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Preparation of novel nano-composite Ni(OH)2/USY material and its application for electrochemical capacitance storageElectronic supplementary information (ESI) available: calculation method of the measured and theoretical specific capacitance. See http://www.rsc.org/suppdata/cc/b4/b401922a/

Lin Cao、Ling‐Bin Kong、Yanyu Liang 等 4 位作者2004-01-01Chemical Communications

A novel nano-composite material of Ni(OH)2/USY was prepared in our lab. This nanostructure creates electrochemical accessibility of electrolyte OH- ions to Ni(OH)2 thin layers and a fast diffusion rate within the redox phase.

Supercapacitor Materials and FabricationConducting polymers and applicationsTransition Metal Oxide Nanomaterials

High-resolution transmission electron microscopy: the ultimate nanoanalytical technique

John Meurig Thomas、Paul A. Midgley2004-01-01Chemical Communications

To be able to determine the elemental composition and morphology of individual nanoparticles consisting of no more than a dozen or so atoms that weigh a few zeptograms (10(-21) g) is but one of the attainments of modern electron microscopy. With slightly larger specimens (embracing a few unit cells of the structure) t…

Advanced Electron Microscopy Techniques and ApplicationsCopper-based nanomaterials and applicationsElectron and X-Ray Spectroscopy Techniques

Application of Vibration Technology to Polymer Electrospinning

Ji‐Huan He、Yu-Qin Wan、Jianyong Yu2004-01-01International Journal of Nonlinear Sciences and Numerical Simulation

Article Application of Vibration Technology to Polymer Electrospinning was published on September 1, 2004 in the journal International Journal of Nonlinear Sciences and Numerical Simulation (volume 5, issue 3).

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

The Effect of Dual Microstructure Heat Treatment on an Advanced Nickel-Base Disk Alloy

John Gayda、Timothy P. Gabb、Pete Kantzos2004-01-01OpenAlex

Five heat treat options for an advanced nickel-base disk alloy, LSHR, have been investigated.These included two conventional solution heat treat cycles, subsolvus/oil quench and supersolvus/fan cool, which yield fine grain and coarse grain microstructure disks respectively, as well as three advanced dual microstructur…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesHigh Temperature Alloys and Creep

Synthesis and linear/nonlinear optical properties of a new class of ‘RHS’ NLO chromophore

Andrew J. Kay、Anthony D. Woolhouse、Yuxia Zhao 等 4 位作者2004-01-01Journal of Materials Chemistry

Examples of a new class of zwitterionic, “right-hand side” merocyanines containing a cyanodicyanomethylidenedihydrofuran electron acceptor have been prepared. As well as allowing for the facile synthesis of these chromophores, our synthetic methodology enables considerable variation in both the donor moiety as well as…

Porphyrin and Phthalocyanine ChemistryNonlinear Optical Materials ResearchChemical synthesis and pharmacological studies

Formation of cyanide-functionalized SBA-15 and its transformation to carboxylate-functionalized SBA-15

Chia‐Min Yang、Yanqin Wang、Bodo Zibrowius 等 4 位作者2004-01-01Physical Chemistry Chemical Physics

Cyanide-functionalized mesoporous silica SBA-15 (CN/SBA-15) with pore diameters larger than 6 nm has been prepared by a one-pot synthesis. The structure of CN/SBA-15 is affected by the amount of the functional silane 2-cyanoethyltriethoxysilane (CTES) and the conditions of co-condensation in the acidic aqueous solutio…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Regioregular polythiophene/gold nanoparticle hybrid materials

Lei Zhai、Richard D. McCullough2004-01-01Journal of Materials Chemistry

We report a one-pot synthesis of regioregular polythiophene stabilized gold nanoparticles with narrow size distributions that can form fibril-like structures due to the self-assembly of regioregular polythiophene.

Gold and Silver Nanoparticles Synthesis and ApplicationsConducting polymers and applicationsDendrimers and Hyperbranched Polymers

Water and Redox Conditions in Wetland Soils—Their Influence on Pedogenic Oxides and Morphology

Sabine Fiedler、Michael Sommer2004-01-01Soil Science Society of America Journal

For wetland soil studies, it would be desirable to estimate soil redox status and its effect on element translocations based on diagnostic redoximorphic features. However, their identification and interpretation is often complicated and require a regional calibration. This study was conducted (i) to determine the rela…

Soil and Unsaturated FlowClay minerals and soil interactionsMine drainage and remediation techniques

Crystal engineering of photochromic diarylethene single crystals

Masakazu Morimoto、Seiya Kobatake、Masahiro Irie2004-01-01The Chemical Record

Photochromic performance of diarylethene single crystals was controlled by crystal engineering using non-covalent aromatic-aromatic interactions as the directional intermolecular force. A diarylethene derivative with two pentafluorophenyl groups, 1,2-bis(2-methyl-5-pentafluorophenyl-3-thienyl)perfluorocyclopentene (1a…

Porphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence ChemistryOrganic Chemistry Cycloaddition Reactions

Surface/Interface-Related Conductivity in Nanometer Thick YSZ Films

Igor Kosacki、Christopher M. Rouleau、Paul Becher 等 5 位作者2004-01-01Electrochemical and Solid-State Letters

Results of the electrical conductivity study of highly textured, ultrathin (15 nm) cubic yttria-stabilized zirconia (YSZ) thin films are presented for the first time. A nanoscale effect that results in exceptionally high ionic conductivity at moderate temperatures is detected in films less than 60 nm thick. The conduc…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides

Colloidal Crystal-Templated Porous Carbon as a High Performance Electrical Double-Layer Capacitor Material

Isamu Moriguchi、Fumihiro Nakahara、Hiroshi Furukawa 等 5 位作者2004-01-01Electrochemical and Solid-State Letters

Bimodal porous carbons with both micropores and meso- or macropores were selectively synthesized by an colloidal crystal-templating process. The opal templates exclusively contributed to the formation of meso- and macropores in carbons. The electrical double-layer capacitance per surface area of the templated porous c…

Supercapacitor Materials and FabricationConducting polymers and applicationsMesoporous Materials and Catalysis

First cation radical salt of a tetrathiafulvalene–based phosphine metal complex

N. Avarvari、Marc Fourmigué2004-01-01Chemical Communications

Electrocrystallization of (o-P2)Mo(CO)4, where o-P2 is the tetrathiafulvalene-based chelating diphosphine o-Me2TTF-(PPh2)2, in the presence of the Linquist anion Mo6O192− affords a 2:1 salt, formulated as [(o-P2)Mo(CO)4]2[Mo6O19], with a Heisenberg spin chain magnetic behaviour.

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesOrganic and Molecular Conductors Research

Photodynamic studies and photoinactivation of Escherichia coli using meso-substituted cationic porphyrin derivatives with asymmetric charge distribution

Débora Lazzeri、Marisa Rovera、Liliana Pascual 等 4 位作者2004-01-01Photochemistry and Photobiology

The photodynamic activities of novel asymmetrically meso-substituted cationic porphyrins, 5,10-di(4-methylphenyl)-15,20-di(4-trimethylammoniumphenyl)porphyrin iodide 1 and 5-(4-trifluorophenyl)-10,15,20-tris(4-trimethylammoniumphenyl)porphyrin iodide 2 and its metal complex with Pd(II) 3, have been investigated in bot…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Dinámica de fluidos computacional aplicada al estudio de regeneradores térmicos

Nieto Londoño, César、Mejía Álvarez, Ricardo、Agudelo Santamaría, John Ramiro2004-01-01Institutional Repository University of Antioquia (University of Antioquia)

El servicio de alcantarillado de Cajicá no responde a un proyecto de ingeniería pensado hacía el futuro, sino, más bien, a 
\nsoluciones coyunturales de las comunidades urbana y rurales, y, por tanto, pensado para beneficiar una población relativamente pequeña (menos de 10.000 habitantes), sin tener en cuenta que,…

Advanced ceramic materials synthesisPlant and soil sciences

Self-assembled arrays of ZnO nanoparticles and their application as varistor materialsElectronic supplementary information (ESI) available: XRD plots and FESEM images. See http://www.rsc.org/suppdata/jm/b4/b400927d/

Suresh C. Pillai、John M. Kelly、Declan E. McCormack 等 4 位作者2004-01-01Journal of Materials Chemistry

Linear arrays of ZnO nanoparticles have been successfully prepared by a simple sol–gel condensation reaction involving chemical modifiers, followed by drying (80 °C) and calcination (500 °C). The calcined material (nano-array ZnO) is composed of approximately spherical nanoparticles of average diameter 21 ± 3 nm, self…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

K6Cd4Sn3Se13: A polar open-framework compound based on the partially destroyed supertetrahedral [Cd4Sn4Se17]10? cluster

Nan Ding、Duck Young Chung、Mercouri G. Kanatzidis2004-01-01Chemical Communications

K6Cd4Sn3Se13 forms in superheated water and has a polar open-framework structure that is based on an octahedral topological motif. It forms from the polymerization of a single [Cd4Sn3Se13]6− cluster which formally derives from a [Cd4Sn4Se17]10−via elimination of one [SnSe4]4− anion. K6Cd4Sn3Se13 exhibits facile ion-ex…

Crystal Structures and PropertiesInorganic Chemistry and MaterialsInorganic Fluorides and Related Compounds

Chemical recycling of sulfur-cured natural rubber using supercritical carbon dioxide

Masaaki Kojima、Masatoshi Tosaka、Yuko Ikeda2004-01-01Green Chemistry

Sulfur-cured unfilled natural rubber (NR) was devulcanized in supercritical CO2 (scCO2) by using diphenyl disulfide (DD) as a devulcanizing reagent. The product was fractionated into sol and gel components. The fraction of sol component that contains reusable linear polymer increased with the increase in CO2 pressure,…

Polymer crystallization and propertiesPhase Equilibria and ThermodynamicsPolymer Nanocomposites and Properties

Effect of Pass Strain on Grain Refinement in 7475 Al Alloy during Hot Multidirectional Forging

Oleg Sitdikov、Taku Sakai、Alexandre Goloborodko 等 5 位作者2004-01-01MATERIALS TRANSACTIONS

Effect of pass strain (Δε) on grain refinement was studied in multidirectional forging (MDF) of a coarse-grained 7475 Al alloy at 490°C under a strain rate of 3 × 10−4 s−1. Samples of rectangular shape were deformed up to accumulated strains of around 6 with subsequent changes in loading direction 90° from pass to pas…

Microstructure and mechanical propertiesMetallurgy and Material FormingAdvanced materials and composites

A general one-pot process leading to highly functionalised ordered mesoporous silica films

Florence Cagnol、David Grosso、Clément Sánchez2004-01-01Chemical Communications

Various organic moieties are homogeneously introduced in high quantities into mesostructured porous silica films through a general co-condensation process, which influences the self-assembly mechanism, depending on the physico-chemical properties of each function.

Catalytic Processes in Materials SciencePhotonic Crystals and ApplicationsMesoporous Materials and Catalysis