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SUR LES SPECTRES INFRAROUGES DES PHTALOCYANINES

H. F. Shurvell、L. Pinzuti1966-01-15Canadian Journal of Chemistry

Infrared spectra of metal-free phthalocyanine, chlorinated and unchlorinated copper phthalocyanines, and three new metal derivatives of phthalocyanine: MoPc, Na 2 Pc, and AlOH—Pc (Pc = C 32 H 16 N 8 ), have been recorded. Assignments have been suggested for many of the peaks in the infrared spectra of the phthalocyani…

Porphyrin and Phthalocyanine Chemistry

Calculation of Thermal Conductivity by the Kubo Formula

B. B. Deo、S. N. Behera1966-01-14Physical Review

The Kubo expression for lattice thermal conductivity is analyzed by the method of the double-time Green's function. The usual relaxation-time formula of kinetic theory can be obtained from the Kubo formula by suitable approximations only.

Thermal Radiation and Cooling TechnologiesThermal properties of materialsAdvanced Thermoelectric Materials and Devices

Remark on the Hopping Transition Probability of Polaron Holes in NiO

J. Appel1966-01-14Physical Review

For the hopping motion of polaron holes the frequency factor ${W}_{0}$ of the transition probability is determined by the observation that hole localization occurs in a molecular orbital of the irreducible set ${t}_{2g}$ of a cation site group (with transfer integral ${b}_{\ensuremath{\pi}}$), whereas the superexchang…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsPhysics of Superconductivity and Magnetism

Far-Infrared Properties of Cuprous Oxide

E. C. Heltemes1966-01-14Physical Review

The transmission and reflectance of cuprous oxide has been measured from 6 to 250 \ensuremath{\mu} and analyzed by classical dispersion theory. The two infrared-active vibrational frequencies are given by ${\ensuremath{\nu}}_{1}=613$ ${\mathrm{cm}}^{\ensuremath{-}1}$ and ${\ensuremath{\nu}}_{2}=146.0$ ${\mathrm{cm}}^{…

Copper-based nanomaterials and applications

Room-Temperature Deformation Luminescence in Alkali Halides

Charles Butler1966-01-14Physical Review

Emission of light by crystals mechanically deformed at room temperature after $\ensuremath{\gamma}$ irradiation at 35\ifmmode^\circ\else\textdegree\fi{}C has been studied. Spectra of several alkali halides were measured, and the intensity of the luminescence investigated in relation to $\ensuremath{\gamma}$ dose, stra…

X-ray Diffraction in CrystallographyCrystallography and molecular interactionsGlass properties and applications

Acoustical-Optical Phonon Scattering in Ge, Si, and III-V Compounds

E. F. Steigmeier、I. Kudman1966-01-14Physical Review

The thermal conductivities of AlSb apd GaSb have been measured between 300 and 950\ifmmode^\circ\else\textdegree\fi{}K, and of GaP between 300 and 550\ifmmode^\circ\else\textdegree\fi{}K, on $n$-type samples of about ${10}^{18}$ ${\mathrm{cm}}^{\ensuremath{-}3}$ using the diffusivity technique. The room temperature th…

Thermography and Photoacoustic TechniquesUltrasonics and Acoustic Wave PropagationThermal properties of materials

Mica Polytypes: Systematic Description and Identification

Malcolm Ross、Hiroshi Takeda、David R. Wones1966-01-14Science

X-ray studies of mica specimens from a variety of geological localities show that biotite and certain lithium-rich mica samples are composed of a mixture of different polytypes. Many of the biotite structures are new complex polytypes not before reported. A new method of designating mica polytypes is proposed. Techniq…

Clay minerals and soil interactionsNuclear materials and radiation effectsGeological and Geochemical Analysis

Superconducting Transition Temperature ofLa3S4

G.L. Guthrie、R. L. Palmer1966-01-07Physical Review

The superconducting transition temperature of stoichiometric ${\mathrm{La}}_{3}$${\mathrm{S}}_{4}$ has been measured by two different methods and has been found to be (8.25\ifmmode\pm\else\textpm\fi{}0.2)\ifmmode^\circ\else\textdegree\fi{}K. A range of superconducting compositions exists in the metal-rich end of the $…

Crystal Structures and PropertiesMagnetic and transport properties of perovskites and related materialsHigh-pressure geophysics and materials

Spin-Lattice Relaxation in Some Rare-Earth Salts. I. Temperature Dependence

G. H. Larson、C. D. Jeffries1966-01-07Physical Review

We report measurements of the spin-lattice relaxation rate ${{T}_{1}}^{\ensuremath{-}1}$ for several magnetically dilute rare-earth ions in the temperature range $1.2\ifmmode^\circ\else\textdegree\fi{}\ensuremath{\leqq}T\ensuremath{\leqq}5\ifmmode^\circ\else\textdegree\fi{}$K, using the transient recovery of the micro…

Advanced NMR Techniques and ApplicationsLanthanide and Transition Metal ComplexesSolid-state spectroscopy and crystallography

Die Modifikationen des Niobpentoxids

Harald Schäfer、R. Gruehn、F. Schulte1966-01-07Angewandte Chemie

Abstract Niobpentoxid kristallisiert in zahlreichen Modifikationen. Die Arbeit bringt einen Überblick, insbesondere über die Bildungsweisen, die Strukturen und das thermische Verhalten.

Lubricants and Their AdditivesThermal and Kinetic AnalysisCorrosion Behavior and Inhibition

Tungsten Diboride: Preparation and Structure

Hannah Woods、F. E. Wawner、Brian G. Fox1966-01-07Science

A new tungsten boride has been prepared and has been assigned the formula WB(2). The assignment is based on comparison of the x-ray diffraction data of this boride with those of diborides of the AlB(2) type structure. Values of a(0) = 3.02 and c(0) = 3.05 were calculated for a hexagonal unit cell.

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsBoron and Carbon Nanomaterials Research

Données cristallographiques sur trois nouveaux trimétaphosphates de type benitoïte : (PO3)3 Cd MI (MI = Ag, Tl et Rb)

Μ. Τ. Averbuch-Pouchot、I. Tordjman、André Durif-Varambon1966-01-01Bulletin de la Société française de Minéralogie et de Cristallographie

Averbuch-Pouchot Marie-Thérèse, Tordjman Isaac, Durif-Varambon André. Données cristallographiques sur trois nouveaux trimétaphosphates de type benitoïte : (PO3)3 Cd MI (MI = Ag, Tl et Rb). In: Bulletin de la Société française de Minéralogie et de Cristallographie, volume 89, 3, 1966. pp. 405-406.

Crystal Structures and PropertiesLuminescence Properties of Advanced MaterialsSolid-state spectroscopy and crystallography

A Note on the Tempering Behavior of a Ti-9wt% Ta Alloy Quenched from β Region

Toshimi Yamane、Jitsuhiko Ueda1966-01-01Transactions of the Japan Institute of Metals

Changes in dislocation arrangement and twin faults formation by quenching and tempering of a Ti-9% Ta alloy were investigated by means of internal friction measurements and transmission electron microscopy. It has been found that typical needle-like martensite structures were produced by quenching from the β region, a…

Titanium Alloys Microstructure and PropertiesIntermetallics and Advanced Alloy PropertiesMicrostructure and Mechanical Properties of Steels

Forme rhomboédrique des métaphosphates du type (PO3)3MIIK (MII = Co, Ni, Mg, Zn)

André Durif-Varambon、Jean‐Claude Grenier、Μ. Τ. Averbuch-Pouchot 等 4 位作者1966-01-01Bulletin de la Société française de Minéralogie et de Cristallographie

Durif-Varambon André, Grenier Jean-Claude, Averbuch-Pouchot Marie-Thérèse, Tranqui Duc. Forme rhomboédrique des métaphosphates du type (PO3)3MIIK (MII = Co, Ni, Mg, Zn). In: Bulletin de la Société française de Minéralogie et de Cristallographie, volume 89, 2, 1966. pp. 273-274.

Crystal Structures and PropertiesThermal and Kinetic AnalysisChemical Synthesis and Characterization

Caractérisation des minéraux kaoliniques par diverses techniques

C. de Kimpe、F. Colmet Daage1966-01-01Bulletin du Groupe français des Argiles

Identification of kaolin minerals by D.T.A., X-ray diffraction, electron microscopy is sometimes unfeasible, mainly as far as low -crystallized forms are concerned. It can be the case with fire-clay, metahalloysite or intermediate forms. Infrared spectroscopy in the OH vibration band and Al-O-H deformation band region…

Soil and Unsaturated FlowGeochemistry and Geologic MappingClay minerals and soil interactions

Studies of the polyanions by Glauber-salt cryoscopy. Part I. Polyanions of tungsten

Deepali Jain、S.K. Dogra1966-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

Depression in the transition temperature of Glauber's salt due to the presence of WO42– and its polyanions have been measured at different pH values. The average degrees of condensation calculated from these measurements indicate the existence of mono-, tri-, and hexa-polytungstates. Polymerisation towards WO3 takes p…

Chemical Thermodynamics and Molecular StructureThermal and Kinetic AnalysisCorrosion Behavior and Inhibition

Oxide Inclusions Formed in the Steels of Fe-Cr-O System

Akira Adachi、Nobuya Iwamoto1966-01-01Transactions of the Iron and Steel Institute of Japan

The imjJortance oj inclusions in steel has been velY milch ellljJhasi;:ed, and many investigations have been carried out, but in most cases too 1Ilalry variables have been jJresented to draw wry definite conclusion.

Metallurgical Processes and ThermodynamicsMetal Alloys Wear and PropertiesMaterial Properties and Failure Mechanisms

Curling of crystals of 2,5-di-t-butyl-1,4-dimethoxybenzene during growth

J. M. Blatchly、N. H. Hartshorne1966-01-01Transactions of the Faraday Society

A further study has been made of the curling during growth of thin crystal plates of 2,5-di-t-butyl-1,4-dimethoxybenzene, and this behaviour has been related to the approximate structure of the compound deduced from its optical properties. It is suggested that the curling may be due to differential adsorption of the s…

Crystallization and Solubility Studies

Absorption Spectra of Mn2+Ion in Glasses

Sanjeev Kumar、Prabhu Nath1966-01-01Transactions of the Indian Ceramic Society

Absorption spectra of Mn2+ ion in alumino-boro-phosphate, magnesium-aluminoborate and soda-lime-silica glasses were studied within the range, 16000 cm-1 30000 cm-1 Five absorption bands were observed at or around 19200 cm-1 [4Γ4(G)], 23300 cm-1 [4Γ5(G)], 24000 cm-1 [4Γ3,4Γ1 (G)], 28100 cm-1 [4Γ5 (D)] and 29300 cm-1 [4…

Glass properties and applicationsLuminescence Properties of Advanced MaterialsOptical and Acousto-Optic Technologies