has been constructed. Five detector arms are attached radially at intervals of 25 degrees to the 2theta axis and form a multiple-detector system. Five scintillation counters coupled with flat Ge(111) crystal analyzers on the respective arms c…
We have examined the adsorption of CO, NO, and H2on modelPd/ceria catalysts, formed by vapor deposition of Pd metal ontoa flat, polycrystalline ceria support, using temperatureprogrammed desorption. For CO adsorption on freshly deposited Pdfilms, a substantial fraction of the CO reacts to CO2in TPD,between 450 and 550…
The embrittlement of poly(hydroxybutyrate), and its copolymers with hydroxyvalerate, on storage at room temperature has been considered in the light of the relaxation of the interlamellar glassy regions and also the development of secondary crystallisation. From a study of the kinetics of the two processes, the first…
The relative conductivity of ${\mathrm{Fe}}_{3}$${\mathrm{O}}_{4}$ single crystals very close to ideal stoichiometry has been measured as a function of pressure up to P=16 GPa and in the temperature range of 4.2 to 300 K. The pressure dependence of the Verwey transition ${\mathit{T}}_{\mathit{V}}$ and the mechanism of…
Sonochemical decomposition of a series of hydroxybenzoic acids such as monohydroxy-, 3,4-dihydroxy-, 3,4,5-trihydroxybenzoic acids, tannic acid, and reagent and prepared humic acids in water under argon or air atmosphere was investigated. The decomposition followed first-order kinetics at initial stage, and initial ra…
Using a high-resolution digital x-ray camera we have accurately measured the density profiles of several sediments of highly screened polystyrene colloidal spheres suspended in water. From the integral of the profile with height we directly measured the osmotic pressure as a function of volume fraction. The results ar…
Abstract Ground rubber tire (GRT) is devulcanized in a continuous process where the rubber crumb is conveyed by a screw extruder to a thin gap between a stationary die and a vibrating horn. Ultrasound amplitude, gap thickness and the duration of the treatment are varied, and their effect on the rubber properties is st…
An experimental technique for imposing lateral confinement on specimens subjected to dynamic or quasi‐static uniaxial compression has been developed. Lateral confinement is provided by a shrink‐fit metal sleeve installed on the lateral surface of a cylindrical ceramic specimen. Experiments using this technique were pe…
PURPOSE: To determine if tumor-specific monoclonal antibodies conjugated to superparamagnetic monocrystalline iron oxide nanoparticles can be used to yield specific diagnoses with the use of MR imaging. METHODS: Monoclonal antibodies conjugated to monocrystalline iron oxide nanoparticles were given to nude rats with i…
The conventional Langelier index or Larson's ratio approach to controlling copper corrosion by‐product release is demonstrably inaccurate. Contrary to expectations, higher bicarbonate concentrations exacerbate copper corrosion rates and by‐product release. In fact, as illustrated by monitoring experiences of large uti…
The potential of chitosan, a non-toxic and biodegradable polymer of beta -1,4-glucosamine, for controlling fusarium crown and root rot of greenhouse-grown tomato caused by Fusarium oxysporum f.sp. radicis-lycopersici (FORL) was investigated. The amendment of plant growth substratum with chitosan at concentrations of 1…
The solid-phase portion of the Al-Li phase diagram has been computed from first principles both at zero pressure and at a hydrostatic compression of 5.4 GPa. Computation of the pressure dependence of the Al-Li phase equilibria answers two questions: (1) how important is the effect of the atomic size difference, and (2…
Thin films of nickel oxide (NiO) with NaCl-type structure were prepared on glass substrates at 400°C by plasma-enhanced metalorganic chemical vapor deposition using nickel acetylacetonate as a source material. The relationship between O 2 flow rate, and preferred orientation and microstructure of the NiO films was inv…
The thickness of the intergranular films in Si 3 N 4 densified with lanthanide oxides has been systematically investigated using high‐resolution transmission electron microscopy. Four lanthanide oxides—La 2 O 3 , Nd 2 O 3 , Gd 2 O 3 , and Yb2O3—as well as Y 2 O 3 are chosen so that the results will reflect the overall…
All articles of this category The utilisation of the 2-cyanoethyl group as a versatile protecting group for 2-thioxo-1,3-dithiole-4,5-dithiolates and tetrathiafulvalene-thiolates is reported. Mono deprotection of bis-protected 2-thioxo-1,3-dithiole-4,5-dithiolate and of bis-protected tetrathiafulvalene-2,3-dithiolates…
We report the fabrication of several multilayer light-emitting-diode (LED) devices based on a novel conjugated polymer, poly(2,5-dihexadecanoxy phenylene vinylene pyridyl vinylene) (PPV-PPy V), involving the use of polyaniline (emeraldine base, EB) as an insulating layer between the emissive polymer layer and the elec…
The effect of host glass composition on the optical absorption spectra of ${\mathrm{Nd}}^{3+}$, ${\mathrm{Sm}}^{3+}$, and ${\mathrm{Dy}}^{3+}$ in lead borate glasses, with PbO contents varying from 30 to 70 mol %, has been analyzed using Judd-Ofelt theory and the compositional dependence has been determined for the hy…