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Pilhas a combustível de óxido sólido: materiais, componentes e configurações

Roberto Salgado Amado、Luiz Fernando B. Malta、Francisco Manoel dos Santos Garrido 等 4 位作者2007-02-01Química Nova

In this paper the current status of fuel cells is described with particular emphasis on high (T > 800 o C) and intermediate (T < 800 o C) temperature solid oxide fuel cells. Also the importance of the fuel cell technology is shown. Reviewed are the fundamental features, the basic principles, types of fuel cell, fabric…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel Cells

DNA Encapsulation Inside Carbon Nanotubes Using Micro Electrolyte Plasmas

Toshiro Kaneko、Takeru Okada、Rikizo Hatakeyama2007-02-01Contributions to Plasma Physics

Abstract DNA encapsulated carbon nanotubes are formed using a plasma ion irradiation method in electrolyte solutions with DNA, which can be regarded as electrolyte plasmas from the view point that the electrolyte solutions consist of positive and negative ions, and neutral particles in the same way as gas phase plasma…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesIon-surface interactions and analysis

Tissue Compatibility of Interfacial Polyelectrolyte Complexation Fibrous Scaffold: Evaluation of Blood Compatibility and Biocompatibility

Evelyn K. F. Yim、I‐Chien Liao、Kam W. Leong2007-02-01Tissue Engineering

Interfacial polyelectrolyte complexation (PEC) fiber has been proposed as a biostructural unit and biological construct for tissue engineering applications, with its ability to incorporate proteins, drug molecules, DNA nanoparticles, and cells. In this study, we evaluated the biocompatibility and blood compatibility o…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesPeriodontal Regeneration and Treatments

Rheological and Structure Investigation of Melt Mixed Multi‐Walled Carbon Nanotube/PE Composites

Maria Rosella Nobile、George P. Simon、O. Valentino 等 4 位作者2007-02-01Macromolecular Symposia

Abstract In this study a series of melt mixed multi‐walled carbon nanotube (MWNT)/Polyethylene composites with several carbon nanotube (CNTs) concentrations were investigated. A good dispersion of the nanotubes in the matrix was seen using scanning electron microscopy. Melt rheological measurements in dynamic mode wer…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Structure of WO3-TeO2 glasses

V. O. Sokolov、В. Г. Плотниченко、Е. М. Dianov2007-02-01Inorganic Materials

WO 3 -TeO 2 glasses have been studied by quantum-chemical simulation and Raman spectroscopy. The results have been used to develop a model for the network of tungstate-tellurite glasses. The model allows one to correlate the structure and optical properties (in particular, the position and intensity of Raman bands) of…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCatalysis and Oxidation Reactions

Competitive Surface Adsorption of Solvent Molecules and Compactness of Agglomeration in Calcium Hydroxide Nanoparticles

Emiliano Fratini、Miles Page、Rodorico Giorgi 等 7 位作者2007-02-01Langmuir

Calcium hydroxide forms unstable reactive nanoparticles that are stabilized when they are dispersed in ethylene glycol or 2-propanol. The aggregation behavior of these particles was investigated by contrast-variation small-angle neutron scattering (SANS), combined with small-angle X-ray scattering (SAXS). Nanoparticle…

Surfactants and Colloidal SystemsCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

Preparation and photocatalytic activity of PANI/TiO2 composite film

G JINZHANG、Shengying Li、Yu Wu 等 6 位作者2007-02-01Rare Metals

A PANI/TiO2 composite film deposited on the glass surface was successfully prepared using sol-gel dip-coating technique and chemical oxidation method. The film was characterized using XRD, AFM, and UV. The result showed that the TiO2 film consists of both cuboid-shaped and anatase-phased TiO2 nanoparticles. The averag…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesConducting polymers and applications

Microwave synthesis and photophysics of new tetrasulfonated tin(II) macrocycles

Samson Khene、Abimbola Ogunsipe、Edith Antunes 等 4 位作者2007-02-01Journal of Porphyrins and Phthalocyanines

This work reports on the microwave synthesis of tetrasulfonated tin phthalocyanine and tetrasulfonated tin α,β,γ-tetrabenzcorrole. The latter was only formed at low ratios (&lt;1:8) of 4-sulfophthalic acid to urea. Both complexes are aggregated in aqueous media, but can be partly or fully disaggregated by the addition…

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

MAPLE applications in studying organic thin films

M. Jelı́nek、T. Kocourek、Jan Remsa 等 6 位作者2007-02-01Laser Physics

Thin films of various organic materials have been created by the matrix assisted pulsed laser evaporation (MAPLE) technique. The principles, advantages, and difficulties of deposition are discussed. The focus is on target preparation, solvents, studied materials, and growth rate. Measured solvent transmissions and the…

Diamond and Carbon-based Materials ResearchMass Spectrometry Techniques and ApplicationsIon-surface interactions and analysis

MeV N+-ion irradiation effects on α-MoO3 thin films

R. Sivakumar、C. Sanjeeviraja、M. Jayachandran 等 7 位作者2007-02-01Journal of Applied Physics

In this work, modifications in the structural, vibrational, optical, and surface morphological properties of 2MeV N+-ion irradiated α-MoO3 thin films are studied. Nitrogen irradiation up to the fluence of 1×1015ionscm−2 does not lead to any structural phase change. The irradiation induced formation of nanoscale defect…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsIon-surface interactions and analysis

Biofunctional properties of polyester fibers grafted with chitosan and collagen

Chi‐Hsiung Jou、Shang‐Ming Lin、Yun Ling 等 8 位作者2007-02-01Polymers for Advanced Technologies

Abstract Poly(ethylene terephthalate) (PET) fiber was treated with 60 Co‐ γ ‐ray and grafted with acrylic acid (AA). The resulting fibers were further grafted with chitosan (CS) via esterification. Afterward collagen (COL) was immobilized onto CS‐grafting fibers. The antibacterial activity of CS against Staphylococus…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsAntimicrobial agents and applications

The effects of magnesium particles in posterolateral spinal fusion: an experimental in vivo study in a sheep model

Ramazan Alper Kaya、Halit Çavuşoğlu、Canan Tanık 等 8 位作者2007-02-01Journal of Neurosurgery Spine

OBJECT: Magnesium has recently become a material of interest as a biocompatible and biodegradable implant metal. Authors of several reports have noted the potential bone-cell activating or bone-healing effect of high Mg ion concentrations. The classic method for achieving intertransverse process fusion involves using…

Bone Tissue Engineering MaterialsSpine and Intervertebral Disc PathologyMagnesium Alloys: Properties and Applications

In Silico Prediction of Drug Solubility: 2. Free Energy of Solvation in Pure Melts

Kai Lüder、Lennart Lindfors、Jan Westergren 等 5 位作者2007-02-01The Journal of Physical Chemistry B

The solubility of drugs in water is investigated in a series of papers and in the current work. The free energy of solvation, DeltaG*(vl), of a drug molecule in its pure drug melt at 673.15 K (400 degrees C) has been obtained for 46 drug molecules using the free energy perturbation method. The simulations were perform…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesChemical Thermodynamics and Molecular Structure

The phase diagram and spinodal decomposition of metastable states of Lennard-Jones system

A. Yu. Kuksin、G. É. Norman、Vladimir Stegailov2007-02-01High Temperature

The method of molecular dynamics is used to treat the metastable states of Lennard-Jones crystal and liquid at different temperatures and pressures, including the negative-pressure region. Analysis is made of the pattern of relative position of surfaces of the equation of state of the crystal and liquid phases in the…

Material Dynamics and PropertiesTheoretical and Computational Physicsnanoparticles nucleation surface interactions

Carbon Combustion Synthesis of Ferrites: Synthesis and Characterization

Karen S. Martirosyan、Dan Luss2007-02-01Industrial & Engineering Chemistry Research

Submicrometer powders of Mn−Zn and Ni−Zn ferrites have been produced by carbon combustion synthesis of oxides (CCSO). The self-propagating temperature front had a maximum temperature of a up to 1300 °C and moved at a velocity 3.5 mm/s. Solid-state interactions between the precursors and crystal growth of the crystalli…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsSemiconductor materials and interfaces

Structure of gyroid mesophase formed by monodendrons with fluorinated alkyl tails

С. Н. Чвалун、Maxim A. Shcherbina、A. N. Yakunin 等 5 位作者2007-02-01Polymer Science Series A

The structure of a three-dimensional mesophase has been studied by the methods of small-angle X-ray diffraction and reconstruction of electron-density maps of the cubic lattice. In the oriented samples based on monodendrons with partially fluorinated alkyl tails, this mesophase has been shown to coexist with a two-dim…

Liquid Crystal Research AdvancementsPolymer Nanocomposites and PropertiesMesoporous Materials and Catalysis

Leakage current behavior in pulsed laser deposited Ba(Zr0.05Ti0.95)O3 thin films

Arnab Mukherjee、P. Victor、Jayanta Parui 等 4 位作者2007-02-01Journal of Applied Physics

Barium zirconium titanate [Ba(Zr0.05Ti0.95)O3, BZT] thin films were prepared by pulsed laser ablation technique and dc leakage current conduction behavior was extensively studied. The dc leakage behavior study is essential, as it leads to degradation of the data storage devices. The current-voltage (I-V) of the thin f…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Preparation and characterisation of ball-like MoS2 nanoparticles

Kunhong Hu、Y. R. Wang、Xianguo Hu 等 4 位作者2007-02-01Materials Science and Technology

Molybdenum sulphide (MoS x ) particles were prepared from Na 2 MoO 4 and CH 3 CSNH 2 by the quick homogenous precipitation method within 5 min in alcohol–water solution at 82°C and normal pressure. The prepared MoS x particles were studied by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), tran…

2D Materials and ApplicationsChalcogenide Semiconductor Thin FilmsMXene and MAX Phase Materials

Ionicity scale based on the centers of maximally localized Wannier functions

Hazem Abu‐Farsakh、A. Qteish2007-02-01Physical Review B

The maximally localized Wannier functions (MLWFs) of 32 ${A}^{N}{B}^{8\ensuremath{-}N}$ compounds, ranging from elemental group-IV solids to I-VII compounds, have been constructed according to the method of Marzari and Vanderbilt [Phys. Rev. B 56, 12847 (1997)]. The considered systems crystallize in the diamond, zinc-…

Semiconductor materials and devicesBoron and Carbon Nanomaterials ResearchX-ray Diffraction in Crystallography

Investigation on Relationship between Charge Transfer Position and Dielectric Definition of Average Energy Gap in Eu3+-Doped Compounds

Ling Li、Shihong Zhou、Siyuan Zhang2007-02-01The Journal of Physical Chemistry C

The dielectric definition of average energy gap E g of the chemical bond has been calculated quantitatively in Eu 3+ -doped 30 lanthanide compounds based on the dielectric theory of chemical bond for complex structure crystals. The relationship between the experimental charge transfer (CT) energy of Eu 3+ and the corr…

Ferroelectric and Piezoelectric MaterialsSolid-state spectroscopy and crystallographyMicrowave Dielectric Ceramics Synthesis