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Dislocation Structures of Duplex Stainless Steel in Uniaxial and Biaxial Cyclic Loading

Martin Petrenec、Véronique Aubin、Jaroslav Polák 等 4 位作者2005-04-15Materials science forum

Austenitic-ferritic duplex stainless steel has been subjected to uniaxial and biaxial nonproportional cyclic loading with the same equivalent strain amplitude. The dislocation structures in specimens fatigued to fracture using both types of loadings were studied and compared. Uniaxial cyclic loading, both in austeniti…

Microstructure and Mechanical Properties of SteelsFatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metals

XRD, SEM/EDX and FTIR Characterization of Brazilian Natural Coral

Herman S. Mansur、Alexandra A.P. Mansur、Marivalda M. Pereira2005-04-15Key engineering materials

In the present work, natural coral from Brazilian reefs were studied according to their crystallography by X-ray diffraction and microstructure by Scanning Electron Microscopy (SEM/EDX). FTIR spectroscopy was also used to evaluate the chemical functionalities and major components present in the material. The SEM morph…

Coral and Marine Ecosystems StudiesCalcium Carbonate Crystallization and Inhibition

Compatibilizer Effect of Grafted Glycidyl Methacrylate on EPDM/Organoclay Nanocomposites

Konstantinos G. Gatos、A. A. Apostolov、J. Karger‐Kocsis2005-04-15Materials science forum

The nanocomposite formation in ethylene/propylene/diene rubber (EPDM) mixed with montmorillonite modified with octadecylamine (MMT-ODA) was investigated. The rubber formulation used proved to be critical for the final materials’ properties. The combined action of the curatives and glycidyl methacrylate (GMA), which wa…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesPolymer Nanocomposite Synthesis and Irradiation

Bonding properties and their relation to residual stress and refractive index of amorphous Ta(N,O) films investigated by x-ray absorption spectroscopy

J. C. Jan、P. D. Babu、H. M. Tsai 等 11 位作者2005-04-15Applied Physics Letters

This work presents N, O K-edge x-ray absorption near-edge structure (XANES) and Ta L3-edge extended x-ray absorption fine structure (EXAFS) studies of amorphous Ta(N,O) films prepared with various flow rate ratios of N2∕O2. The N and O K-edge XANES and Ta L3-edge EXAFS spectra demonstrate the presence of N2 molecules.…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchCopper Interconnects and Reliability

Mechanical Behavior of Nanostructured Aluminum Alloys Containing Quasicrystalline Phase

Yu.V. Milman2005-04-15Materials science forum

Aluminum-based alloys containing quasicrystalline particles of 50 – 600 nm in diameter as a reinforcing phase were produced in the form of powder or ribbons by water atomization or melt spinning techniques, respectively. Rods were compacted from powders and some ribbons by severe plastic deformation without sintering.…

Microstructure and mechanical propertiesMetallic Glasses and Amorphous AlloysQuasicrystal Structures and Properties

New fluorinated thermoplastic elastomers. III. Novel method of synthesis and characterization of alternating fluorinated polyimide/fluorinated polyhybridsiloxane block copolymers via polycondensation

S. André、F. Guida‐Pietrasanta、Alain Rousseau 等 5 位作者2005-04-15Journal of Polymer Science Part A Polymer Chemistry

Abstract The synthesis of fluorinated polyimide/fluorinated polyhybridsiloxane (FPI–FPHSX) block copolymers was achieved through the polycondensation of α,ω‐dichlorosilane fluorinated polyimides and α,ω‐disilanol fluorinated polyhybridsiloxanes. Three FPI–FPHSX block copolymers with 41, 50, and 76 wt % polyimide were…

Synthesis and properties of polymersTribology and Wear AnalysisSilicone and Siloxane Chemistry

CVD diamond devices for charged particle detection

Minglong Zhang、Yiben Xia、Linjun Wang 等 4 位作者2005-04-15Semiconductor Science and Technology

A (1 0 0)-oriented chemical vapour deposited (CVD) diamond film was grown by using a hot-filament chemical vapour deposition technique and then fabricated as an alpha particle detector. The current characteristics indicate a fine Ohmic contact for bias voltage up to 150 V. The dark current and the net current induced…

Diamond and Carbon-based Materials ResearchIon-surface interactions and analysisElectronic and Structural Properties of Oxides

Simulation Of Electrochemical Processes

C. A. Brebbia、V. G. DeGiorgi、R. A. Adey2005-04-15Medical Entomology and Zoology

Section 1: Cathodic protection systems Computer simulation of the interference between a ship's and a dock's cathodic protection systems Zonal ICCP system control interactions Optimum design of cathodic protection using the Boundary Element Method Experimental vs. computational system analysis Numerical 3D BEM simulat…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Separation and Characterization of the Two Diastereomers for [Gd(DTPA-bz-NH2)(H2O)]2-, a Common Synthon in Macromolecular MRI Contrast Agents: Their Water Exchange and Isomerization Kinetics

László Burai、Éva Tóth、Angélique Sour 等 4 位作者2005-04-15Inorganic Chemistry

Chiral, bifunctional poly(amino carboxylate) ligands are commonly used for the synthesis of macromolecular, Gd(III)-based MRI contrast agents, prepared in the objective of increasing relaxivity or delivering the paramagnetic Gd(III) to a specific site (targeting). Complex formation with such ligands results in two dia…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications

Odd−Even Oscillations in First Hyperpolarizability of Dipolar Chromophores: Role of Conformations of Spacers

Ayan Datta、Swapan K. Pati、Daly Davis 等 4 位作者2005-04-15The Journal of Physical Chemistry A

Quantum chemical calculations on the linear and nonlinear electric polarizabilities of dipolar molecules separated by the alkyl spacers have been performed on O(2)N-Ph-N=N-Ph-(CH(2))(n)-Ph-N=N-Ph-NO(2), n = 1-12. These molecules exhibit a very strong odd-even behavior in the first hyperpolarizabilities (beta), with la…

Nonlinear Optical Materials ResearchSynthesis and Properties of Aromatic CompoundsSolid-state spectroscopy and crystallography

Incorporation of chromium into hexagonal barium titanate: an electron paramagnetic resonance study

R. Böttcher、Emre Erdem、H. T. Langhammer 等 5 位作者2005-04-15Journal of Physics Condensed Matter

The EPR spectra of BaTiO 3 +0.04 BaO +0.01 Cr 2 O 3 ceramics are studied in three frequency bands (9, 34 and 94 GHz). Three different, axially symmetric EPR spectra assigned to Cr 3+ ions substituted at Ti sites corresponding to the different distorted octahedra in tetragonal and hexagonal crystal surroundings are obs…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Epitaxial growth of highly coercive Sm–Co thin films using pulsed laser deposition

A. Singh、R. Tamm、V. Neu 等 8 位作者2005-04-15Journal of Applied Physics

Hard magnetic materials with a uniaxial magnetocrystalline anisotropy can be most efficiently used if the easy axis is well aligned along one crystallographic direction in the entire sample volume. Epitaxial growth is one suitable method to achieve this aim and therefore Sm–Co thin films on Cr-buffered single-crystal…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Controlling automotive exhaust emissions: successes and underlying science

M. V. Twigg2005-04-15Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences

Photochemical reactions of vehicle exhaust pollutants were responsible for photochemical smog in many cities during the 1960s and 1970s. Engine improvements helped, but additional measures were needed to achieve legislated emissions levels. First oxidation catalysts lowered hydrocarbon and carbon monoxide, and later n…

Catalytic Processes in Materials ScienceVehicle emissions and performanceAir Quality Monitoring and Forecasting

Size dependence of initial polarization direction in nanosized epitaxial PbTiO3 islands fabricated by hydrothermal epitaxy below Curie temperature

S. H. Ahn、W. W. Jung、Shin-Kyu Choi2005-04-15Applied Physics Letters

Nanosized epitaxial PbTiO3 (PTO) islands with a mono c domain were fabricated via self-assembly on a Nb-SrTiO3 (NSTO) substrate at 160 °C by hydrothermal epitaxy without undergoing the paraelectric to ferroelectric phase transition. The direction of the polarization at the as-fabricated state was observed with an isla…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

A Straightforward Synthesis of Diverse Nickel Dithiolene Complexes Appended with Hydrogen-Bond Donor/Acceptor Groups

Stéphane A. Baudron、Narcis Avarvari、Patrick Batail2005-04-15Inorganic Chemistry

Nickel dithiolene complexes symmetrically appended with hydrogen-bond donor/acceptor functionalities such as imide, amide, or cyano/amide groups have been synthesized by a straightforward method of wide applicability starting from one single precursor. Single-crystal X-ray structures reveal the occurrence of one type…

Perovskite Materials and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research

Magnetostriction in ⟨110⟩ and ⟨112⟩ oriented crystals Tb0.36Dy0.64(Fe0.85Co0.15)2

Tianyu Ma、Chengbao Jiang、Huibin Xu2005-04-15Applied Physics Letters

Magnetostriction of ⟨110⟩ and ⟨112⟩ oriented crystals Tb0.36Dy0.64(Fe0.85Co0.15)2 under various conditions of compressive prestress and applied fields was investigated at room temperature (30°C), elevated temperature (100°C) and cryogenic temperature (−80°C). Obvious magnetostriction jump effect was observed in both ⟨…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Magnetic properties of MnN: Influence of strain and crystal structure

Miguel A. L. Marques、L. K. Teles、L. M. R. Scolfaro 等 6 位作者2005-04-15Applied Physics Letters

For manganese mononitride (MnN), the total energy versus lattice constant is obtained using the spin density functional theory. Instead of the tetragonally distorted NaCl structure, we study the zinc blende and wurtzite structures in which AlN, GaN, and InN crystallize. The ground state with nonmagnetic, antiferromagn…

ZnO doping and propertiesGaN-based semiconductor devices and materialsBoron and Carbon Nanomaterials Research

Ultra-Structural Study of the Laminin-Apatite Composite Layer Formed on Ethylene-Vinyl Alcohol Copolymer by a Biomimetic Process

Ayako Oyane、Masaki Uchida、Yousuke Ishihara 等 4 位作者2005-04-15Key engineering materials

Mechanism of formation of a laminin-apatite composite layer on the surface of an ethylene-vinyl alcohol copolymer (EVOH) using a liquid phase coating process was investigated by transmission electron microscopy (TEM). In this coating process, an EVOH substrate is alternately dipped in calcium and phosphate solutions,…

Cell Adhesion Molecules ResearchPolymer Surface Interaction StudiesSilk-based biomaterials and applications

Experimental measurement of stress at a four-domain junction in lead zirconate titanate

Ian MacLaren、Ljubomira Ana Schmitt、Hartmut Fuess 等 5 位作者2005-04-15Journal of Applied Physics

A junction between two lamellar bands of ferroelectric domains in a lead zirconate titanate ceramic is analyzed using Kikuchi diffraction patterns in the transmission electron microscope. Indexing of the diffraction patterns allowed the determination of the three-dimensional relative orientation of the four different…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisUltrasonics and Acoustic Wave Propagation

Gravimetric and volumetric approaches adapted for hydrogen sorption measurements with in situ conditioning on small sorbent samples

É. Poirier、Richard Chahine、André Tessier 等 4 位作者2005-04-15Review of Scientific Instruments

We present high sensitivity (0 to 1 bar, 295 K) gravimetric and volumetric hydrogen sorption measurement systems adapted for in situ sample conditioning at high temperature and high vacuum. These systems are designed especially for experiments on sorbents available in small masses (mg) and requiring thorough degassing…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies