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Viscoelastic And Electrohydrodynamic Behavior Of Thin Free-Standing Liquid Crystal Films

R. Pindak1989-08-15Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Optical experiments on free-standing liquid crystal films which address the issues of structural ordering, fluctuations in two dimensions and enhanced surface ordering will be reviewed. Also, results on a novel electrohydrodynamic mode will be presented.

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Melt-spun Nd2(CoxFe1−x)14B systems: Optimization of the hard magnetic properties

C. D. Fuerst、J. F. Herbst1989-08-15Journal of Applied Physics

By appropriate variation of starting composition we demonstrate that melt-spun materials comprised primarily of Nd2(CoxFe1−x)14B and having optimum energy products can be prepared. Twelve cobalt concentrations spanning the entire cobalt substitution range have been investigated. We report ambient as well as elevated t…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Picosecond photoinduced exciton bleaching in emeraldine base: Crossover in decay mechanisms

M. G. Roe、J. M. Ginder、Terry L. Gustafson 等 6 位作者1989-08-15Physical review. B, Condensed matter

We report picosecond photoinduced bleaching (PB) of the exciton absorption of the emeraldine base form of polyaniline. The temperature- (T-) independent dispersive decay, \ensuremath{\sim}${t}^{\mathrm{\ensuremath{-}}0.11}$, observed in this study differs markedly from the dynamics of earlier studied semiconductors. I…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsElectron Spin Resonance Studies

Free-surface velocity measurement of shock-compressed alumina powder compact using a Fabry–Perot interferometer

Takashi Taniguchi、H. Yasuo、Ken‐ichi Kondo 等 4 位作者1989-08-15Journal of Applied Physics

A Fabry–Perot interferometer system was used to measure the free-surface velocity of α-alumina powder compact. In situ pressure profile measurements using a pair of manganin gauges were also carried out to clarify the compaction process during compression and stress release. The Fabry–Perot system indicates that the r…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsEnergetic Materials and Combustion

Hydrogen as a local probe: Diffusion and short-range order inTi1−yVyalloys

R. C. Brouwer、J. H. Rector、N. J. Koeman 等 4 位作者1989-08-15Physical review. B, Condensed matter

Diffusion coefficients of hydrogen have been measured in disordered ${\mathrm{Ti}}_{1\mathrm{\ensuremath{-}}\mathrm{y}}$${\mathrm{V}}_{\mathrm{y}}$ alloys, as a function of temperature, hydrogen concentration, and alloy composition. Diffusion and electron microprobe analysis data indicate the existence of short-range…

Hydrogen embrittlement and corrosion behaviors in metalsIntermetallics and Advanced Alloy PropertiesNuclear Materials and Properties

Structural and electronic structural properties of ordered LiAl compounds

Xin Guo、R. Podloucky、A. J. Freeman1989-08-15Physical review. B, Condensed matter

Precise results of first-principles electronic-structure calculations of the structural and electronic properties of the binary compound LiAl are presented for the bcc-based B32 and B2 crystal structures, the fcc-based L${1}_{0}$ and the simple-cubic-based B1 structures as obtained with the full-potential linearized a…

Intermetallics and Advanced Alloy PropertiesBoron and Carbon Nanomaterials ResearchSuperconductivity in MgB2 and Alloys

The effects of cross-linking on the equation of state of a polymer solution

Ferenc Horkay、A. M. Hecht、Erik Geissler1989-08-15The Journal of Chemical Physics

Measurements of the swelling pressure ω̄ and shear modulus Gs in a set of poly(vinyl acetate) networks swollen to different degrees in toluene and in acetone are reported, using solutions of the uncross-linked polymer to obtain deswelling under known conditions of osmotic pressure. The swelling pressure can be complet…

Hydrogels: synthesis, properties, applicationsPhase Equilibria and ThermodynamicsPolymer Nanocomposites and Properties

Weak localization in pregraphitic carbon fibers

V. Bayot、Luc Piraux、J.-P. Michenaud 等 4 位作者1989-08-15Physical review. B, Condensed matter

High-resolution resistivity and magnetoresistance measurements have been performed as a function of temperature on pregraphitic carbon fibers. The resistivity exhibits a negative temperature coefficient (d\ensuremath{\rho}/dT<0) from room temperature down to 1.5 K. It is shown that such behavior can hardly be expla…

Graphene research and applicationsQuantum and electron transport phenomenaThermal properties of materials

Simulation of aggregating colloids in shear flow. II

D. Chen、Masao Doi1989-08-15The Journal of Chemical Physics

Three-dimensional computer simulation is carried out for the aggregation process of colloids using the sticky sphere model proposed in the previous paper. Time evolution of the structure of aggregates and macroscopic viscosity is studied when a shear flow is started in a suspension of the sticky spheres. In the transi…

Material Dynamics and PropertiesCoagulation and Flocculation StudiesRheology and Fluid Dynamics Studies

Solitary Tilt Waves in Thin Lamellar Eutectics

G Faivre、Suzanne de Cheveigné、C. Guthmann 等 4 位作者1989-08-15Europhysics Letters (EPL)

During directional solidification of thin layers (50 μm) of the transparent CBr 4 -C 2 Cl 6 lamellar eutectic alloy, we observed tilt waves, a type of instability consisting in small domains of tilted lamellae moving transversely along the growth front. This instability is a way the system adjusts its wavelength after…

Cold Atom Physics and Bose-Einstein CondensatesSolidification and crystal growth phenomenaAcoustic Wave Resonator Technologies

Thermal line broadening in small metal clusters

G. F. Bertsch、David Tománek1989-08-15Physical review. B, Condensed matter

Plasmon broadening in small metal clusters is calculated using the jellium model. We find that thermal fluctuations in the shape of the cluster could be a significant source of broadening of the Mie resonance. The shape fluctuation mechanism makes definite predictions for the shape of the resonance line, its temperatu…

Advanced Chemical Physics StudiesGold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactions

Photochemistry of oriented molecules coadsorbed on solid surfaces: The formation of CO2+O from photodissociation of O2 coadsorbed with CO on Pt(111)

W. D. Mieher、W. Ho1989-08-15The Journal of Chemical Physics

Measurement of a photoinduced reaction involving two types of molecular species coadsorbed with well-defined configurations on a solid surface is reported. The photoinduced reaction, occurring on Pt(111) at 100 K, is O2+CO+hν→O+{O→CO}→O+CO2. A mechanism involving photochemically produced hot O atoms (with high transla…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Molecular orientational correlation in liquid halogens

Masakatsu Misawa1989-08-15The Journal of Chemical Physics

The characteristic features of structure factor Sm(Q) of liquid halogens F2, Cl2, Br2, and I2 have been discussed in terms of preferred orientational correlations introduced between the nearest neighbors. The orientational correlations estimated directly from the experimental Sm(Q)’s of these liquids are rather simila…

Solid-state spectroscopy and crystallographyCrystallization and Solubility StudiesThermodynamic and Structural Properties of Metals and Alloys

Imperfections in amorphous chalcogenides. IV. A model of electrical conduction processes in amorphous and crystallineIn2Se3

Yuichi Watanabe、Shuichi Kaneko、Hiroshi Kawazoe 等 4 位作者1989-08-15Physical review. B, Condensed matter

Electrical conduction in amorphous ${\mathrm{In}}_{\mathrm{x}}$${\mathrm{Se}}_{100\mathrm{\ensuremath{-}}\mathrm{x}}$ (a-${\mathrm{In}}_{\mathrm{x}}$${\mathrm{Se}}_{100\mathrm{\ensuremath{-}}\mathrm{x}}$) thin films is examined, where x ranges from 35 to 44. Models of electrical conduction processes in both crystallin…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Structure of monoclinic chloro(meso-tetraphenylporphyrinato)iron(III)

W. Robert Scheidt、Michael G. Finnegan1989-08-15Acta Crystallographica Section C Crystal Structure Communications

[FeCl(C44H28N4)], Mr = 704.03, monoclinic, P21/n, a = 10.254 (2), b = 15.969 (3), c = 20.810 (4) A, beta = 90.48 (2) degree, V = 3407.7 A3, Z = 4, Dx = 1.37 g cm-3, Mo K alpha, lambda = 0.71073 A, mu = 5.6 cm-1, F(000) = 363, T = 293 K, R = 0.047 for 3357 unique observed reflections. The iron(III) ion is coordinated t…

Metal complexes synthesis and propertiesMolecular Sensors and Ion DetectionPorphyrin and Phthalocyanine Chemistry

Optical properties of gallium selenide under high pressure

M. Gauthier、A. Polian、Jean Besson 等 4 位作者1989-08-15Physical review. B, Condensed matter

Compressibility, optical-absorption, Raman-scattering, and refractive-index measurements for GaSe are reported at 300 K and pressures up to 8 GPa. A model which separates intra- and interlayer contributions along the c axis is used, with adequate deformation potentials, to quantitatively reproduce the compressibility…

High-pressure geophysics and materialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Ferromagnetic and antiferromagnetic intermolecular interactions of organic radicals, α-nitronyl nitroxides. II

Kunio Awaga、Yusei Maruyama1989-08-15The Journal of Chemical Physics

The temperature dependence of the magnetic susceptibilities and the magnetizations for the three kinds of α-nitronyl nitroxides, 2-R-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy 3-oxide [with R=phenyl (I), 3-nitrophenyl (II), 4-nitrophenyl (III)] have been measured. It is found that the intermolecular spin inte…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Modeling of plasma-induced self-healing in organic dielectrics

J. Kammermaier、G. Rittmayer、S. Birkle1989-08-15Journal of Applied Physics

Plasma-induced self-healing in organic dielectrics, which is of extremely great importance for capacitor technology, is dependent, in a complicated manner, upon electrical and physicochemical processes, which cannot be determined by metrology. Accordingly, a theoretical model was developed which describes the spatiote…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAnalytical Chemistry and Sensors

Fast linear electro-optic effect based on cholesteric liquid crystals

Jay Patel、Sin‐Doo Lee1989-08-15Journal of Applied Physics

Flexoelectric effect in cholesteric liquid crystals can be used to produce optical switching on a microsecond time scale. In a simple geometry, this effect produces a light modulation the amplitude of which is linear in field. The switching time from one optical state to the other is predicted to be independent of the…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationPlant Reproductive Biology

Optical spectroscopy of extrinsic recombinations in gallium selenide

V. Capozzi、M. Montagna1989-08-15Physical review. B, Condensed matter

Luminescence at energy lower than the absorption edge has been investigated in crystals of GaSe, containing different degrees of lattice disorder, as a function of temperature, of photoexcitation intensity, and of excitation energy. At low excitation intensity, the extrinsic luminescence is composed of broad overlappi…

Advanced Chemical Physics StudiesPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography