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Selection rules for the intermolecular enhancement of spin forbidden transitions in molecular oxygen

Charles Long、David R. Kearns1973-11-15The Journal of Chemical Physics

An experimental examination of the spin forbidden transitions of molecular oxygen dissolved in various solvents and in the gas phase reveals the following selection rules governing the intermolecular enhancement of these transitions: (i) Nonheavy atom solvents selectively enhance the 1Δg← 3Σg− transition (factor of 10…

Porphyrin and Phthalocyanine ChemistryHemoglobin structure and functionElectron Spin Resonance Studies

Electrically conducting mixtures

R.M. Scarisbrick1973-11-15Journal of Physics D Applied Physics

Mixtures consisting of conducting particles dispersed in an insulating medium are considered, and the electrical conduction which can occur by particles touching is related to the proportion of conducting material present in the mix, and its conductivity. It is found that limiting values of conduction can be obtained…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Inelastic Effects in Photoemission: Microscopic Formulation and Qualitative Discussion

C. Caroli、D. Lederer-Rozenblatt、B. Roulet 等 4 位作者1973-11-15Physical review. B, Solid state

The previous microcoscopic models of photoemission are developed and reformulated in order to include inelastic scattering effects. A general expression is given for the photocurrent and its energy distribution (EDC). The problem of inelastic scattering is more thoroughly discussed in the case of electron-phonon inter…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

X-Ray Photoelectron Band Structure of Some Transition-Metal Compounds

S. Hüfner、G. K. Wertheim1973-11-15Physical review. B, Solid state

The valence-band structures of MnO, CoO, NiO, CuO, ${\mathrm{Cu}}_{2}$O, Ni${\mathrm{Cl}}_{2}$, NiS, and KNi${\mathrm{F}}_{3}$ have been obtained by x-ray photoelectron spectroscopy. Band widths and positions are obtained, and are compared with the results of band-structure calculations. Bandwidths for the oxides are…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsInorganic Fluorides and Related Compounds

Thermal expansion of reference materials: copper, silica and silicon

G. K. White1973-11-15Journal of Physics D Applied Physics

Between 30 and 290 K the thermal expansion of vitreous silica is shown to be particularly sensitive to thermal history. Values given for the linear coefficient α were determined relative to copper, and existing reference data for copper are discussed. α for silicon has also been measured relative to copper from 55 K t…

High-pressure geophysics and materialsGlass properties and applicationsBuilding materials and conservation

A RADIOACTIVE TRACER STUDY OF DIFFUSION PROCESSES IN LEAD AND SILVER BROMIDE

S. RUSHBROOK WILLIAMS、L. W. Barr1973-11-01Le Journal de Physique Colloques

Anion self-diffusion has been studied in PbBr2 and AgBr using an isotope exchange technique. In addition the diffusion of Pb in PbBr2 has been measured using 210Pb as tracer and a chemical sectioning method. The effect of bromine gas pressure on anion diffusion has been examined for both materials. In the case of PbBr…

Nuclear Materials and PropertiesMolten salt chemistry and electrochemical processesAdvanced Materials Characterization Techniques

Sewing Needle Temperature

G. Michael Howard、D.R. Virgilio、E.R. Mack1973-11-01Textile Research Journal

The effect of various sewing conditions and needle characteristics on the temperature observed during high speed sewing has been studied. The maximum needle temperatures were determined by means of infrared (ir) flux measurements. A complete statistical experiment was used to show the effect of sewing speed, the use o…

Thermoregulation and physiological responsesTextile materials and evaluationsHeat Transfer Mechanisms

Grain boundary dislocations: Burgers vectors and arrangement in cubic metals

M. A. Fortes1973-11-01Philosophical magazine

The unit Burgers vectors of perfect grain boundary dislocations, in near coincidence site lattice (c.s.l.) boundaries, are determined for the case of the b.c.c. and f.c.c. structures. The method of Frank for low-angle boundaries is applied to the determination of the dislocation content of a general grain boundary, an…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesMaterial Properties and Failure Mechanisms

Aberration Correction for Increased Lines per Field in Scanning Electron Beam Technology

G. Owen、W. C. W. Nixon1973-11-01Journal of Vacuum Science and Technology

The scanned field performance of probe forming systems has been investigated leading to various methods for increasing the current that may be delivered into an electron probe scanning a square field of 104 lines. Programs for evaluating the third-order aberrations of both lenses and single and double deflection syste…

Advanced Electron Microscopy Techniques and ApplicationsAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Article

Hj. Matzke1973-11-01Le Journal de Physique Colloques

The predominant defects in the fluorite structure are anion vacancies and interstitials. Cation defects occur at a much smaller rate and are therefore more difficult to study. They are, however, of crucial interest since they are rate-determining for many high temperature matter transport processes. Cation diffusion w…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear materials and radiation effects

On Electron Projection Systems

Hans W. P. Koops1973-11-01Journal of Vacuum Science and Technology

Demagnifying EPS have the capacity to generate as much as 5000 line pairs per diameter at a resolution as small as 0.1 μ. The diameter of the recorded image and the maximum number of line pairs per diameter decrease with increasing values of the chromatic field aberrations of the lens system, and with increasing relat…

Advanced Electron Microscopy Techniques and ApplicationsAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Isochronal annealing studies of a plastically deformed ferromagnetic metal using magnetic hysteresis measurements

Frederick Milstein、John A. Baldwin、Timothy W. James1973-11-01Journal of Applied Physics

An experimental study has been made of magnetic hysteresis in plastically deformed and annealed gadolinium (Gd) metal as a function of annealing temperature. Seven plastically deformed samples were annealed at temperatures ranging from 155° to 916°C; major and minor magnetic hysteresis loops of these seven samples plu…

Magnetic properties of thin filmsMicrostructure and Mechanical Properties of SteelsMagnetic Properties and Applications

An Analysis of Three-Dimensional Asymmetric Field Distribution in SF6 Gas Insulated Cables

Takayoshi Misaki、Hideki Yamamoto、K. Itaka1973-11-01IEEE Transactions on Power Apparatus and Systems

An analysis of three-dimensional asymmetric field distribution in SF6 gas insulated cables is shown. The equations to be used in the calculation are derived drecty from Gauss' theorem, and this procedure is quite simple. The field problems in the cables with epoxy pole spacers are solved by digital computer. The solut…

High voltage insulation and dielectric phenomenaThermal Analysis in Power TransmissionOffshore Engineering and Technologies

Optimization of the Performance of High-Brightness Electron Guns

H. Ahmed、Eric Munro1973-11-01Journal of Vacuum Science and Technology

The optimization of the performance of a high-brightness electron gun requires the correct choice of material, and LaB6 has been shown to have advantages over pure metal emitters. The finely pointed tip must be accurately positioned in the grid aperture to achieve maximum brightness and the electrode positions must be…

Electron and X-Ray Spectroscopy TechniquesElectronic and Structural Properties of OxidesSurface and Thin Film Phenomena

The crystal structure of magnesium paratungstate, Mg5H2W12O42-38H2O

T.-H. TSAY、J. V. Silverton1973-11-01Zeitschrift für Kristallographie - Crystalline Materials

Article The crystal structure of magnesium paratungstate, Mg5H2W12O42-38H2O was published on November 1, 1973 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 137, issue 1-6).

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsPigment Synthesis and Properties

A New High-Resolution Electron Probe

A. N. Broers1973-11-01Journal of Vacuum Science and Technology

A new high-resolution electron probe has been built for scanning microscopy studies. The probe has a final lens with a focal length of 0.8 mm, a spherical aberration coefficient; of 0.4 mm, and a chromatic aberration coefficient of 0.5 mm. A lanthanum hexaboride cathode is employed with a maximum brightness of 1.5×107…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

The effect of free silica on the mucosal protective and antiflatulent properties of polydimethylsiloxane

R. D. N. BIRTLEY、J. S. Burton、D. N. KELLETT 等 5 位作者1973-11-01Journal of Pharmacy and Pharmacology

Abstract The mucosal protective and antiflatulent properties of polydimethylsiloxane (PMS) alone, or containing free silica have been examined in rats. Both PMS and PMS + 6% silica significantly protected rat gastric mucosa from the irritant effects of aspirin but there was no significant difference between the protec…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsBiopolymer Synthesis and Applications

Matrix elements of general configuration of nonorthogonalized orbitals in state with definite spin

Ilya G. Kaplan、О. Б. Родимова1973-11-01International Journal of Quantum Chemistry

Abstract The expressions for matrix elements of spin‐independent operators F and G with the use of Young operators are obtained in the case of arbitrary nonorthogonalized orbital configuration, including both singly and doubly filled orbitals and corresponding to the definite value of total spin. The formulas obtained…

Advanced Chemical Physics StudiesCrystal Structures and PropertiesNonlinear Optical Materials Research

Immunosuppression Produced by Lead, Cadmium, and Mercury

Loren D. Koller1973-11-01American Journal of Veterinary Research

SUMMARY Rabbits given lead acetate, cadmium chloride, or mercuric chloride in their drinking water for 70 days and then inoculated with pseudorabies virus (3 doses, 7 days between doses) as antigen had significantly lower neutralizing antibody titers than did the controls. The titers were determined by the plaque assa…

Nanoparticles: synthesis and applicationsAdvanced biosensing and bioanalysis techniquesAdvanced Nanomaterials in Catalysis