Materials Literature
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The effect of the correction of the self-interaction error on the calculation of exchange coupling constants with methods based on density-functional theory has been tested in simple model systems. The inclusion of the self-interaction correction cancels the nondynamical correlation energy contributions simulated by t…
In this paper, we demonstrate the first use of a catecholic initiator for surface-initiated polymerization (SIP) from metal surfaces to create antifouling polymer coatings. A new bifunctional initiator inspired by mussel adhesive proteins was synthesized, which strongly adsorbs to Ti and 316L stainless steel (SS) subs…
The seed-mediated growth of gold nanostructures is shown to be strongly dependent on the gold seed nanocrystal structure. The gold seed solutions can be prepared such that the seeds are either single crystalline or multiply twinned. With added silver(I) in the cetyltrimethylammonium bromide (CTAB) aqueous growth solut…
The Helfrich-Hurault effect is a phase transition that occurs in samples of cholesteric or smectic liquid crystals subject to external electric or magnetic fields. In this paper we analyze the Helfrich-Hurault effect of smectic-A liquid crystals in an electrostatic field taking into account the complete electromechani…
We report the results of ac conductivity measurements on silver halide silver oxysalt glasses. Like Kincs and Martin [Phys. Rev. Lett. 76, 70 (1996)], we find that these glasses exhibit non-Arrhenius behavior in the dc conductivity, which depends strongly on the silver halide content and on the type of the halide anio…
Abstract Summary: Amphiphilic hyperbranched polyester (H20‐AM) with methacrylate end groups was synthesized based on hyperbranched aliphatic polyester (Boltorn™ H20). Narrow‐dispersed crosslinkable vesicles were obtained by dissolving H20‐AM in water, and characterized by laser light scattering and TEM. The hollow str…
Abstract 1,1,1‐Tris(4‐trimethylsiloxyphenyl)ethane, (silylated THPE), was polycondensed with 2,4‐difluoroacetophenone and 2,4‐difluorobenzophenone. All polycondensations were performed in N ‐methylpyrrolidone with K 2 CO 3 as promotor. The feed ratio THPE/difluoroaromat was varied from 1.0:1.3 to 1.0:1.5. Instead of h…
In situ S K-edge XANES experiments were carried out on second-generation SO(x)() trapping materials under oxidizing and reducing conditions. The experiments clearly show that the strong release of SO(2) under rich conditions at plug flow conditions is caused by the facilitated reduction of sulfite species on Pt. In th…
Multitype Moran sets are introduced in this paper. They appear naturally in the study of the structure of the quasi-crystal spectrum, and they generalize some known fractal structures such as self-similar sets, graph-direct sets and Moran sets. It is known that for any Moran set E with a bounded condition on contracti…
The glass-forming liquids 3-bromopentane (3BP) and 3-methylpentane (3MP) are readily miscible across the entire composition range, although their polarities differ considerably. As noted by Berberian [J. Non-Cryst. Solids 131-133, 48 (1991)], the nearly matching molar volumes makes this binary system appear ideal for…
A unique guest-guest ion exchange method was developed for preparing a thin film of a nano-layered K(4)Nb(6)O(17).3H(2)O that possesses both (1) optical transparency and (2) ion-exchangeability under ambient conditions without calcination at high temperature. An optically transparent Ru(bpy)(3)(2+)-K(4)Nb(6)O(17) hybr…
We focus on a basic issue regarding optically uniaxial left-handed materials of lossless. We give the necessary and sufficient conditions for the optically uniaxial generalized left-handed materials in a nondissipative limit, based on the optic axis concept in crystal optics. The results show that the normal surface o…
Self-assembly of block copolymer is used as the template to form nanoscale ordered structure of a polymeric ceramic precursor. The self-assembly is subsequently pyrolyzed to form Si−C−N ceramic with nanoscale structure bearing local order.
The aim of this study was to evaluate the influence of pegylated copolymeric micelle carrier on the biodistribution of drug in rats. The copolymers were synthesized via a modified ring-opening copolymerization of lactone monomers (epsilon-caprolactone, delta-valerolactone, L-lactide) and poly(ethylene glycol) (PEG(10,…
A nonanuclear nickel(II) complex [Ni9(PyA)(10)(mu3-OH)2(mu2-OH)2(mu2-OH2)2(H2O)6](ClO4)4.12H2O, containing pyridine-2-aldoximato monoanion, PyA, has been structurally and magnetochemically characterized. The nickel(II) ions, linked together via several bi- or trifurcated oximato, hydroxo, and water bridges, are antife…
A new open-framework copper borophosphate was hydrothermally synthesized and structurally characterized. Its structure may be regarded as a layer forming via vertex-sharing BO3(OH) and PO4 tetrahedra bonded together with CuO2(OH)2(H2O)2 octahedral units. The thermal stability and magnetic properties are also discussed.
The synthesis and characterization of anisotropic liquid single crystal hydrogels (LSCHs) via photoinduced radical polymerization of magnetically aligned samples in the lyotropic mesophase are reported, which are stable against tensile stresses in all three dimensions. The hydrogels exhibit a lamellar phase (L α ) in…
Structural, luminescence, and electronic properties of the family of alkaline metal-strontium cyclotetravanadates ${M}_{2}\mathrm{Sr}{(\mathrm{V}{\mathrm{O}}_{3})}_{4}$, $M=\mathrm{Na}$, K, Rb, and Cs have been characterized by means of elemental analyses, x-ray powder diffraction, neutron diffraction, electron diffra…
Abstract Summary: The photopolymerization of two reactive mesogens with photopolymerizable acrylate endgroups, the methyl substituted 1,4‐phenylene‐bis{4‐[6‐(acryloyloxy)hexyloxy]benzoate} 1 and acrylic acid 6‐{4‐[6‐(6‐acryloyloxyhexyloxy)naphthalen‐2‐yl]‐phenoxy}hexyl ester 2 has been investigated using Photo‐DSC mea…
The relaxation of electronic spins S of paramagnetic species is studied by the field-dependence of the longitudinal, transverse, and longitudinal in the rotating frame relaxation rates R1, R2, and R1rho of nuclear spins I carried by dissolved probe solutes. The method rests on the model-independent low-frequency dispe…