Materials Literature
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The complexes present in freshly-prepared solutions containing cobalt(II) and cyanide ions have been investigated. The main complex is identified as the hexaco-ordinate [Co(CN)5H2O]3– by comparison of its spectrum with those of the analogous isocyanide complexes. No evidence was found for the hexacyanide [Co(CN)6]4– u…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelf-diffusion in simple fluidsJohn A. Palyvos and Howard Ted DavisCite this: J. Phys. Chem. 1967, 71, 2, 439–444Publication Date (Print):January 1, 1967Publication History Published online1 May 2002Published inissue 1 January 1967https://pubs.acs.org/doi/10.1021/j100861a037…
Get PDF Email Share Share with Facebook Tweet This Post on reddit Share with LinkedIn Add to CiteULike Add to Mendeley Add to BibSonomy Get Citation Copy Citation Text D. A. Holmes, "On the Calculation of Thin Film Refractive Index and Thickness by Ellipsometry," Appl. Opt. 6, 168-169 (1967) Export Citation BibTex End…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTKinetics of calcium oxalate pyrolysisF. E. Freeberg, Kenneth Owen Hartman, Isamu C. Hisatsune, and John M. SchempfCite this: J. Phys. Chem. 1967, 71, 2, 397–402Publication Date (Print):January 1, 1967Publication History Published online1 May 2002Published inissue 1 January 1…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTKinetics of oxalate ion pyrolysis in a potassium bromide matrixKenneth Owen Hartman and Isamu C. HisatsuneCite this: J. Phys. Chem. 1967, 71, 2, 392–396Publication Date (Print):January 1, 1967Publication History Published online1 May 2002Published inissue 1 January 1967https…
Density (and some viscosity) data are presented for binary sodium borate melts containing as much as 60 mole % Na 2 O and for ternary sodium silicoborate melts with B/Si <2.0 between 1000°C and 1300°C. The high‐temperature partial molar volume analysis of the binary sodium borate melts reveals about 50% BO 4 tetrah…
Abstract Two high purity Al foils of thickness 40 μm and 5.6 μm are simultaneously irradiated. The initial resistivity increments per unit defect concentration for the foils differ by a factor of two due to the size effect. Sondheimer's theory is in good agreement with the experimental data. The calculations are prese…
Author: Zwick, Peter; Genre: Journal Article; Published in Print: 1967; Title: Beschreibung der aquatischen Larve von Neurorthus fallax (Rambur) und Errichtung der neuen Planipennierfamilie Neurorthidae fam. nov.
Abstract Deformation processes in polymers are reviewed within the framework of rubber elasticity theory. The effect of hindered rotation on imposed and spontaneous length changes of polymeric fibers is discussed, leading to a new definition of crystallinity as a localized region of hindered rotation. This concept, to…
A hard-sphere model analogue of undirectional crystal growth has been devised and used to measure quantitatively the rates of growth normal to (111) and (100) planes in a face-centred cubic crystal structure. It has been found that 〈111〉 growth is much faster than 〈100〉 growth, and the result is interpreted in terms o…
Methods have been developed for growing thin polycrystalline films, and oriented polycrystalline films. Experiments with the thin films allow measurement of the absorption spectra of the N-salicylideneanilines well into the ultraviolet, and thus permit comparison of the effects of temperature change on the “thermochro…
Abstract Calculations of characteristic energy losses of electrons in thin dielectric foils are given for a) electrons with inclined incidence to the foil, b) electrons travelling parallel to the foil surface. Retardation is taken into account for case b) in the limit of very thick foils. For the special case in which…
The kinetics of the formation of zinc ferrite from zinc oxide and iron(III) oxide powders have been studied. Below about 1000°C Jander's equation is obeyed. Vaporization of the more mobile reactant (ZnO) occurs to form a coating on the particles of the other reactant with subsequent diffusion into it. An activation fr…
The isolation of complexes of stoicheiometry [Fe2B4O]X2Y2·xH2O (where B = 1,10-phenanthroline, X = Y = Cl, ClO4, NO3, or ½SO4, or X = Cl, Y = ClO4, or B = bipyridyl, X = Cl, Y = ClO4) is reported. For the chloride complex co-ordination of chlorine to iron appears to occur. The magnetic properties of the complexes over…
Abstract This study delineates the complex morphological‐deformation processes that occur during the spinning, fabrication, and testing of a series of drawn yarns as an integrated picture of mass movement on all morphological levels. The study involved the use of nine different experimental techniques, including small…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermodynamics of metal cyanide coordination. VI. Copper(I)- and silver(I)-cyanide systemsReed M. Izatt, Harlin Dee Johnston, Gerald D. Watt, and James J. ChristensenCite this: Inorg. Chem. 1967, 6, 1, 132–135Publication Date (Print):January 1, 1967Publication History Publis…
Passive films of γ ‐ Al 2 O 3 formed on aluminum by chromate solutions exhibit lower ionic resistance and higher electronic resistance than amorphous thermal films of the same thickness. The low ionic resistance is attributed to the formation of some crystalline γ ‐ Al 2 O 3 of very low ionic resistance at the oxide s…
Abstract A comparison is made of the properties of magnesium oxides prepared from basic magnesium carbonates and Indian and Greek rock magnesites. the density increased with burning temperature and the reactivity decreased. the effect of this on the properties of oxychloride cements is shown. Iodine number is shown to…
The effect of a hydrated oxide on the kinetics of anodic oxidation of aluminum has been studied and the properties of the resulting composite oxides compared with those of purely anodic oxides. The presence of a hydrate layer reduced the amount of anodic oxide needed to support a given voltage and increased the curren…
An absolute precision determination of lattice constants by electron diffraction is made with thin monocrystalline films of germanium and aluminium, having a thickness between 1000 and 5000 A. The films are prepared from the bulk material by mechanical polishing and subsequent chemical polishing or etching. The obtain…