Materials Literature
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Absorption bands in the region from 40 000 to 80 000 ${\mathrm{cm}}^{\ensuremath{-}1}$ have been found for the divalent ions of V, Cr, Mn, Fe, Co, and Ni in the host crystals KMg${\mathrm{F}}_{3}$, Ca${\mathrm{F}}_{2}$, and Mg${\mathrm{F}}_{2}$. Their spectral positions are near those of the free-ion $3d\ensuremath{\r…
The Raman spectrum of (TMA)2UCl6, not reported previously, is presented and the assignments of the observed bands to normal modes of vibration are discussed based on polarized room temperature scans of single crystals. Seventeen of the eighteen fundamental vibrational bands and seven nonfundamental ones are identified…
A theory analyzing the temperature dependence of second-order elastic constants on the basis of a quasiharmonic-anisotropic-continuum model is applied to LiBr, KCl, RbF, $\ensuremath{\beta}$-brass, Cu, Ag, and Au. The number of fourth-order elastic constants is reduced from 11 to 2 by assuming that nearest-neighbor (n…
Ni 3 P 2 O 8 crystallizes in the monoclinic system with space group P2 1 /c with a = 5.830(2), b = 4.700(2), c = 10.107(4) Å, β = 91.22(2)°, and Z = 2. The structure was refined by full-matrix least squares methods to a final R value of 0.035 using 986 symmetry independent reflections. The structure is isotypic with t…
Thermally stimulated depolarization (TSD) current has been measured in polycrystalline H2O and D2O ice in the temperature range 77–260 K and at pressures of about 1 bar and 1.2 kbar. Three peaks in current have been observed at about 1 bar at a heating rate of 0.0023 K sec−1, the smallest of which appears at 110.4 K a…
The plasmon structure accompanying core-level x-ray photoemission in Na, Mg, and Al is reported and analyzed using a model of random spatial emission of extrinsic plasmons. The Mg and Al spectra are well fit by this model without intrinsic plasmon production. The Na data are not explained by purely extrinsic plasmon e…
The dynamics of the switching process in amorphous semiconductors is analyzed using a previously described electrothermal model. Utilizing recent preswitching noise data as input, we calculate the switching delay time as a function of current in the low-overvoltage regime in the nucleation approximation. It is found t…
The absorptivity or reflectivity of polycrystalline samples of Ti, Zr, and Hf was measured from 0.15 to \ensuremath{\sim}30 eV. The data were Kramers-Kronig analyzed to determine the dielectric functions. Between \ensuremath{\sim}0.2 and \ensuremath{\sim}7 eV, each metal showed five structures in the absorptivity and…
Abstract Micro-examination of irradiated uranium dioxide has shown that pores formed along triple-point grain edges play an important part in the swelling of the fuel. When the volume change is greater than 7 % this porosity has the form of long tunnels linking adjacent grain corners and forming an interconnected netw…
We have enlarged the theory of the coercive force to include the wave nature of the ferromagnetic domain walls. Specifically, we obtain an explicit equation for the magnetic field required to move a 180\ifmmode^\circ\else\textdegree\fi{} ferromagnetic domain wall across a planar defect such as a grain boundary. Using…
Differential scanning calorimetry measurements of the smectic-$A$---nematic latent heat of transition in binary mixtures of ${\mathrm{C}}_{8}$${\mathrm{H}}_{17}$O-${\mathrm{C}}_{6}$${\mathrm{H}}_{4}$-CHN-${\mathrm{C}}_{6}$${\mathrm{H}}_{4}$-${\mathrm{C}}_{3}$ ${\mathrm{H}}_{7}$ (8O.3) and ${\mathrm{C}}_{2}$${\mathrm{H…
A study of the effect of magnetic impurities and magnetic field on the purported charge-density-wave (CDW) transition in Nb${\mathrm{Se}}_{2}$ reveals an intriguing connection between the CDW and the superconducting states. Increasing magnetic impurity concentration results in a reduction of the transition temperature…
Abstract The catalytic hydrogenation of ethylene over the non-stoichiometric calcium hydride (CaH2−δ) prepared by means of high-temperature evacuation was studied. The order of introducing gases had no effect on the rate of ethylene hydrogenation. The rate expressions for the initial stage were ν=k PH0.8–1.0 PE and ν′…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotosensitized oxygenation of trans,trans-1-methylcyclodeca-1,6-diene. Regiospecific hydroperoxidation with singlet oxygenSung-Kee Chung and A. Ian ScottCite this: J. Org. Chem. 1975, 40, 11, 1652–1653Publication Date (Print):May 1, 1975Publication History Published online1…
Abstract This article considers two topics: (1) Cooling of the film bubble and (2) Production of shrinkable film. Heat is transported by conduction, convection, and radiation, but only convection and radiation are relevant for the cooling results. Heat radiation can be calculated with known surface area, temperatures,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCapability and nature of the amide bond as a transmitter of electronic effectsJohn P. Idoux and Rudolfo ZarrilloCite this: J. Org. Chem. 1975, 40, 10, 1519–1521Publication Date (Print):May 1, 1975Publication History Published online1 May 2002Published inissue 1 May 1975https…
Messung der Sauerstoffaktivität in binären Nickelschmelzen mit Zusätzen an Aluminium, Chrom, Kohlenstoff, Mangan, Molybdän, Silicium, Titan, Vanadin oder Wolfram mit Hilfe von ZrO 2 (CaO)‐Festelektrolytzellen bei 1600 °C. Probenahme und analytische Bestimmung der Gehalte an Sauerstoff und Legierungselement. Beschreibu…
Anodic polarization tests on certain metastable austenitic (TRIP) steels having very high strength and good ductility, with contents of sulfur, phosphorus, and other impurities comparable to those of commercial alloy steels, indicate they would have about the same general corrosion resistance as commercial Type 316 st…
This paper presents a comparison between the hairiness and diameter of open-end and ring yams spun from various polyester/cotton blends. The yarn hairiness and diameter were measured using an optical technique. The study covered the effects of blend ratio, yarn count, and twist on the hairiness and diameter of open-en…
The changes in the structure of commercial polyethylene terephthalate yam, when it is textured on a spindle false- twist machine, have been studied over a range of heater temperatures and heater contact times. Compared to the un textured yarn, crystalline content increases on texturing, but crystallite orientation, bi…