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1H-NMR study of water dynamics in hydrated collagen: Transverse relaxation-time and diffusion analysis

A. Traoré、L. Foucat、J. P. Renou2000-05-01Biopolymers

Water proton transverse relaxation times (T2) and self-diffusion coefficients (D) were measured in randomly oriented hydrated collagen fibers. Three T2 relaxation times were discerned indicating the presence of at least three water fractions in the collagen sample. The D values associated with each water fraction were…

Bone health and osteoporosis researchCollagen: Extraction and CharacterizationNMR spectroscopy and applications

Preparation and magnetic properties of Ba–Co2Z and Sr–Zn2Y ferrites

In‐Gann Chen、Shu-Hau Hsu、Yu-Hsuan Chang2000-05-01Journal of Applied Physics

We have prepared Ba–Co2Z and Sr–Zn2Y ferrites by mixing SrCO3 (BaCO3), Co2O3 (ZnO), and Fe2O3 and calcinating in air and O2. The effects of sintering atmosphere (O2 and Ar) and sintering temperatures (1373–1573 K) on the structural, magnetic, and electrical properties have been measured. The Ba–Co2Z sample sintered at…

Advancements in Battery MaterialsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

First-principles molecular-dynamics study of glassyAs2Se3

Jun Li、D. A. Drabold2000-05-01Physical review. B, Condensed matter

A first-principles molecular-dynamics study of glassy ${\mathrm{As}}_{2}{\mathrm{Se}}_{3},$ using a 215-atom model, is presented. Our model is in good and uniform agreement with available measurements of the structural, vibrational, and electronic properties. The model reproduces the structure of the experimental stat…

Glass properties and applicationsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Thermal characterization of film-on-substrate systems with modulated thermoreflectance microscopy

Bincheng Li、L. T. Le Pottier、J.P. Roger 等 5 位作者2000-05-01Review of Scientific Instruments

Computer simulations are performed in this article to show the feasibility of simultaneous determination of the film diffusivity, the substrate diffusivity, and the thermal boundary resistance of film-on-substrate systems by modulated thermoreflectance microscopy and multiparameter fitting. The dependences of the phas…

Thermal properties of materialsThermography and Photoacoustic TechniquesThermal Radiation and Cooling Technologies

Synthesis of quasicrystalline phase by mechanical alloying of Al70Cu20Fe10

P. Barua、V. Srinivas、B.S. Murty2000-05-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

An icosahedral phase (i-phase) has been synthesized by mechanical alloying of an elemental blend of Al70Cu20Fe10. Mechanical alloying of Al and Fe in the stoichiometric ratio of 3:1 and continued milling after the addition of Al and Cu to yield the nominal composition of Al70Cu20Fe10 does not result in the i-phase for…

Microstructure and mechanical propertiesQuasicrystal Structures and Properties

Plasma-assisted molecular beam epitaxy for ZnO based II–VI semiconductor oxides and their heterostructures

Yefan Chen、Hang-Ju Ko、Soon‐Ku Hong 等 6 位作者2000-05-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Plasma-assisted molecular beam epitaxy of ZnO epilayers and MgZnO/ZnO heterostructures on Al2O3(0001) substrates is described. A thin MgO layer is employed as a buffer for ZnO. The influence of the buffer on the initial growth of ZnO is discussed with the corresponding reflection high-energy electron diffraction (RHEE…

ZnO doping and propertiesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Exit wave reconstructions using through focus series of HREM images

H.W. Zandbergen、D. Van Dyck2000-05-01Microscopy Research and Technique

The through focus exit wave reconstruction technique uses a series of high resolution electron microscopy images to reconstruct the complex electron wavefunction at the exit plane of the specimen. The feasibility of the through focus exit wave reconstruction method and its most important limitations are discussed. It…

Advanced Electron Microscopy Techniques and ApplicationsNuclear Physics and ApplicationsElectron and X-Ray Spectroscopy Techniques

Magnetization canting in epitaxial Cu/Ni/Cu/Si(001) films

K. Ha、Robert C. O’Handley2000-05-01Journal of Applied Physics

The magnetic anisotropy of epitaxial Cu(50 Å)/Ni(tNi/Cu(2000 Å)/Si(001) films as a function of the nickel film thickness (30 Å⩽tNi⩽150 Å) has been studied using a torque magnetometer. It is found that the magnetization rotates continuously from out-of-plane to in-plane as the nickel film thickness increases. For the 1…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

Interactions between Pyruvate and Lactate Metabolism in Propionibacterium freudenreichii subsp. shermanii : In Vivo 13 C Nuclear Magnetic Resonance Studies

Catherine Deborde、Patrick Boyaval2000-05-01Applied and Environmental Microbiology

In vivo (13)C nuclear magnetic resonance spectroscopy was used to elucidate the pathways and the regulation of pyruvate metabolism and pyruvate-lactate cometabolism noninvasively in living-cell suspensions of Propionibacterium freudenreichii subsp. shermanii. The most important result of this work concerns the modific…

Mitochondrial Function and PathologyEnzyme Structure and FunctionBiochemical Acid Research Studies

Infrared phonon spectrum of pure and dopedLaMnO3

A. Paolone、Pascale Le Roy、A. Pimenov 等 6 位作者2000-05-01Physical review. B, Condensed matter

The infrared reflectance spectra of two ${\mathrm{LaMnO}}_{3}$ crystals (pure and doped) have been measured at various temperatures between 300 and 10 K. The infrared active phonons of the two samples have been studied in detail and have been compared to recent lattice dynamics calculations. In the case of the undoped…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsSolid-state spectroscopy and crystallography

Magnetic ordering in M(ox)(bpy) system (M=Fe, Co, Ni; ox=C2O42−; bpy=4,4′-bipyridine)

Tan Yuen、Cai‐Xia Lin、T.W. Mihalisin 等 5 位作者2000-05-01Journal of Applied Physics

The temperature and field dependence of the magnetization have been measured to investigate the magnetic properties of the first oxalate–bpy mixed-ligand framework with a general formula M(ox)(bpy) (M = Fe(II), Co(II), Ni(II); ox = C2O42−; bpy = 4,4′-bipyridine). All compounds in the M(ox)(bpy) system crystallize in a…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Laser pyrolysis fabrication of ferromagnetic γ′-Fe4N and FeC nanoparticles

Craig A. Grimes、Dong Qian、Elizabeth C. Dickey 等 5 位作者2000-05-01Journal of Applied Physics

Using the laser pyrolysis method, single phase gamma'-Fe4N nanoparticles were prepared by a two step method involving preparation of nanoscale iron oxide and a subsequent gas-solid nitridation reaction. Single phase Fe3C and Fe7C3 could be prepared by laser pyrolysis from Fe(CO)5 and 3C2H4 directly. Characterization t…

Diamond and Carbon-based Materials ResearchElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Microwave properties of pulsed laser deposited Sc-doped barium hexaferrite films

P. Shi、S. D. Yoon、Xu Zuo 等 6 位作者2000-05-01Journal of Applied Physics

The properties of thick BaScxFe12−xO19 (0.3<x<0.6) scandium hexaferrite films were measured by static and microwave field techniques. Films were deposited by pulsed laser ablation onto c-plane sapphire at oxygen pressures of 20 and 50 mTorr. Vibrating sample magnetometer measurements as corroborated by x…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesMagnetic Properties and Applications

Behavior of μMAG standard problem No. 2 in the small particle limit

M. J. Donahue、D. G. Porter、R. D. McMichael 等 4 位作者2000-05-01Journal of Applied Physics

For a uniformly magnetized rectangular particle with dimensions in the ratio 5 : 1 : 0.1, the coercive and switching fields in the (1,1,1) direction are determined to be Hc/Ms=0.057069478 and Hs/Ms=0.057142805. Previous micromagnetic computations of coercive and switching fields that did not approach these values for…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Titanium oxide films on Si(100) deposited by electron-beam evaporation at 250 °C

Hyunchul Jang、S. W. Whangbo、H. B. Kim 等 10 位作者2000-05-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Titanium oxide films with a thickness of a 400 nm were deposited on p-type Si(100) at 250 °C by electron-beam evaporation where titanium dioxide was evaporated in oxygen environment at a pressure of 2×10−6–4×10−5 Torr. Effects of oxygen flow rate (FO2) between 0 and 40 sccm on properties such as crystallinity, surface…

ZnO doping and propertiesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Physiology and continuous culture of the hyperthermophilic deep-sea vent archaeonPyrococcus abyssiST549

Anne Godfroy、Neil Raven、Richard Sharp2000-05-01FEMS Microbiology Letters

The deep-sea vent archaeon Pyrococcus abyssi strain ST549 was grown in batch cultures in closed bottles and by continuous culture in a gas-lift bioreactor, both in the presence and in the absence of elemental sulfur. Growth on carbohydrates, proteinaceous substrates and amino acids was investigated. The disaccharides…

Microbial Community Ecology and PhysiologyProtist diversity and phylogenyDiatoms and Algae Research

The Collagen-like Peptide (GER)15GPCCG Forms pH-dependent Covalently Linked Triple Helical Trimers

Diane E. Mechling、Hans Peter Bächinger2000-05-01Journal of Biological Chemistry

A collagen-like peptide with the sequence (GER)(15) GPCCG was synthesized to study the formation of a triple helix in the absence of proline residues. This peptide can form a triple helix at acidic and basic pH, but is insoluble around neutral pH. The formation of a triple helix can be used to covalently oxidize the c…

biodegradable polymer synthesis and propertiesProtein Hydrolysis and Bioactive PeptidesCollagen: Extraction and Characterization

Hydrogen production in ?-ray and helium-ion radiolysis of polyethylene, polypropylene, poly(methyl-methacrylate), and polystyrene

Z. Chang、Jay A. LaVerne2000-05-01Journal of Polymer Science Part A Polymer Chemistry

The production of molecular hydrogen in the radiolysis of high-density polyethylene, isotactic polypropylene (PP), poly(methyl-methacrylate) (PMMA), and polystyrene (PS) by γ rays and 5–20-MeV helium ions was investigated. Molecular hydrogen is the dominant gaseous product from these polymers, and the yields with γ ra…

Polymer Nanocomposites and PropertiesRadiation Shielding Materials AnalysisPolymer Nanocomposite Synthesis and Irradiation

High-pressure transitions of trigonalα−ZrMo2O8

Stefan Carlson、Anne Marie Krogh Andersen2000-05-01Physical review. B, Condensed matter

High-pressure synchrotron x-ray powder-diffraction studies show that trigonal $\ensuremath{\alpha}\ensuremath{-}{\mathrm{ZrMo}}_{2}{\mathrm{O}}_{8}$ transforms to a monoclinic symmetry phase $(\ensuremath{\delta}\ensuremath{-}{\mathrm{ZrMo}}_{2}{\mathrm{O}}_{8})$ at 1.06--1.11 GPa. The space group was determined to $C…

Ferroelectric and Piezoelectric MaterialsInorganic Chemistry and MaterialsThermal Expansion and Ionic Conductivity

Flow-Induced Silica Structure during in Situ Gelation of Wormy Micellar Solutions

Wonjong Kim、Seung‐Man Yang2000-05-01Langmuir

In this study, we observed the flow-induced silica structure, which was formed during in situ gelation in the presence of wormlike micelles of cetyltrimethylammonium bromide and structure-forming additive, sodium salicylate. A silicon alkoxide of tetramethyl orthosilicate was used for the in situ gelation as a precurs…

Photonic Crystals and ApplicationsMesoporous Materials and CatalysisPickering emulsions and particle stabilization