Materials Literature
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The crystal structure of [OCr3(CH3COO)6.3H20]+C1 -. 6H20 has been determined from three-dimensional diffractometer data using Cu Ke radiation. The configuration of the complex cation consists of three chromium atoms linked to a central oxygen atom in a planar configuration. Each chromium atom is coordinated octahedral…
A comparison between the ultraviolet-reflectivity spectrum and the characteristic energy-loss spectrum of ZnO has been carried out. Reflectivity measurements made over an energy range of band gap to 22 eV yielded a spectrum with structure at 3.34, 5.0, 7.3, and 8.4 eV, and in the region 11-15 eV. Energy-loss measureme…
The theory of dielectric relaxation in a model polar liquid is developed and applied to experimental data. The model is a spherical Onsager cavity, with a uniform dielectric background described by the high frequency limit ε∞ and containing a permanent point dipole. The dipole moment undergoes rotational Brownian moti…
The 5D emissions of Eu3+ in Y2O2S, La2O2S, and LaOCl quench sequentially with increasing temperature in the simple order 5D3, 5D2, 5D1, 5D0. These 5D quenchings are attributed to thermally activated resonance crossovers from the 5D states to the charge-transfer states (CTS). The activation energies for the 5D quenchin…
The electronic band structure of graphite has been calculated from an ab initio variational approach using a linear-combination of atomic-orbitals (LCAO) basis of Bloch states, including nonspherical terms in the one-electron crystal potential. Matrix elements of the Hamiltonian are evaluated directly without any tigh…
El presente trabajo comprende el estudio taxonómico de catorce especies de equinoides, de las que diez son regulares y cuatro son irregulares. Entre las irregulares, dos especies son nuevas: Heteraster aguilerai n. sp. y Heteraster alencasterae n. sp. La colección de equinoides estudiada proviene de las formaciones Za…
The far-infrared spectra of thin films of PH4Cl and PD3Cl have been recorded at −170°C. Raman spectra of polycrystalline samples of both compounds were also recorded at −170°C. One libration and three translations were observed as well as eight internal modes. Several combinations and overtones were assigned and the z…
Some relationships between crystal textures and their permanent magnet properties are reviewed on the basis of a homogeneous uniaxial anisotropic ferromagnet and a mosaic grain agglomerate in the commercial size of an Alnico 8 alloy. From the results obtained, it has been concluded that the highest energy might be obt…
Solutions of N 2 O in liquid formamide (dielectric constant 109) gave a yield of N 2 during γ-radiolysis of G(N 2 ) = 3.3 ± 0.3. Competition between N 2 O and other scavengers, including water, ethanol, acids, AgNO 3 , and CdI 2 strongly resembled the pattern of reactivity characteristic of solvated electrons found in…
The paper reviews the development and application of tungsten halogen lamps since their first introduction. The halogen cycle is described and the advantages of using bromine compounds in the fill gas of some halogen lamps are indicated. Many problems have arisen from the use of halogens; the ways in which these have…
The energy distribution of electrons in a part of the electron beam selected by two apertures situated on the axis was measured using a wienfilter-type energy analyser. These measurements gave brightness values for electrons in specific energy intervals of the distribution which fitted the theory extremely well. The i…
Single crystals of Al 2 O 3 (sapphire) were grown from PbO‐PbF 2 and MoO 3 ‐PbF 2 fluxes; they varied from flat plates (PbF 2 ‐rich melts) to equidimensional crystals (PbO‐ or MoO 3 ‐rich melts). The primary growth planes are basal {0001}, first‐order rhombohedral {1011}, and second‐order rhombohedral {0112}. The habi…
For Alnico alloys containing 32-42 percent Co, 0-9 percent Ti, 6-8 percent Al, 14 percent Ni, 3 percent Cu, 0-0.5 percent S, 0-2 percent Nb, remainder Fe, the liquidus and solidus temperatures and the upper limit of the (α + γ) phase field were determined. The greatest influence is exerted by titanium in that all temp…
Precipitation and dissolution potentials for KCl, NaCl, BaCl2, and NH4Cl have been measured with a Lindemann electrometer both in air as well as in nitrogen. The values in the latter case are lower. The electrode on which precipitation and dissolution takes place is found to be negative. The available evidence shows t…
The magnitude of the thermal hysteresis exhibited by cholesteric liquid crystals is mainly dependent upon the material composition of the system and the operating range.
Silicate glass containing arsenic as a diffusant into silicon was studied. The glass was deposited on a heated silicon substrate in the atmosphere of mixture of tetra-ethyl ortho-silicate vapor, arsenic trichloride vapor and oxygen gas between 500–700°C. The structure of the glass and its changes with heat treatments…
The heat-transfer properties of 10 underwear-outerwear ensembles were determined in the laboratory by using a heated "sweating" sectional manikin. Theoretically, by applying the i m theory to these results, a Nomex underwear-Nomex outerwear ensemble showed a slightly greater environmental range. However, little differ…
The reduction by hydrogen of Fe 3+ , Ce 4+ , and Sn 4+ in soda‐lime‐silica glass was found to be diffusion‐limited in the glass transition temperature range (500°C). The reduction was studied in fibers by chemical analysis and in bulk samples by optical absorption. Reduction to Fe 2+ , Ce 3+ , and Sn 2+ proceeds by a…
X-ray and magnetic studies have been made on the intermetallic compound Co 3+ x Ti 1- x . X-ray study indicates that Co 3+ x Ti 1- x with the Cu 3 Au-type structure has the phase field ranging from about 20.5 to 25.0 at. % Ti( x =0.180∼0) below 1,000°C. According to magnetic measurements, Co 3 Ti( x =0) is a paramagne…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAntiferromagnetism in transition metal complexes. III. Ground and low-lying excited states of cupric acetateR. W. Jotham and Sidney F. A. KettleCite this: Inorg. Chem. 1970, 9, 6, 1390–1395Publication Date (Print):June 1, 1970Publication History Published online1 May 2002Pub…