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Isolated ultracold porphyrins in supersonic expansions. III. Free-base porphine

U. Even、Joshua Jortner1982-11-01The Journal of Chemical Physics

The vibrational level structure of the S0→S1x transition (the Qx band) and of the S0→S1y transition (the Qy band) of free-base porphine in supersonic expansions of He was interrogated by laser-induced fluorescence excitation spectroscopy. Electronic relaxation in the S1x manifold was explored by time-resolved spectros…

Porphyrin and Phthalocyanine ChemistryNeonatal Health and BiochemistryHemoglobin structure and function

Short Jute Fiber Reinforced Carboxylated Nitrile Rubber

Samarshi Chakraborty、D. K. Setua、S. K. De1982-11-01Rubber Chemistry and Technology

Abstract Silica is not an essential component in the bonding system in XNBR-jute fiber systems. Mechanical anisotropy is observable only at the higher fiber loadings (40 phr and above) in XNBR-jute fiber composites. In composites containing sufficient amounts of bonding agent and fibers for tensile-strength anisotropy…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

The C‐terminal extrahelical peptide of type I collagen and its role in fibrillogenesis in vitro

Michael J. Capaldi、John A. Chapman1982-11-01Biopolymers

Abstract The formation in vitro of fibrils from type I acid‐soluble calf skin collagen has been studied before and after removal of the extrahelical peptides with carboxypeptidase and with pepsin. Turbidimetric studies show that the mechanism of fibril growth in undigested collagen is similar to that in pepsin‐digeste…

Proteins in Food SystemsEnzyme Production and CharacterizationCollagen: Extraction and Characterization

Residual monomer (Bis‐GMA) of composite resins

K. Inoue、Ichiro Hayashi1982-11-01Journal of Oral Rehabilitation

Summary A method of measuring residual monomer (Bis‐GMA) is described. In addition, the percentage of residual monomer eluted into water from composite resins after setting was compared for several commercial products.

Graphite, nuclear technology, radiation studies

Recent advances in the destabilization of dairy emulsions

Donald F. Darling1982-11-01Journal of Dairy Research

SUMMARY Destabilization of emulsion droplets is described in terms of flocculation, coalescence and adsorption processes, and then discussed with reference to various technological aspects of dairy emulsions. A semi-quantitative measurement of homogenization-induced flocculation of cream is described using measurement…

Proteins in Food SystemsPickering emulsions and particle stabilizationMicroencapsulation and Drying Processes

Investigation of the conformation of elastic chains in poly(dimethylsiloxane) networks by small-angle neutron scattering

Michel Beltzung、Claude Picot、Paul Rempp 等 4 位作者1982-11-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInvestigation of the conformation of elastic chains in poly(dimethylsiloxane) networks by small-angle neutron scatteringM. Beltzung, Claude Picot, P. Rempp, and Jean HerzCite this: Macromolecules 1982, 15, 6, 1594–1600Publication Date (Print):November 1, 1982Publication Hist…

Conducting polymers and applicationsPolymer composites and self-healingLuminescence and Fluorescent Materials

Theory and application of highly magnetoelastic Metglas 2605SC (invited)

H. T. Savage、Mark L. Spano1982-11-01Journal of Applied Physics

We show by a variety of experiments that the magnetomechanical coupling k in Metglas 2605SC has larger values than in any other device material. Our Mössbauer experiments show that the anisotropy axis is quite well defined when compared with Metglas 2605CO. The small value of the anisotropy and the well defined axis l…

Shape Memory Alloy TransformationsMultiferroics and related materialsMagnetic Properties and Applications

Simulation of the (001) plane crack in α-iron employing a new boundary scheme

Mayes Mullins、M. A. Dokainish1982-11-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

A new boundary scheme for atomic-level computer simulations in solid mechaisms has been developed which is based on the finite-element method and which provides several advantages over previous boundary schemes. This has been applied to the simulation of (001) plane two-dimensional cracks in ac-Fe having crack line di…

Microstructure and mechanical propertiesHigh Temperature Alloys and CreepIntermetallics and Advanced Alloy Properties

Syntheses and crystal and molecular structures of hexaaquaruthenium(II) p-toluenesulfonate and hexaaquaruthenium(III) p-toluenesulfonate, [Ru(H2O)6](C7H7SO3)2 and [Ru(H2O)6](C7H7SO3)3.3H2O

Paul Bernhard、Hans Beat Buergi、J. Häuser 等 5 位作者1982-11-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSyntheses and crystal and molecular structures of hexaaquaruthenium(II) p-toluenesulfonate and hexaaquaruthenium(III) p-toluenesulfonate, [Ru(H2O)6](C7H7SO3)2 and [Ru(H2O)6](C7H7SO3)3.3H2OPaul Bernhard, Hans Beat Buergi, Juerg Hauser, Hans Lehmann, and Andreas LudiCite this:…

Crystal structures of chemical compoundsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Dependence of Fracture Toughness of Alumina on Grain Size and Test Technique

Bernhard Mussler、Michael V. Swain、Nils Claussen1982-11-01Journal of the American Ceramic Society

The fracture toughness ( K Ic ) of sintered alumina was measured using notched beam (NB) and indentation/strength‐in‐bending (ISB) techniques. K Ic (NB) decreases with increasing grain size. For fine‐grained materials (<5 μ m ), NB results overestimate K Ic , and exhibit a substantial notch‐radius sensitivity. A st…

Advanced ceramic materials synthesisHigh-Velocity Impact and Material BehaviorAdvanced materials and composites

Atomic Structure of Amorphous Metallic Ni81B19

P. Lamparter、W. Sperl、S. Steeb1982-11-01Zeitschrift für Naturforschung A

The three partial Faber Ziman structure factors as well as the Bhatia Thornton structure factors of the metallic glass Ni 81 B 19 were evaluated by neutron diffraction experiments using the isotopic substitution method. In one of the investigated specimens the isotopic composition of the components was adjusted in suc…

Glass properties and applicationsMetallic Glasses and Amorphous AlloysMineralogy and Gemology Studies

Band structure, intercalation, and interlayer interactions of transition-metal dichalcogenides: TiS2and LiTiS2

C. J. Umrigar、D. E. Ellis、Ding-Sheng Wang 等 5 位作者1982-11-01Physical review. B, Condensed matter

The layered structure dichalcogenide Ti${\mathrm{S}}_{2}$ was studied in thin-film and bulk models, with the use of the self-consistent linearized augmented-plane-wave (LAPW) scheme. Band-structure calculations were performed on the single sandwich (S-Ti-S), the double sandwich ${(\mathrm{S}\ensuremath{-}\mathrm{T}\ma…

2D Materials and ApplicationsIron-based superconductors researchInorganic Chemistry and Materials

Effect of annealing on the secondary relaxations in glasses

G. P. Johari1982-11-01The Journal of Chemical Physics

The dielectric loss in a rigid-molecular glass (toluene–pyridine) and in poly(propylene oxide) has been measured from 50 to 2×105 Hz during the course of isothermal annealing at several temperatures. The decrease in the loss on annealing is predominantly due to a decrease in the number of molecules participating in th…

Material Dynamics and PropertiesGlass properties and applicationsThermodynamic properties of mixtures

Neurotoxicity of iohexol: a new nonionic contrast medium.

R. Nick Bryan、Ricardo Silva Centeno、Norman Hershkowitz 等 5 位作者1982-11-01Radiology

The neurotoxicity of iohexol was evaluated and compared with the neurotoxicity of sodium diatrizoate, meglumine iothalamate, and metrizamide. Direct neurotoxicity was evaluated with in vitro rat hippocampal slices, and angiographic neurotoxicity was studied in a cat's spinal cord following thoracic aortography. In the…

Intracranial Aneurysms: Treatment and ComplicationsTraumatic Brain Injury and Neurovascular DisturbancesLanthanide and Transition Metal Complexes

Stress‐Induced Transformation During Subcritical Crack Growth in Partially Stabilized Zirconia

L. K. Lenz、A. H. Heuer1982-11-01Journal of the American Ceramic Society

Fracture surfaces of a commercial partially stabilized ZrO 2 that had undergone subcritical crack growth in H 2 0 were characterized by scanning and transmission electron microscopy. At high stress intensities (≥4.6 MPa·m −1/2 ), fracture was primarily trans granular, and coherent tetragonal ZrO 2 precipitates had und…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Determination of Trapping Parameters from TSC in Polyethylene

Teruyoshi Mizutani、Yasuo Suzuoki、Masahiro Hanai 等 4 位作者1982-11-01Japanese Journal of Applied Physics

The trapping parameters of one of the carrier traps in low-density polyethylene were evaluated by using the X-ray-induced thermally-stimulated current (TSC) technique. The values obtained were E t (trap depth): 0.90 eV, µτ (product of mobility and lifetime): 5×10 -13 m 2 /V and n to (initial density of trapped carrier…

High voltage insulation and dielectric phenomenaElectron and X-Ray Spectroscopy TechniquesNon-Destructive Testing Techniques

A checklist of freshwater algae of the Northwest Territories, Canada

Robert G. Sheath、Alan D. Steinman1982-11-01Canadian Journal of Botany

A checklist of the freshwater algae from the Northwest Territories has been compiled to add to an algal flora of Canada. The 44 studies included report on 279 bodies of water. A large diversity of algal communities has been examined in these investigations, such as phytoplankton and periphyton in permanent and tempora…

Aquatic Ecosystems and Phytoplankton DynamicsMarine and coastal plant biologyDiatoms and Algae Research

Paracrystalline Disorder of Biological and Synthetic Carbonate-substituted Apatites

D.G.A. Nelson、J.D.B. Featherstone、J. F. Duncan 等 4 位作者1982-11-01Journal of Dental Research

Paracrystalline disorder, a type of lattice imperfection which results in a loss of long-range crystalline order, was assessed in a range of biological and synthetic apatites using x-ray diffraction data. Carbonate substitution in the apatite lattice increased the amount of paracrystalline disorder in synthetic precip…

Crystallography and molecular interactionsEnzyme Structure and FunctionX-ray Diffraction in Crystallography

Oscillatory behavior of a gas bubble growing (or collapsing) in viscoelastic liquids

Hee Ju Yoo、Chang Dae Han1982-11-01AIChE Journal

Abstract A theoretical study was carried out to achieve a better understanding of the oscillatory behavior of a gas bubble growing (or collapsing) in a viscoelastic liquid, by taking into account both the hydrodynamic and diffusion effects. The Zaremba‐DeWitt model was chosen to represent the rheological properties of…

Fluid Dynamics and MixingLattice Boltzmann Simulation StudiesUltrasound and Cavitation Phenomena

Effect of Reinforcing Silica on Vulcanization, Network Structure, and Technical Properties of Natural Rubber

Parthajit Pal、S. K. De1982-11-01Rubber Chemistry and Technology

Abstract Reinforcement of silica filler in NR in the presence of a silane coupling agent (Si-69), and an additive (TEA) has been analyzed by studies on swelling of the vulcanizate, network structure, technical properties, and scanning electron micrographs. Failure properties in the presence of a coupling agent have be…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersTribology and Wear Analysis