Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of electrolyte concentration on axial anion ligation in manganese(III) meso-tetraphenylporphyrin chloridesGarry J. Foran, Robert S. Armstrong, Maxwell J. Crossley, and Peter A. LayCite this: Inorg. Chem. 1992, 31, 8, 1463–1470Publication Date (Print):April 1, 1992Publ…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRapid versus intermediate electronic relaxation between S = 3/2 and S = 1/2 states in nitrosyl-iron complexes with Jaeger-type ligandsE. Koenig, G. Ritter, J. Dengler, and L. F. LarkworthyCite this: Inorg. Chem. 1992, 31, 7, 1196–1202Publication Date (Print):April 1, 1992Pub…
Calibration curves of extremely low concentrations of the alloying elements Sn, Fe, Cr and Ni in Zircaloy were obtained, using standard samples, by energy dispersive X-ray spectroscopy to measure concentration distributions of alloying elements dissolved in the Zircaloy matrix. Their detectable limits were 0.21 at% fo…
This study examines the biocompatibility of two different syn thetic copolymers; a water soluble copolymer based on [N-(2-hydroxypropyl) methacrylamide] (HPMA) and an insoluble polymer based on 2-hydroxyethyl methacrylate (HEMA). Activation of classical and alternative complement pathways, phagocytic function, bone ma…
A computer simulation program, based on a two sublattice model, is performed to analyze the magnetization process of ferromagnetic materials (like, for instance, RCo5 and R2Fe14B compounds). Without using the assumption of the existence of a small canting angle between the two sublattices, as has been used in the anal…
Abstract Some esters of (2‐hydroxypropyl) cellulose have been prepared and studied. Their cholesteric properties change with ageing and may disappear. Accelerated aging has been performed in order to analyze degradation processes which are relevant to the scission of the polymeric main chain and to the hydrolysis of t…
We report molecular-dynamics simulations of the anisotropic diffusion of infinitely thin platelets in the nematic phase. Our simulations are used to distinguish between the predictions of two different theories. The first theory, based on a mapping of the nematic phase of ellipsoidal particles on the hard-sphere fluid…
ω-Vinylpolydimethylsiloxanes (ω-PDMS) and α,ω-divynilpolydimethylsiloxanes (α,ω-PDMS) have been synthesized by anionic polymerization of hexamethylcyclotrisiloxane (D3). The reactions were carried out in n-hexane and tetrahydrofuran (THF), respectively. The initiator was n-butyl-lithium (n-BuLi); tetrahydrofuran was u…
A new procedure of pattern decomposition in energy-dispersive powder diffraction is presented. The total observed pattern is taken as a sum of incoherent and coherent scattering. The incoherent part is calculated from theoretical cross sections for individual atoms, the coherent part is described as a sum of discrete…
The characterisation of platinum group metals catalysts is commonly carried out by temperature-programmed reduction, the spectrum of which has been used as a “finger-print” of the reducibility of the catalyst. Recent literature suggests that the utility of temperature-programmed reduction can be further enhanced by co…
The formation of the oxides of nitrogen, NOx, is examined through experiments and chemical kinetic modeling for lean, premixed combustion in a laboratory, atmospheric pressure, jet-stirred reactor. The experimental conditions are as follows: fuel-air equivalence ratio (φ) of 0.6, temperatures of 1460 to 1730 K, and re…
We have studied the elastic recovery and inverse relaxation phenomena of polyester staple fiber rotor spun yarns. Better fiber orientation obtained with a drawing passage before spinning results in higher permanent deformation and lower delayed elastic recovery of the yarn. Yarn twist has little influence on elastic c…
A method is developed for computing the ion flow from an AC coronating wire above the ground plane, without resort to unnecessary simplifying assumptions. The emission of ions is considered to take place from the wire when the surface field of the wire exceeds the onset value. The space charges are simulated by discre…
Techniques for calculating overheating effects of GIC (geomagnetically induced currents) on large shell-form transformers are described. The techniques include: the method of calculating the exciting current and its harmonic content under DC injection in the transformer neutral; three-dimensional magnetic flux calcula…
We report on the development of a new coating design for applications in the vacuum ultraviolet that yields significantly higher reflectivity over selectable bandwidths. We demonstrate that the concept can be used to fabricate high-performance narrow-band and broadband reflection filters, whose spectral properties can…
Chemicals from various suppliers were tested for the metal contamination levels left on silicon wafers after cleaning. During the investigations, hydrochloric acids and ammonium hydroxides from three vendors and hydrogen peroxides from four vendors, were evaluated. The wafers were cleaned in RCA standard solutions, af…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCobalt-59 NMR of six-coordinate cobalt(III) tetraphenylporphyrin complexes. 4. The effect of phenyl ortho substituents on chemical shift, line width, and structureH. Bang, J. O. Edwards, J. Kim, R. G. Lawler, K. Reynolds, W. J. Ryan, and D. A. SweigartCite this: J. Am. Chem.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRelaxation enhancement of water protons by manganese(III) porphyrins: influence of porphyrin aggregationKenneth E. Kellar and Natalie FosterCite this: Inorg. Chem. 1992, 31, 8, 1353–1359Publication Date (Print):April 1, 1992Publication History Published online1 May 2002Publi…
The freezing behavior and the cluster formation in the liquid and supercooled-liquid state of monodeuterated 2-cyclooctylamino-5-nitropyridine have been studied by deuteron magnetic resonance and relaxation. The results show that the molecular dynamics is both polydispersive and non-Arrhenius-like. The data can be des…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxidative electropolymerization of iron and ruthenium complexes containing aniline-substituted 2,2'-bipyridine ligandsColin P. Horwitz and Qi ZuoCite this: Inorg. Chem. 1992, 31, 9, 1607–1613Publication Date (Print):April 1, 1992Publication History Published online1 May 2002…