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FT‐Raman and FT‐IR spectroscopic study of synthetic Mg/Zn/Al‐hydrotalcites

J. Theo Kloprogge、Leisel Hickey、Ray L. Frost2004-09-02OpenAlex

Abstract Synthetic Mg/Zn/Al‐hydrotalcites with atomic ratios of 6:0:2, 4:2:2, 2:4:2 and 0:6:2 were characterized by FT‐Raman and FT‐IR spectroscopy. ‘AlOH’ IR translation modes are observed at 419, 427, 559, 616 and 771 cm −1 with two corresponding Raman bands at 465–477 and 547–553 cm −1 . ‘MgOH’ IR translation mod…

Layered Double Hydroxides Synthesis and ApplicationsMicrowave Dielectric Ceramics SynthesisMagnesium Oxide Properties and Applications

Magic Polyicosahedral Core-Shell Clusters

Giulia Rossi、Arnaldo Rapallo、C. Mottet 等 6 位作者2004-09-02OpenAlex

A new family of magic cluster structures is found by genetic global optimization, whose results are confirmed by density functional calculations. These clusters are Ag-Ni and Ag-Cu nanoparticles with an inner Ni or Cu core and an Ag external shell, as experimentally observed for Ag-Ni, and present a polyicosahedral ch…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applicationsnanoparticles nucleation surface interactions

Bottom-Up and Top-Down Approaches to the Synthesis of Monodispersed Spherical Colloids of Low Melting-Point Metals

Yuliang Wang、Younan Xia2004-09-02OpenAlex

We report two different, solution-based approaches that have allowed us to process metals with melting points below 400 °C as monodispersed spherical colloids, in copious quantities, and with diameters controllable in the range of 100 to 600 nm. Bismuth was selected as a typical example to demonstrate the concepts. Th…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And Propertiesnanoparticles nucleation surface interactions

Macroscopic, Neat, Single-Walled Carbon Nanotube Fibers

Lars M. Ericson、Hua Fan、Haiqing Peng 等 24 位作者2004-09-02OpenAlex

Well-aligned macroscopic fibers composed solely of single-walled carbon nanotubes (SWNTs) were produced by conventional spinning. Fuming sulfuric acid charges SWNTs and promotes their ordering into an aligned phase of individual mobile SWNTs surrounded by acid anions. This ordered dispersion was extruded via solution…

Carbon Nanotubes in CompositesGraphene research and applicationsFiber-reinforced polymer composites

Response to Comment on “Catalysis and Temperature Dependence on the Formation of ZnO Nanoparticles and of Zinc Acetate Derivatives Prepared by the Sol−Gel Route”

Valérie Briois、Miriam Sanae Tokumoto、Sandra H. Pulcinelli 等 4 位作者2004-09-01The Journal of Physical Chemistry B

ADVERTISEMENT RETURN TO ISSUEPREVCommentResponse to Comment on "Catalysis and Temperature Dependence on the Formation of ZnO Nanoparticles and of Zinc Acetate Derivatives Prepared by the Sol−Gel Route"V. Briois, M. S. Tokumoto, S. H. Pulcinelli, and C. V. SantilliView Author Information LURE, Centre Universitaire Pari…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesGas Sensing Nanomaterials and Sensors

Orientation Control of Vanadylphthalocyanine Molecules Deposited on Pt (111) and Au (111) Surfaces

Yonglong Jin、Goro Sawa、Yoshiyuki Uchida 等 7 位作者2004-09-01Japanese Journal of Applied Physics

Vanadylphthalocyanine (VOPc) thin films were prepared on Au (111) and Pt (111) substrates by molecular beam epitaxy. VOPc molecules deposited on the Au (111) substrate orientated parallel to the substrate surface, and grew epitaxially on the substrate surface whose temperature was maintained at 200°C. On the other han…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresSurface Chemistry and Catalysis

Corrosion behaviour of steel ropes for snow and rockfall barriers

F. Deflorian、Stefano Rossi、B. Tancon 等 4 位作者2004-09-01Corrosion Engineering Science and Technology The International Journal of Corrosion Processes and Corrosion Control

During service, steel ropes can suffer from corrosion, which can reduce their mechanical properties. This degradation is particularly important in the case of structural ropes, or barriers, for snow and rockfall protection because it is not easy to detect any significant degradation over time due to the locations of t…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityMechanical stress and fatigue analysis

Relaxor-Like Properties and Anomalous Phase Boundaries in Mixed Crystals Rb1-x(NH4)xH2PO4

Eiko Matsushita、Yuuto Shinkai2004-09-01Japanese Journal of Applied Physics

In order to search for relaxor ferroelectrics or relaxor antiferroelectrics in Pb-free substances, a theoretical approach is presented for hydrogen-bonded mixed crystals under conditions similar to those for relaxor perovskite oxides. On the basis of the theory for local resonance techniques proposed by one of the pre…

Glass properties and applicationsSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

Problems in crystal chemistry of ferroelectric and antiferroelectric perovskites PbB′0.5B″0.5O3

В. А. Исупов2004-09-01Crystallography Reports

The most interesting problems in the crystal chemistry of ferroelectric and antiferroelectric perovskites PbB 0.5 ′ B 0.5 ″ O3 are considered. The properties and specific features of perovskites (such as the smearing of ferroelectric phase transitions, relaxor state, ferroelectric-antiferroelectric transformations, an…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Mechanical Properties of Carbon Nanotubes Composites

David Hui、Mircea Chipara、Jagannathan Sankar 等 4 位作者2004-09-01Journal of Computational and Theoretical Nanoscience

A critical review of theoretical models aiming to explain the physical properties of composites based on polymeric matrices reinforced with carbon nanotubes is presented. Attention is paid to descriptions based on molecular dynamics, continuum mechanics, and finite element analysis. It is shown that both the continuum…

Carbon Nanotubes in CompositesTribology and Wear AnalysisNanotechnology research and applications

Caracterização de biopolímeros produzidos por Beijerinckia sp. 7070 em diferentes tempos de cultivo

Caroline Dellinghausen Borges、Ângela Nunes Moreira、Angelita da Silveira Moreira 等 5 位作者2004-09-01Food Science and Technology

Biopolímeros são polissacarídeos microbianos. O biopolímero produzido por Beijerinckia sp. 7070 possui comportamento pseudoplástico e apresenta alta viscosidade em baixas velocidades de deformação, conferindo ao polímero excelentes características de suspensão. O objetivo desse trabalho foi caracterizar o biopolímero…

biodegradable polymer synthesis and propertiesEnzyme Production and CharacterizationPolysaccharides Composition and Applications

Removal of ungrafted monomer from polypropylene‐graft‐maleic anhydride via supercritical carbon dioxide extraction

Kelly Clark、Sunggyu Lee2004-09-01Polymer Engineering and Science

Abstract The removal of spent initiator, excess initiator and unbound monomer from newly synthesized polypropylene‐graft‐maleic anhydride (PP‐g‐MA) has typically been carried out using Soxhlet extraction. Standard solvents used in the Soxhlet process are xylene, toluene, acetone or methanol. These chemicals are not on…

Polymer crystallization and propertiesInjection Molding Process and PropertiesPolymer Foaming and Composites

Excitons and defects in homoepitaxial diamond films from cathodoluminescence of p–/p+ samples

Mamadou Wade、Mohamed Kadri、E. Bustarret 等 6 位作者2004-09-01physica status solidi (a)

We study the signals from excitons and defects from the cathodoluminescence spectra (CL) of the p–/pseudo substrate sample. The CL from the p– film are determined from the variation of the CL of the sample as the voltage of the exciting electron beam increases. At the lower voltages, it probes the p– film. The CL is d…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Optical rectification effect in nanocarbon films

G. M. Mikheev、R. G. Zonov、A. N. Obraztsov 等 4 位作者2004-09-01Technical Physics Letters

When a nanocarbon film obtained by plasmachemical deposition is fixed between two parallel electrodes and exposed to the pulsed radiation of a Q-switched neodymium laser, a pulsed electric voltage appears between the electrodes, with the pulse shape repeating the laser pulse envelope. It is shown that the amplitude an…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchSilicon Nanostructures and Photoluminescence

Short-and long-range order effects on resonance energy transfer in crystals and glasses

Mário N. Berberan‐Santos、Е. Н. Бодунов2004-09-01Optics and Spectroscopy

Resonance energy transfer by the Förster-Dexter mechanism in a cubic crystal and in a rigid homogeneous medium is studied. The homogeneous medium is modeled using a hard-sphere fluid (HSF) radial distribution function. This distribution is more realistic than the commonly used uniform distribution with excluded volume…

Glass properties and applicationsPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

ZnO films deposited by RF magnetron sputtering

Liqiang Jing、Suntao Wu、Junyong Kang2004-09-01OpenAlex

ZnO nano films were deposited on p-Si(100) with different pre-deposited buffer layers by RF magnetron sputtering system under different processing conditions. The film surface morphology and crystal structure were characterized by scanning electron microscopy, atomic force microscopy, and X-ray diffraction. The result…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Antiplane electro‐mechanical field of a piezoelectric finite wedge under a pair of concentrated forces and free charges

Ching‐Hwei Chue、Wei‐Ju Liu2004-09-01Journal of the Chinese Institute of Engineers

This paper presents general antiplane electro‐mechanical field solutions for a piezoelectric finite wedge subjected to a pair of concentrated forces and free charges. The boundary conditions on the circular segment are considered as traction free and insulated. Using finite Mellin transform methods, the stress and ele…

Fluid Dynamics Simulations and InteractionsHigh-Velocity Impact and Material BehaviorElasticity and Wave Propagation

Effects of β-Glucans, Shearing, and Environmental Factors on Wort Filtration Performance

Yu-Lai Jin、R. Alex Speers、A.T. Paulson 等 4 位作者2004-09-01Journal of the American Society of Brewing Chemists

A model filtration device with diatomaceous earth (DE) as a filter bed was used to investigate the effects of β-glucans, wort pH, maltose concentration, shearing, and shearing temperature on the efficiency of wort filtration at 76°C. A 0.45-μm membrane filtration of wort was performed at 20°C as an alternative test. H…

Food composition and propertiesAdvanced Cellulose Research StudiesWound Healing and Treatments

Characteristics of degummed ramie fibre and its cotton blended yarns

Mohammad Tofayel Ahmed、Shyamal Kumar Chattopadhyay、A K Chaphekar 等 5 位作者2004-09-01OpenAlex

Ramie is a strong and lustrous bast fibre obtained from the inner bark of Boehmeria nivea (L) Gaud. The fibres are embedded in the cells of bast that lies between the outer bark and the woody core of the stem. The spinnable fibres are obtained by decOltication and degumming. It is not normally possible to spin the fib…

Natural Fiber Reinforced CompositesTextile materials and evaluations

An Integrated Approach to Analyzing the Nature of Multicomponent Fiber Blending

Y.E. El Mogahzy、Ramsis Farag、Faissal Abdel-Hady 等 4 位作者2004-09-01Textile Research Journal

In this part of our study, we report the results of an experimental analysis of the structural and attributive blending modes discussed in Part I. This analysis results in a number of interesting findings relevant to the nature of multiple-component fiber blends. In the case of cotton/cotton blends, cotton fibers of s…

Textile materials and evaluations