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Deposition of silicon modified aluminide coatings on nickel base superalloys by pack cementation process

Zheng Xiang、P.K. Datta2003-07-01Materials Science and Technology

The equilibrium partial pressures of vapour species generated in halide activated pack powder mixtures at high temperatures were calculated for a series of compositions using thermochemical analysis tools. The results obtained were applied to identify suitable activators and pack compositions for codepositing Al and S…

High-Temperature Coating BehaviorsIntermetallics and Advanced Alloy PropertiesThermal and Kinetic Analysis

Factorial design in optimization of PHAs processing

Emo Chiellini、Elizabeth Grillo Fernandes、Matteo Pietrini 等 4 位作者2003-07-01Macromolecular Symposia

Abstract Poly(hydroxyalkanoate)s (PHA)s, as all melt‐processed polymers, may undergo thermal degradation at temperatures close to the melting point. The primary purpose of the present study is to screen out process variables on the basis of a factorial design for two variables at two levels. The investigated parameter…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesTribology and Wear Analysis

Theoretical and experimental determination of the permeability tensor components of magnetized ferrites at microwave frequencies

Stéphane Mallégol、Patrick Quéffélec、M. Le Floc’h 等 4 位作者2003-07-01IEEE Transactions on Magnetics

We compare the diagonal /spl mu/ and off-diagonal /spl kappa/ permeability tensor components of magnetized polycrystalline ferrites given by the theoretical model of Gelin and Berthou with experimental ones at microwave frequencies. We used a broad-band and noniterative measurement technique recently developed within…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsMagneto-Optical Properties and Applications

Effect of filler shape on mechanical properties of rigid polyurethane composites containing plant particles

Masahiro Funabashi、Shigeo Hirose、Tatsuko Hatakeyama 等 4 位作者2003-07-01Macromolecular Symposia

Abstract The effect of types of fillers on mechanical properties of rigid polyurethane composite samples was investigated. Polyurethane (PU) composites were prepared using a molasses polyol (MP, a mixture of molasses and polyethylene glycol, Mw=200) diphenylmethane diisocyanate (MDI) and fillers. The following plant p…

Natural Fiber Reinforced CompositesPolymer composites and self-healingPlant Surface Properties and Treatments

Experimental resolution measurement in critical dimension scanning electron microscope metrology

Gian F. Lorusso、David C. Joy2003-07-01Scanning

By applying the basic principles of metrology we discuss how to define the standards that any experimental method to measure resolution has to obey. Our results clearly indicate the need to apply a calibration procedure when designing algorithms to estimate resolution to satisfy accuracy requirements. Similarly, the p…

Advanced Electron Microscopy Techniques and ApplicationsAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Imaging multispectral polarimetric sensor: single-pixel design, fabrication, and characterization

Donghyun Kim、Cardinal Warde、K. Vaccaro 等 4 位作者2003-07-01Applied Optics

A discrete-component approach was taken to establish the operational feasibility of a novel, imaging, midinfrared, multispectral, polarimetric sensor for remote-sensing application. The sensor is designed to exploit the spectral and polarimetric characteristics of the scene as discriminants. Pixelated multispectral fi…

Photonic and Optical DevicesOptical Coatings and GratingsOptical Polarization and Ellipsometry

Investigations of a Control Surface Seal for Reentry Vehicles

Patrick H. Dunlap、Bruce M. Steinetz、Donald M. Curry 等 6 位作者2003-07-01Journal of Spacecraft and Rockets

Covers advancements in spacecraft and tactical and strategic missile systems, including subsystem design and application, mission design and analysis, materials and structures, developments in space sciences, space processing and manufacturing, space operations, and applications of space technologies to other fields.

Diamond and Carbon-based Materials ResearchTribology and Lubrication EngineeringSilicone and Siloxane Chemistry

Alkylated naphthalenes as high‐performance synthetic fluids

E. T. Hessell、Richard A. Abramshe2003-07-01Journal of Synthetic Lubrication

Abstract The physical and chemical properties for a series of structurally well‐defined, alkylated naphthalenes have been compared. Structural characteristics, such as the alkyl chain length, alkyl chain branching, and number of alkyl groups on the naphthalene ring, have been correlated with physical properties, such…

Surfactants and Colloidal SystemsPolymer composites and self-healingLignin and Wood Chemistry

Polymorphism and design of noncentrosymmetric crystals of 4-hydroxybenzaldehyde-4-nitrophenylhydrazone and N′-(2-phenyl-1H-indole-3-aldehyde)-4-nitrophenylhydrazone

L. N. Kuleshova、Mikhail Yu. Antipin、Victor N. Khrustalev 等 6 位作者2003-07-01Crystallography Reports

The products of crystallization of 4-hydroxybenzaldehyde-4-nitrophenylhydrazone ( I ) and N ′-(2-phenyl-1 H -indole-3-aldehyde)-4-nitrophenylhydrazone ( II ) from different solvents are studied by X-ray diffraction with the aim of examining the polymorphism of hydrazone derivatives. The structural features of the crys…

Synthesis and biological activityNonlinear Optical Materials ResearchChemical synthesis and pharmacological studies

Acid-Base Titrations in Nonaqueous Solvents and Solvent Mixtures

Lajos Barcza、Ágnes Buvári-Barcza2003-07-01Journal of Chemical Education

The acid–base determination of different substances by nonaqueous titrations is highly preferred in pharmaceutical analyses since the method is quantitative, exact, and reproducible. The modern interpretation of the reactions in nonaqueous solvents started in the last century, but several inconsistencies and unsolved…

Process Optimization and IntegrationCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Ti-Zr-Ni bulk quasicrystals prepared by casting

Jianbing Qiang、Yingmin Wang、Dehe Wang 等 5 位作者2003-07-01Philosophical Magazine Letters

A broad bulk-quasicrystal-forming region, (Ti x Zr100− x )100− y Ni y (43.75 ≤⃒ x ≤⃒ 81.25, 17 ≤⃒ y ≤⃒ 23), has been identified in the Ti-Zr-Ni system, and quasicrystals can be obtained by using a conventional suction-casting method. The quasilattice constant of the icosahedral (i) phase is within the range 0.505-0.53…

Intermetallics and Advanced Alloy PropertiesQuasicrystal Structures and PropertiesEurasian Exchange Networks

Study of Polymer Glasses by Modulated Differential Scanning Calorimetry in the Undergraduate Physical Chemistry Laboratory

J.C.W. Folmer、Stefan Franzen2003-07-01Journal of Chemical Education

Recent technological advances in thermal analysis present educational opportunities. In particular, modulated differential scanning calorimetry (MDSC) can be used to contrast reversing and nonreversing processes in practical laboratory experiments. The introduction of these concepts elucidates the relationship between…

Thermal and Kinetic AnalysisAdsorption, diffusion, and thermodynamic properties of materials

Insitu TEM studies of the mechanisms of crack nucleation and propagation in fully lamellar microstructures

Shaozhi Li、T.H. Yip、R.V. Ramanujan 等 4 位作者2003-07-01Materials Science and Technology

The mechanisms of crack nucleation and propagation of the lamellar microstructures found in pearlite were studied by in situ transmission electron microscopy. It was found that, in addition to the predominant mechanism of cleavage fracture in the cementite plates, ductile fracture of the cementite plates is another cr…

Advanced ceramic materials synthesisRock Mechanics and ModelingMicrostructure and mechanical properties

Investigation of oxide (V2O5) thin films as electrodes for rechargeable microbatteries using Li

A. Talledo、Héctor Valdivia、Carsten Benndorf2003-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

V 2 O 5 thin films were prepared by reactive rf sputtering and used in the application as electrodes in rechargeable battery with Li as a counterelectrode. The V2O5 films were deposited onto uncoated and SnO2 coated glass by sputtering a V cathode using Ar+O2 gas mixtures. The structural properties of the V2O5 films w…

Advancements in Battery MaterialsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Synthesis of a New-type Carbonific and Its Application in Intumescent Flame-retardant (IFR)/Polyurethane Coatings

Jincheng Wang、Yang Shenglin、Guang Li 等 4 位作者2003-07-01Journal of Fire Sciences

This work deals in the first part, with the synthesis and characterization of a new-type carbonific. Two steps were used in the synthesis of the carbonific. Meanwhile, the structure was characterized by Fourier transform infrared spectroscopy (FTIR), magic-angle spinning nuclear magnetic resonance (MAS-NMR) 13 C spect…

biodegradable polymer synthesis and propertiesFlame retardant materials and propertiesCarbon dioxide utilization in catalysis

Indium tin oxide films with low resistivity and low internal stress

S. Takayama、Toshifumi Sugawara、Akira Tanaka 等 4 位作者2003-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Indium tin oxide (ITO) films prepared by dc magnetron sputtering were annealed in air, vacuum, and oxygen gas atmospheres. The electrical properties and internal stresses of these annealed ITO films were systematically investigated. It was found that, among the above postannealing treatments, oxygen gas annealing sign…

ZnO doping and propertiesThin-Film Transistor TechnologiesTransition Metal Oxide Nanomaterials

X-ray photoelectron spectroscopy study of the first stages of ZnO growth and nanostructure dependence of the effects of polarization at ZnO/SiO2 and ZnO/Al2O3 interfaces

A. I. Martín‐Concepción、F. Yubero、J.P. Espinós 等 5 位作者2003-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

A critical characteristic of nanoparticles and, in general, of nanomaterials, is the overweighing importance of the surface and interface layers relative to the bulk because of the small size of the aggregates (in three dimensions) or thickness of the layers (in the case of two dimensions) that constitute the nanomate…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

NMR and CD Spectroscopy Show that Imino Acid Restriction of the Unfolded State Leads to Efficient Folding

Yujia Xu、Timothy J. Hyde、Xin Wang 等 6 位作者2003-07-01Biochemistry

Protein folding is determined by molecular features in the unfolded state, as well as the native folded structure. In the unfolded state, imino acids both restrict conformational space and present cis-trans isomerization barriers to folding. Because of its high proline and hydroxyproline content, the collagen triple-h…

Chemical Synthesis and AnalysisProtein Hydrolysis and Bioactive PeptidesCollagen: Extraction and Characterization

OCTA (Open Computational Tool for Advanced material technology)

Masao Doi2003-07-01Macromolecular Symposia

Abstract OCTA (Open Computational Tool for Advanced material technology) is an integrated simulation system for polymeric materials developed by a joint project of industry and academia supported by Japanese government. It aims at exploring the utility of mesoscale modelings developed in polymer science. OCTA consists…

biodegradable polymer synthesis and properties

Raman spectroscopic studies on the structural changes of electrosynthesized polypyrrole films during heating and cooling processes

Fengén Chen、Jiaxin Zhang、Fan Wang 等 4 位作者2003-07-01Journal of Applied Polymer Science

Abstract Polypyrrole films were electrochemically synthesized by direct oxidative polymerization of pyrrole in acetonitrile containing β‐naphthalene sulfonic acid or tetrabutylammonium tetrafluoroborate as an supporting electrolyte. We characterized the as‐grown polypyrrole films by resonance Raman spectroscopy in the…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors