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Dimethylvioluratobis(phenanthroline)cobalt(II), a Novel Spin-Crossover Octahedral Co(II) Complex. Synthesis, Crystal Structure and Magnetic Properties of [Co(dmvi)(phen)2]ClO4.cntdot.3H2O

Juan Faus、Miguel Julve、Francisco Lloret 等 5 位作者1994-11-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDimethylvioluratobis(phenanthroline)cobalt(II), a Novel Spin-Crossover Octahedral Co(II) Complex. Synthesis, Crystal Structure and Magnetic Properties of [Co(dmvi)(phen)2]ClO4.cntdot.3H2OJuan Faus, Miguel Julve, Francisco Lloret, Jose A. Real, and Jorunn SlettenCite this: In…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Surface-Induced Asymmetries during Spinodal Decomposition in Off-Critical Polymer Mixtures

Georg Krausch、Edward J. Krämer、Frank S. Bates 等 6 位作者1994-11-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface-Induced Asymmetries during Spinodal Decomposition in Off-Critical Polymer MixturesGeorg Krausch, Edward J. Kramer, Frank S. Bates, J. F. Marko, G. Brown, and A. ChakrabartiCite this: Macromolecules 1994, 27, 23, 6768–6776Publication Date (Print):November 1, 1994Publi…

Material Dynamics and PropertiesPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Chain stiffness and bond correlations in polymer brushes

Christopher M. Wijmans、F. A. M. Leermakers、G. J. Fleer1994-11-01The Journal of Chemical Physics

We have incorporated chain stiffness and correlations between neighboring bonds into a self-consistent field (SCF) lattice model for end-attached polymer layers (commonly known as ‘‘brushes’’). An increase in the chain stiffness leads to an increasing brush height. This increase is directly related to the change of th…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

Geometric theory of the ellipsoidal grating

Takeshi Namioka、Masato Koike、David A. Content1994-11-01Applied Optics

A third-order geometric aberration theory of the ellipsoidal grating has been developed by analytically following an exact ray-tracing formalism with the aid of power series expansions. The theory takes into account all the possible aberrations up to third order and provides analytic formulas for the spot diagram of a…

Adaptive optics and wavefront sensingAdvanced optical system designOptical Coatings and Gratings

Numerical modeling of diffractive devices using the finite element method

Bernd Lichtenberg1994-11-01Optical Engineering

The finite element method (FEM) is introduced to numerically model near-field diffraction devices using Maxwell's equations. This method is commonly used in the antenna and microwave communities to analyze scattering and waveguiding problems, but is not yet popular in the optics community. Its advantages are the rigor…

Microwave Engineering and WaveguidesPhotonic and Optical DevicesOptical Coatings and Gratings

High‐Temperature Crack Growth in Monolithic and SiC w ‐Reinforced Silicon Nitride under Static and Cyclic Loads

U. Ramamurty、Thomas Hansson、S. Suresh1994-11-01Journal of the American Ceramic Society

Experimental results are presented on subcritical crack growth under sustained and cyclic loads in a HIPed Si 3 N 4 at 1450°C and a hot–pressed Si 3 N 4 –10 vol% SiC w composite in the temperature range 1300°–1400°C. Static and cyclic crack growth rates are obtained from the threshold for the onset of stable fracture…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Transition between bipolaron and polaron states in doped heterocycle polymers

Shi-jie Xie、Liangmo Mei、D. L. Lin1994-11-01Physical review. B, Condensed matter

On the basis of a model similar to that of Su, Schrieffer, and Heeger, we investigate transitions between bipolaron and polaron states in doped heterocycle polymers such as polypyrrole, polythiophene, and polyselenophene. The dopant impurity is assumed to be located between chains, and the interchain coupling is due t…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsMolecular Junctions and Nanostructures

An FTIR Study of the Species Adsorbed on a Rh/Al2O3 Catalyst in the Selective Reduction of NO by Propylene

G.R. Bamwenda、Akira Obuchi、Atsushi Ogata 等 4 位作者1994-11-01Chemistry Letters

Abstract An in situ FTIR study of the reduction of NO by propylene in O2 has shown that the reaction on the Rh/Al2O3 surface at 623 K leads to the formation of IR bands assigned to adsorbed hydrocarbons, -NCO, -CN, -NO+, -CO32− and CO2 species. The intensity of the bands depends on the reaction time and the presence o…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsAmmonia Synthesis and Nitrogen Reduction

Ionic Interactions and Charge Transport Properties of Metallopolymer Films on Electrodes

Robert J. Forster、Johannes G. Vos1994-11-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIonic Interactions and Charge Transport Properties of Metallopolymer Films on ElectrodesRobert J. Forster and Johannes G. VosCite this: Langmuir 1994, 10, 11, 4330–4338Publication Date (Print):November 1, 1994Publication History Published online1 May 2002Published inissue 1…

Fuel Cells and Related MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Reaction Bonding and Mechanical Properties of Mullite/Silicon Carbide Composites

Suxing Wu、Nils Claussen1994-11-01Journal of the American Ceramic Society

Based on the RBAO technology, low‐shrinkage mullite/SiC/ Al 2 O 3 /ZrO 2 composites were fabricated. A powder mixture of 40 vol% Al, 30 vol% A1 2 O 3 and 30 vol% SiC was attrition milled in acetone with TZP balls which introduced a substantial ZrO 2 wear debris into the mixture. The precursor powder was isopressed at…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

Deposition and Characterization of Ferroelectric Pb[(Mg1/3Nb2/3)xTi1-x]O3 Thin Films by RF Magnetron Sputtering

Ming-Chrong Jiang、Tian-Jue Hong、Tai-Bor Wu Tai-Bor Wu1994-11-01Japanese Journal of Applied Physics

Ferroelectric Pb[(Mg 1/3 Nb 2/3 ) x Ti 1- x ]O 3 (PMNT) thin films with a well-developed perovskite structure were prepared on Si(100) and Pt/Ti/ SiO 2 /Si(100) substrates by rf magnetron sputtering deposition at high substrate temperatures of 480–650° C. The effect of substrate materials was investigated by X-ray dif…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Ordered and disordered phases in Al-Ni-Co decagonal quasicrystals

Keiichi Edagawa、Hiroharu Tamaru、Satoshi Yamaguchi 等 5 位作者1994-11-01Physical review. B, Condensed matter

The composition ranges of Al-Ni-Co decagonal quasicrystals in superlattice-ordered and disordered states have been investigated. The single-decagonal-phase region is limited to a very small area around ${\mathrm{Al}}_{71}$${\mathrm{Ni}}_{16}$${\mathrm{Co}}_{13}$ at 650 \ifmmode^\circ\else\textdegree\fi{}C, which expan…

Quasicrystal Structures and PropertiesMineralogy and Gemology Studies

Enhanced Electrochemical Deposition with an Atomic Force Microscope

John R. LaGraff、Andrew A. Gewirth1994-11-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEnhanced Electrochemical Deposition with an Atomic Force MicroscopeJohn R. LaGraff and Andrew A. GewirthCite this: J. Phys. Chem. 1994, 98, 44, 11246–11250Publication Date (Print):November 1, 1994Publication History Published online1 May 2002Published inissue 1 November 1994…

Hydrogen embrittlement and corrosion behaviors in metalsElectron and X-Ray Spectroscopy TechniquesAnodic Oxide Films and Nanostructures

Specific heat of the organic superconductor κ-(BEDT-TTF)2I3

J. Wosnitza、Xiaoxi Liu、D. Schweitzer 等 4 位作者1994-11-01Physical review. B, Condensed matter

We present high-resolution specific-heat, C, measurements on a large (4.47 mg) single crystal of \ensuremath{\kappa}-(BEDT-TTF${)}_{2}$${\mathrm{I}}_{3}$ from 0.25 to 20 K in zero and different magnetic fields. The electronic specific-heat coefficient in the normal state is extracted to \ensuremath{\gamma}=(18.9\ifmmo…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

Observation of four-coordinate aluminum oxynitride (AlO4-xNx) environments in AlON solids by MAS 27Al NMR at 14 T

John J. Fitzgerald、Scott D. Kohl、Gilberto Piedra 等 5 位作者1994-11-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTObservation of four-coordinate aluminum oxynitride (AlO4-xNx) environments in AlON solids by MAS 27Al NMR at 14 TJohn J. Fitzgerald, Scott D. Kohl, Gilberto Piedra, Steven F. Dec, and Gary E. MacielCite this: Chem. Mater. 1994, 6, 11, 1915–1917Publication Date (Print):Novemb…

Advanced ceramic materials synthesisSemiconductor materials and devicesBoron and Carbon Nanomaterials Research

The Layered Borates Ba3M(BO3)3 (M = Dy, Ho, Y, Er, Tm, Yb, Lu, and Sc)

James R. Cox、Douglas A. Keszler、Jinfan Huang1994-11-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Layered Borates Ba3M(BO3)3 (M = Dy, Ho, Y, Er, Tm, Yb, Lu, and Sc)James R. Cox, Douglas A. Keszler, and Jinfan HuangCite this: Chem. Mater. 1994, 6, 11, 2008–2013Publication Date (Print):November 1, 1994Publication History Published online1 May 2002Published inissue 1 No…

High-pressure geophysics and materialsCrystal Structures and PropertiesChemical Synthesis and Characterization

Metal-insulator transitions in La1-xTiO3, 0.0 .ltoreq. x .ltoreq. 0.33. structure-property correlations

M. J. MacEachern、H. A. Dabkowska、J. D. Garrett 等 7 位作者1994-11-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMetal-insulator transitions in La1-xTiO3, 0.0 .ltoreq. x .ltoreq. 0.33. structure-property correlationsM. J. MacEachern, H. Dabkowska, J. D. Garrett, G. Amow, Wenhe Gong, Guo Liu, and J. E. GreedanCite this: Chem. Mater. 1994, 6, 11, 2092–2102Publication Date (Print):Novembe…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Structure relationship to dielectric, elastic and chiral properties

S. C. Abrahams1994-11-01Acta Crystallographica Section A Foundations of Crystallography

Crystallography provides a major approach toward reaching an understanding of the relationship between crystal structure and material physical properties. The specific relationships of five highly structure dependent physical properties, namely piezoelectricity, pyroelectricity, ferroelectricity, ferroelasticity and o…

Acoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

Domain morphology in a two-dimensional anisotropic mesophase: Cusps and boojum textures in a Langmuir monolayer

Daniel K. Schwartz、Mei-Wei Tsao、Charles M. Knobler1994-11-01The Journal of Chemical Physics

Brewster angle microscopy (BAM) and polarized fluorescence microscopy (PFM) were used to observe domains of a tilted condensed phase in coexistence with an isotropic liquid phase in Langmuir monolayers of pentadecanoic acid. The orientation of the molecular tilt direction inside the domains can be described as a ‘‘vir…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsForce Microscopy Techniques and Applications

High‐performance X‐ray detection in a new analytical electron microscope

Charles E. Lyman、Joseph I. Goldstein、D. B. Williams 等 7 位作者1994-11-01Journal of Microscopy

Summary X‐ray detection by energy‐dispersive spectrometry in the analytical electron microscope (AEM) is often limited by low collected X‐ray intensity ( P ), modest peak‐to‐background ( P/B ) ratios, and limitations on total counting time (τ) due to specimen drift and contamination. A new AEM has been designed with m…

X-ray Spectroscopy and Fluorescence AnalysisNuclear Physics and ApplicationsElectron and X-Ray Spectroscopy Techniques