Materials Literature
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In this paper, we present a new method for highly efficient size separation of water-soluble CdTe quantum dots (QDs) based on CGE using polymer solution as sieving medium. CdTe QDs were synthesized in aqueous phase by a chemical route with mercaptopropionic acid as a ligand. In the alkaline solution, CdTe QDs possess…
Thermal cycloaddition of 1,3-dipolar azomethine ylides to the sidewalls of multiwalled carbon nanotubes (MWNTs) has been used to prepare MWNTs that contain 2-methylenethiol-4-(4-octadecyloxyphenyl) (4), N-octyl-2-(4-octadecyloxyphenyl) (5) or 2-(4-octadecyloxyphenyl)pyrrolidine (6) units. All these contain the 4-octad…
We report that electromagnetic wave reflected from a flat metallic mirror superimposed with a planar wavy metallic structure with subwavelength features that resemble “fish scales” reflects like a conventional mirror without diffraction, but shows no phase change with respect to the incident wave. Such unusual behavio…
ZnO -based p-n homojunctions were grown using molecular-beam epitaxy. Sb and Ga were used as dopants to achieve the p-type and n-type ZnO, respectively. The mesa devices were fabricated by employing wet etching and standard photolithography techniques. Al∕Ti metal was deposited by electron-beam evaporation and anneale…
Abstract Wood–plastic lumber is promoted as a low‐maintenance high‐durability product. When exposed to accelerated weathering, however, wood–plastic composites may experience a color change and loss in mechanical properties. Differences in weathering cycle and composite surface characteristics can affect the rate and…
Crystallization temperature dependency on Si nanoparticles size was studied by using Raman scattering spectroscopy. Si nanoparticles synthesized by pulsed laser ablation were annealed at various temperatures while they were suspended in helium background gas, and then were classified by a differential mobility analyze…
Severe plastic deformation of metals leads to an extremely fine microstructure. This is produced by “fragmentation” of the original crystal structure. The mechanisms for this fragmentation are discussed. Various methods for severe plastic deformation are classified according to the strain paths involved: For compariso…
In dynamical simulations of coarse-grained models of soft matter in a solvent a considerable amount of the total simulation time is generically spent on updating the solvent particles, although their dynamics is in most cases not of primary interest. In order to speed up such simulations and as a consequence allow to…
We develop a series of propensity rules for interpreting Inelastic Electron Tunneling (IET) spectra of single-molecule transport junctions. IETS has no selection rules, such as those seen in optical, infrared and Raman spectra, because IETS features arise not from the field-dipole interaction characterizing these othe…
Filling of single-wall carbon nanotubes with C59N azafullerene derivatives is reported from toluene solvent at ambient temperature. The filling is characterized by high resolution transmission electron microscopy and Raman spectroscopy. The filling efficiency is the same as for C60 fullerenes and the tube-azafullerene…
Polycrystalline AgnPbmSbTem+2n thermoelectric materials, whose compositions can be described as Ag0.8Pb18+xSbTe20 were prepared using a combined process of mechanical alloying and spark plasma sintering. Electric properties of the sintered samples with different Pb contents were measured from room temperature to 700K.…
Sodium carboxymethylcellulose, an etherified derivative of cellulose, has been found to realize stable aqueous dispersion of single-wall carbon nanotubes (SWNTs) that is twenty times more concentrated than when a surfactant is used under the same condition. The dispersion as well as thin films prepared from it exhibit…
Epitaxial films of a deep-ultraviolet transparent oxide semiconductor, Ga2O3, were fabricated on α-Al2O3 (0001) substrates by pulsed laser deposition. Four-axes x-ray diffraction measurements revealed that the tin-doped Ga2O3 films have a crystal structure different from any known polymorphs of Ga2O3. Its crystal latt…
We investigate the relative stability and electronic structure of several ${\mathrm{B}}_{x}{\mathrm{C}}_{y}{\mathrm{N}}_{z}$ layered structures using first-principles calculations. The twenty structures we considered are derived from a graphite layer by placing carbon, nitrogen, or boron atoms on each site. Interestin…
The characteristics of heat flow in a coupled magnetic system are studied. The coupled system is composed of a gapped chain and a gapless chain. The system size is assumed to be quite small so that the mean free path is comparable to it. When the parameter set of the temperatures of reservoirs is exchanged, the charac…
Using renormalized field theory, we examine the dynamics of a growing surface, driven by an obliquely incident particle beam. Its projection on the reference (substrate) plane selects a ``parallel'' direction, so that the evolution equation for the surface height becomes anisotropic. The phase diagram of the model is…
We have theoretically designed three families of the half-metallic (HM) antiferromagnets (AFM), namely, $\mathrm{La}A\mathrm{V}\mathrm{Os}{\mathrm{O}}_{6}$, $\mathrm{La}A\mathrm{Mo}\mathrm{Tc}{\mathrm{O}}_{6}$, and $\mathrm{La}A\mathrm{Mo}\mathrm{Re}{\mathrm{O}}_{6}$ ($A=\mathrm{Ca}$,Sr,Ba), based on a systematic ab i…
${\mathrm{GdFe}}_{3}({\mathrm{BO}}_{3}{)}_{4}$ exhibits a structural phase transition at $156\phantom{\rule{0.3em}{0ex}}\mathrm{K}$, antiferromagnetic order of the ${\mathrm{Fe}}^{3+}$ moments at $36\phantom{\rule{0.3em}{0ex}}\mathrm{K}$, followed by a spin reorientation phase transition at $9\phantom{\rule{0.3em}{0ex…
We present a novel model of the effective thermal conductivity for carbon nanotube composites by incorporating the interface thermal resistance with an average polarization theory. The dependence of the effective thermal conductivity on nanotube length, diameter, concentration, and interface thermal resistance has bee…
Abstract This article contains a detailed calorimetric analysis of the multiple melting behavior of poly( L ‐lactic acid) (PLLA) in dependence of crystallization conditions. PLLA crystals formed upon primary crystallization have a greater tendency to reorganize into more stable structures during the heating scan that…