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Large Third-Order Optical Nonlinearities of a Croconium Dye in Tetrahydrofuran Solution and in Poly(methyl methacrylate) Coating Films Measured Using Resonant Femtosecond Degenerate Four-Wave Mixing Technique

Zhongyu Li、Zhaohui Jin、Kazuo Kasatani 等 5 位作者2005-07-01Japanese Journal of Applied Physics

Large Third-Order Optical Nonlinearities of a Croconium Dye in Tetrahydrofuran Solution and in Poly(methyl methacrylate) Coating Films Measured Using Resonant Femtosecond Degenerate Four-Wave Mixing Technique, Li, Zhongyu, Jin, Zhao-hui, Kasatani, Kazuo, Okamoto, Hiroaki, Takenaka, Shunsuke

Nonlinear Optical Materials ResearchPhotochemistry and Electron Transfer StudiesNonlinear Optical Materials Studies

Crystallization Behavior of Poly(Trimethylene Terephthalate)/Polycarbonate Blends

Meiling Xue、Yong‐Liang Yu、Jing Sheng 等 4 位作者2005-07-01Journal of Macromolecular Science Part B

The crystallization behavior of poly(trimethylene terephthalate (PTT) in compatibilized and uncompatibilized PTT/polycarbonate (PC) blends are investigated in the research reported in this paper. The differential scanning calorimetry (DSC) results showed that the crystallization behaviors of PTT/PC blends were very se…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Small-angle neutron scattering of dilute polystyrene chains at the protein limit of a colloid-polymer mixture

Thomas Kramer、Ralf Schweins、Klaus Huber2005-07-01The Journal of Chemical Physics

The present work investigates the structure of large polystyrene (PS) chains in solutions of small poly(ethyl methacrylate) (PEMA) microgel particles in toluene. Toluene is a good solvent for the PS chains. The PEMA colloids have an outer radius of R=11 nm which is much smaller in size than the radius of gyration Rg=5…

Proteins in Food SystemsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Porosity-induced effects during C4F8∕90% Ar plasma etching of silica-based ultralow-k dielectrics

P. Lazzeri、Xin‐Min Hua、G. S. Oehrlein 等 6 位作者2005-07-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

We describe time-of-flight secondary ion mass spectrometry (SIMS), depth profiling, and atomic force microscopy studies of nanoporous silica (NPS) ultralow-k (ULK) dielectric films after C4F8∕90% Ar plasma etching. The goal of this work was to establish the role of materials chemistry and porosity on determining the c…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Evaluation of the limits of resonance tunability in metallic nanoshells with a spectral averaging method

Stefan Schelm、Geoffrey B. Smith2005-07-01Journal of the Optical Society of America A

Spectral selectivity based on tuning the surface plasmon resonance in metallic nanoshells by variation of the relative shell thickness is shown to be limited by the interplay between scattering and absorption. To achieve resonance energies in the near infrared and infrared, relatively large cores are needed, which lea…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchThermal Radiation and Cooling Technologies

<title>Thermoelectric properties of bismuth telluride thin films deposited by radio frequency magnetron sputtering</title>

Jack Tan、Kourosh Kalantar‐Zadeh、W. Włodarski 等 7 位作者2005-07-01Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

This paper reports the thermoelectric properties of intrinsic N-type bismuth telluride (Bi<sub>2</sub>Te<sub>3</sub>) thin films (2.5-10 &#956;m thickness). These films were deposited using radio frequency (R.F.) magnetron sputtering. These properties include; Seebeck coefficient and electrical resistivity at differen…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Determination of Molecular Orientation of Uniaxially Stretched Polyamide Fibers by Polarized Infrared Spectroscopy: Comparison of X-Ray Diffraction and Birefringence Methods

Nadarajah Vasanthan2005-07-01Applied Spectroscopy

Polarized infrared (IR) spectroscopy has been used to determine the crystalline and amorphous orientation of polyamide fibers. The transition moment angle of the band at 936 cm-1 of PA66 was determined to be 48 degrees using IR spectroscopy and birefringence measurement. The crystalline orientation of PA66 fibers was…

Polymer crystallization and propertiesTextile materials and evaluationsMaterial Properties and Processing

Nanometer‐Scale Patterning of DNA in Controlled Intervals on a Gold‐Disk Array Fabricated Using Ideally Ordered Anodic Porous Alumina

Futoshi Matsumoto、Masahiro Harada、Kazuyuki Nishio 等 4 位作者2005-07-01Advanced Materials

Ideally ordered DNA nanopatterns have been formed by selectively opening holes in a barrier layer covering gold-filled anodic porous alumina, and then adsorbing thiolated DNA onto the exposed gold nanodisks. Fluorescence microscopy of fluorescent-dye-labeled thiolated DNA fixed on the gold-disk array confirms the sele…

Advanced biosensing and bioanalysis techniquesAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Poly(Ethylene Glycol)-Doxorubicin Conjugates with pH-Controlled Activation

Michal Pechar、Alena Braunová、Karel Ulbrich 等 5 位作者2005-07-01Journal of Bioactive and Compatible Polymers

The synthesis and physico-chemical characterisation of a biodegradable multiblock polymer drug carrier based on poly(ethylene glycol) (PEG) is described. The blocks of PEG ( M w 2,000) are connected by an enzymatically degradable tripeptide derivative consisting of one lysine and two glutamic acid residues. Doxorubici…

Nanoparticle-Based Drug DeliveryRadiopharmaceutical Chemistry and ApplicationsPeptidase Inhibition and Analysis

Epitaxial Pt Films with Different Orientations Grown on (100)Si Substrates by RF Magnetron Sputtering

Shoji Okamoto、Takayuki Watanabe、Kensuke Akiyama 等 6 位作者2005-07-01Japanese Journal of Applied Physics

Epitaxial Pt films with (111) and (100) orientations were grown on Y 2 O 3 -stabilized ZrO 2 (YSZ)-covered (100)Si substrates by RF sputtering. (111)Pt films were epitaxially grown on (100)YSZ∥(100)Si substrates at 580 and 680°C, but competitive crystal orientations of (111) and (100) at 780°C. In contrast, a (100)-or…

Ferroelectric and Piezoelectric MaterialsPerovskite Materials and ApplicationsMicrowave Dielectric Ceramics Synthesis

Netropsin interactions in the minor groove of d(GGCCAATTGG) studied by a combination of resolution enhancement and ab initio calculations

Kristof Van Hecke、Pham Cam Nam、Minh Tho Nguyen 等 4 位作者2005-07-01FEBS Journal

The structure of the complex between the minor groove binder netropsin and d(GGCCAATTGG) was determined via single-crystal X-ray techniques. The structure was refined to completion using refmac5.1.24, resulting in a residual R-factor of 20.0% (including 68 water molecules). Using crystal engineering and cryocooling te…

Protein Structure and DynamicsMonoclonal and Polyclonal Antibodies ResearchEnzyme Structure and Function

Synthesis of PEG/TDI/F6 Adducts and Utilization as Water/Oil Repellents and Oily Stain Release Finishes for Cotton Fabric

M.H. Abo‐Shosha、Z. El-Sayed、H.M. Fahmy 等 4 位作者2005-07-01Polymer-Plastics Technology and Engineering

Four polyethylene glycol (PEG)/2,4-toluene diisocyante (TDI)/ perfluorinated aliphatic alcohols mixture (F6) adducts were prepared by reacting equimolar ratios of PEG (300, 600, 1000, or 2000), TDI, and F6 at 90°C for 90 min. All adducts, except that based on PEG 300 were water dispersible. These dispersions were used…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsTextile materials and evaluations

Sub-Tg dynamics in polycarbonate by neutron scattering and its relation with secondary γ relaxation

S. Arrese-Igor、Arantxa Arbe、Ángel Alegría 等 5 位作者2005-07-01The Journal of Chemical Physics

We have investigated the dynamics of phenylene rings in glassy bisphenol-A (BPA) polycarbonate (PC) by means of quasielastic neutron scattering. Taking advantage of selective deuteration of the samples, we have studied the incoherent scattering of hydrogens in phenylene rings on the one hand, and on the other hand the…

Material Dynamics and PropertiesAdvanced NMR Techniques and ApplicationsNMR spectroscopy and applications

Effect of Processing Parameters on Cellular Structures and Mechanical Properties of PMMA Microcellular Foams

Jin Fu、Choonghee Jo、Hani E. Naguib2005-07-01Cellular Polymers

In this study, the effect of processing parameters on the cellular morphologies and mechanical properties of PMMA microcellular foams is investigated. Microcellular closed cell Poly(methyl-methacrylate) (PMMA) foams were prepared using a two stage batch process method. The foam structure was controlled by altering the…

Polymer composites and self-healingRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Polymeric Scaffolds for Cartilage Tissue Engineering

Wan‐Ju Li、Rocky S. Tuan2005-07-01Macromolecular Symposia

Abstract Polymeric scaffolds are three‐dimensional, porous structures that may be used as a vehicle to deliver cells or therapeutic factors to repair tissue defects. Both biodegradable and non‐biodegradable polymers have been developed for this purpose. In this review, we survey the polymers that have been investigate…

Bone Tissue Engineering MaterialsOsteoarthritis Treatment and MechanismsElectrospun Nanofibers in Biomedical Applications

Synthesis and Characterization of GAP-PEG Copolymers

Y. Murali Mohan、M. Padmanabha Raju、K. Mohana Raju2005-07-01International Journal of Polymeric Materials

A series of glycidylazide–poly(ethylene glycol) (GAP-PEG) copolymers were synthesized by cationic ring-opening polymerization of epichlorohydrin (ECH) in the presence of poly(ethylene glycol) (PEG) using borontrifluoride etherate (BF3-etherate) as catalyst, followed by the conversion of the CH2Cl groups of poly(epichl…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesMembrane Separation and Gas Transport

Effect of nanosize modulation of granular La0.67Sr0.33MnO3 manganites on temperature-dependent low-field spin-polarized tunneling magnetoresistance

P. Dey、T. K. Nath、Uday Kumar 等 4 位作者2005-07-01Journal of Applied Physics

We have investigated magnetotransport behaviors of a series of single-phase, nanocrystalline La0.67Sr0.33MnO3 (LSMO) samples having grain sizes in the nanometric regime (14, 22, and 26 nm), all synthesized through chemical route “pyrophoric reaction process.” The motivation behind the present investigation is to study…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Self‐Assembly of Semifluorinated Janus‐Dendritic Benzamides into Bilayered Pyramidal Columns

Virgil Percec、Mohammad R. Imam、Tushar Kanti Bera 等 6 位作者2005-07-01Angewandte Chemie

Zwei Gesichter: Semifluorierte Janus-dendritische Benzamide bilden supramolekulare pyramidale Doppelschichtsäulen, deren Durchmesser mehr als zweimal so groß sind wie die von Säulen aus Zwillings-dendritischen Benzamiden (siehe Modell). Die Janus-dendritischen Benzamide wurden durch selektives Ersetzen der aliphatisch…

Liquid Crystal Research AdvancementsSupramolecular Self-Assembly in MaterialsDendrimers and Hyperbranched Polymers

The size control of silver nano-particles in SiO2matrix film

Kazuma Kurihara、Carsten Rockstuhl、Takashi Nakano 等 5 位作者2005-07-01Nanotechnology

We provide a fabrication method for silver nano-particles with a uniform particle size using vacuum deposition. The size uniformity was controlled by a small amount of neodymium–copper (Nd–Cu) as a co-sputtered material. Particles with a size of 20 ± 7 nm dispersed in a SiO 2 matrix have been obtained. The full width…

Gold and Silver Nanoparticles Synthesis and ApplicationsCoagulation and Flocculation Studiesnanoparticles nucleation surface interactions

Structure-Activity Correlations for the Oxidation of CO over Polycrystalline RuO2 Powder Derived from Steady-State and Transient Kinetic Experiments

Vijay S. Narkhede、Jens Aßmann、Martin Muhler2005-07-01Zeitschrift für Physikalische Chemie

Abstract The oxidation of carbon monoxide was studied at atmospheric pressure in a plug-flow reactor over polycrystalline ruthenium dioxide powder in the temperature range from 363 to 453 K as a function of the pretreatment. Calcining RuO 2 in flowing oxygen resulted in purified bulk RuO 2 , whereas reduction in hydro…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions