Materials Literature
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In order to investigate the thermodynamic behavior of t' , t* , and κ phases with the composition, , the equilibrium oxygen partial pressure, p O 2 , over their mixtures with pyrochlore was measured utilizing an electrochemical cell: . The conclusions described below were derived: the thermodynamic stability of the κ…
The wetting behaviour of carbohydrate surfactants bearing siloxane, carbosilane, polysilane or silane moieties has been investigated. By static surface tension (γlv, σ) and wetting tension (γsv−γsl, α) measurements on a non-polar perfluorinated surface (FEP®), the contact angles of aqueous surfactant solutions above t…
The crystal growth of trans -azobenzene (diamagnetism) has been investigated in a magnetic field of 80 kOe. The crystallographic axes are determined by X-ray diffraction and compared with the magnetic axes. The crystals grow so that the magnetic χ 3 axis is parallel to the direction of the field. The orientation is ex…
Thermo- and photo-stimulated luminescence are studied for CsI—Tl crystal after the irradiation with the UV light at 80 K. Creation spectrum of the photostimulated luminescence coincides with the D absorption band of Tl+ ions. Nature of the defects created by UV light at low temperatures is discussed basing on the corr…
Accumulation of collagen produces organ dysfunction in many pathological conditions. We measured the fractional synthesis rate (FSR) of dermal collagen in five human volunteers from the increment of [13C]proline in detergent-soluble dermal collagen hydroxylated to hydroxyproline during a continuous infusion of L-[1-13…
We demonstrate that thin films of thermotropic smectic liquid crystals can be inflated by external pressure to form bubbles similar to lyotropic soap bubbles. These bubbles can be generated with film thickness of a few molecular layers and radii of several centimeters; they are perfectly suited for studies of static a…
K6Sn23Bi2 wurde aus den Elementen in einer verschweißten Niobampulle bei 620 °C hergestellt. Ein Einkristall der Zusammensetzung K6Sn25 konnte durch Umsetzung einer erstarrten Schmelze der nominellen Zusammensetzung „K4Sn9”︁ mit 18Krone6 (1,4,7,10,13,16-Hexaoxacyclooctadecan) bei 45 °C isoliert werden. K6Sn23Bi2 und K…
We present the results of a systematic ac calorimetric study on the smectic-$A$ to nematic ($\mathrm{Sm}\ensuremath{-}A--N$) phase transition for the alkylcyanobiphenyl liquid crystals, 8CB and 9CB, imbedded in the randomly interconnected voids of Millipore cellulose membranes. The confining void size ranged from 5 to…
The stress of Pt films deposited at various temperatures and its correlation with the formation of hillocks during heat treatment were investigated. The residual stress changes from compressive to tensile as the deposition temperature increases. The compressive residual stress of a Pt film deposited at room temperatur…
Nonlinear transient heat conduction in a finite slab with potential-exponential temperature-dependent specific heat and thermal conductivity is investigated numerically by using the network method. A general network model for this process is proposed, whatever the exponent of the temperature-dependent functions may be…
Crystallization mechanism of Ge 2 Sb 2 Te 5 thin films sandwiched between SiN layers was optically investigated and double transition temperatures were observed in the case of Ge 2 Sb 2 Te 5 film thickness of more than 20 nm. The activation energies were estimated by both Kissinger's and Johnson-Mehl-Avrami equations,…
The authors investigated the characteristics of the electromagnetic spectrum caused by partial discharges (PDs) in air at three different types of high-voltage substations. From the measured results, they characterized the electromagnetic noise spectrum depending on the type of substation. They also measured the long-…
Thermal conductivity measurements on porous metal hybride compacts were performed to supplement the limited existing data. These materials are proposed for reactors that are designed for heat-pump applications requiring high specific powers. Previous computational studies have shown that the effective thermal conducti…
Recently, the clinical application of electronic portal imaging devices has enabled more frequent verification of patient setup for radiation treatment. However, the image quality has sometimes proven to be inadequate, motivating the investigation of alternative sensors with better image quality. Amorphous selenium (a…
The first sharp diffraction peak which signifies medium-range structural order in chalcogenide glasses has been studied based on some observations and the construction of ball-and-stick models. The crystalline model originally proposed by Vaipolin and Porai-Koshits provides straighforward explanations for most feature…
The reversible cleavage of indole-3-glycerol by the alpha-subunit of tryptophan synthase has been proposed to be catalyzed by alphaGlu49 and alphaAsp60. Although previous x-ray crystallographic structures of the tryptophan synthase alpha2beta2 complex showed an interaction between the carboxylate of alphaAsp60 and the…
Poly(oxyethylene)s containing n -octylthiomethyl side groups were synthesized by the reaction of poly[oxy(chloromethyl)ethylene] (CE) and sodium n -octanethiolate in DMAc. These were oxidized to poly(oxyethylene)s containing n -octylsulfonylmethyl side groups. When the mole percentage of sulfur containing monomeric un…
Various kinds of alkali-free Ga-substituted MCM-41 catalysts were synthesized. The BET surface area of all catalysts was over 700 m2/g, and the XRD patterns suggested the hexagonal structure. The hexagonal repeat distance was controlled by changing the carbon number of the surfactant. The acid-probe reaction, 2-methyl…
Nine solution‐phase electrochromic thin‐layer cells based on N,N' ‐di‐ n ‐heptylviologen perchlorate, , and N,N,N',N' ‐tetramethyl‐ p ‐phenylenediamine, TMPD (50 mM each in , no supporting electrolyte), were arranged in three rows and three columns, and were matrix‐addressed without crosstalk with six inputs. The abse…
A low concentration of rare earths $(R)$ plays an important role in magnetic materials because of their large anisotropy. However, the Curie temperature ${(T}_{C})$ has a decreasing trend with increasing Fe concentration in $R$-Fe compounds. In order to understand the variation of ${T}_{C}$ as a function of iron conce…