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Application of a water jet system to the pretreatment of cellulose

Yuka Watanabe、Shinichi Kitamura、Kazunori Kawasaki 等 7 位作者2011-06-22Biopolymers

Plant cellulose is the most abundant organic compound on earth. Technologies for producing cellulose fiber or improving the enzymatic saccharification of cellulose hold the key to biomass applications. A technology for atomizing biomass without strong acid catalysis remains to be developed. The water jet is a well-kno…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Bis‐Azobenzene Crosslinkers for Photocontrol of Peptide Structure

Subhas Samanta、G. Andrew Woolley2011-06-22ChemBioChem

Crosslinkers that undergo large changes in length upon photoisomerization can produce large conformational changes, and thereby functional changes, in biomolecules. We have designed and synthesized extended and rigid bis-azobenzene crosslinkers: 4,4'-bis(4-(2-chloroacetamido)phenyl)diazenylbiphenyl (BPDB) and the wate…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Li experiments on T-11M and T-10 in support of a steady-state tokamak concept with Li closed loop circulation

С. В. Мирнов、É. A. Azizov、A.G. Alekseev 等 8 位作者2011-06-22Nuclear Fusion

This paper presents a review of the last T-11M and T-10 tokamak activity in the field of Li plasma facing component (PFC) investigation. Attention is mainly paid to the realization of the concept of closed loop lithium circulation as a solution of the PFC problem of a steady-state DT volumetric neutron source on a tok…

Magnetic confinement fusion researchFusion materials and technologiesSuperconducting Materials and Applications

La Complex@Fe–PILM Offering Resilient Option for Efficient and Green Processing toward Epoxidation of Cyclohexene

G. Bishwa Bidita Varadwaj、Swagatika Sahu、Kulamani Parida2011-06-22Industrial & Engineering Chemistry Research

An overview focused on the synthesis, structural features, and catalytic applications of lanthanum salen complex heterogenized in iron pillared montmorillonite is described here. In this approach the pillaring species was introduced in the interlayers of montmorillonite by a simple cation-exchange mechanism. The mater…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and Applications

Role of rigidity and temperature in the kinetics of photodarkening in Ge_xAs_(45-x)Se_55 thin films

A. R. Barik、K. V. Adarsh、Ramakanta Naik 等 8 位作者2011-06-22Optics Express

We present insightful results on the kinetics of photodarkening (PD) in Ge(x)As(45-x)Se55 glasses at the ambient and liquid helium temperatures when the network rigidity is increased by varying x from 0 to 16. We observe a many fold change in PD and its kinetics with decreasing network flexibility and temperature. Mor…

Liquid Crystal Research AdvancementsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Helical Assemblies of Gold Nanoparticles

G. Daniel Lilly、Ashish Agarwal、Suchi Srivastava 等 4 位作者2011-06-22Small

Chiral metallic nanohelices with periodicity in the submicrometer regime are made from twisted CdTe nanoribbons. These helices are highly effective in polarization rotation at wavelengths centered at their pitch length. Interestingly, the chiro-optical performance of helical nanoparticle assemblies is better than that…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchLiquid Crystal Research Advancements

Homogeneous and isotropic bends to tunnel waves through multiple different/equal waveguides along arbitrary directions

Tiancheng Han、Cheng‐Wei Qiu、Jian‐Wen Dong 等 5 位作者2011-06-22Optics Express

We propose a novel optical transformation to design homogeneous isotropic bends connecting multiple waveguides of different cross sections which can ideally tunnel the wave along any directions through multiple waveguides. First, the general expressions of homogeneous and anisotropic parameters in the bend region are…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsAdvanced Antenna and Metasurface Technologies

Preparation of biopolymer film from chitosan modified with lipid fraction

Vanderlei C. Souza、Micheli L. Monte、Luiz Antônio de Almeida Pinto2011-06-22International Journal of Food Science & Technology

Summary Films formed from polysaccharides, as chitosan, present a high permeability in water vapour. In order to increase resistance to water vapour for chitosan‐based films, different lipid fractions were incorporated into a filmogenic matrix: fish and vegetable oils, stearic and oleic acids. The chitosan showed a mo…

Advanced Sensor and Energy Harvesting MaterialsNanocomposite Films for Food PackagingPolydiacetylene-based materials and applications

Gold nanoparticles supported on magnesium oxide for CO oxidation

Sónia AC Carabineiro、Nina Bogdanchikova、Alexey Pestryakov 等 6 位作者2011-06-22Nanoscale Research Letters

Au was loaded (1 wt%) on a commercial MgO support by three different methods: double impregnation, liquid-phase reductive deposition and ultrasonication. Samples were characterised by adsorption of N2 at -96°C, temperature-programmed reduction, high-resolution transmission electron microscopy, energy-dispersive X-ray…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanomaterials for catalytic reactions

Extrusion of Magnesium Tubes for Biodegradable Stent Precursors

Q. Ge、Maurizio Vedani、G. Vimercati2011-06-22Materials and Manufacturing Processes

Production of stent precursors in the form of small-size tubes has been evaluated by hot compression tests and extrusion trials on the AZ31B and ZM21 magnesium alloys. The investigation here presented mainly reports on the effects of extrusion parameters on microstructure and properties of the tubes. Processing at 410…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Calcined Mg–Al Layered Double Hydroxides for Uptake of Trace Levels of Bromate from Aqueous Solution

Ramesh Chitrakar、Takaaki Sonoda、Yoji Makita 等 4 位作者2011-06-22Industrial & Engineering Chemistry Research

Layered double hydroxides of Mg and Al (Mg–Al LDH) were synthesized with OH –, Cl –, or CO 3 2– as charge compensating anions. The materials were calcined at 500 °C in air. The bromate uptakes of calcined and uncalcined LDH materials were investigated from 0.78 μmol/dm 3 bromate solution. Results show that uncalcined…

Layered Double Hydroxides Synthesis and ApplicationsChemical Synthesis and CharacterizationMagnesium Oxide Properties and Applications

Multiscale thermodynamics and mechanics of heat

Miroslav Grmela、G. Lebon、Charles Dubois2011-06-22Physical Review E

Heat transfer is investigated on three levels of description: Fourier, Cattaneo, and Peierls. The microscopic nature of the heat that becomes important, in particular in nanoscale systems, is characterized by a vector field related to the heat flux on the Cattaneo level and by the phonon distribution function on the P…

Thermal properties of materialsAdvanced Thermodynamics and Statistical MechanicsThermoelastic and Magnetoelastic Phenomena

Cycloaliphatic epoxy oligosiloxane‐derived hybrid materials for a high‐refractive index LED encapsulant

SeungCheol Yang、Joon‐Soo Kim、Jungho Jin 等 5 位作者2011-06-22Journal of Applied Polymer Science

Abstract Cycloaliphatic epoxy oligosiloxane resins with a high degree of condensation (>85%) were synthesized by a nonhydrolytic sol–gel reaction using 2‐(3,4‐epoxycyclohexyl)ethyltrimethoxysilane (ECTS), diphenylsilanediol (DPSD), and triphenylsilanol (TPS). Cycloaliphatic epoxy hybrimers with 2 mm thickness fabri…

Polymer composites and self-healingSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Differences in Soil Mobility and Degradability between Water-Dispersible CdSe and CdSe/ZnS Quantum Dots

Divina A. Navarro、Sarbajit Banerjee、David F. Watson 等 4 位作者2011-06-22Environmental Science & Technology

The relative leaching potential and degradation of water-dispersible CdSe and CdSe/ZnS quantum dots (QDs) were evaluated using small-scale soil columns. The potential of QDs to release toxic Cd(2+) and/or Se(2-)/SeO(3)(2-) ions upon degradation is of environmental concern and warrants investigation. Both classes of QD…

Quantum Dots Synthesis And PropertiesPharmaceutical and Antibiotic Environmental ImpactsCarbon and Quantum Dots Applications

Optimization of the procedure to burn textile fabrics by cone calorimeter: part II. Results on nanoparticle‐finished polyester

Jennifer Tata、Jenny Alongi、Alberto Frache2011-06-22Fire and Materials

SUMMARY Commercial polyester textiles have been finished with hydrotalcite, nanometric titania and silica aqueous suspensions and further characterised in order to investigate their combustion behaviour. Two different features of the finishing procedure have been studied: the role of immersion time and the pH suspensi…

Polymer Nanocomposites and PropertiesFire dynamics and safety researchFlame retardant materials and properties

Enhanced Crystallization of Bisphenol A Polycarbonate in Thin and Ultrathin Films by Supercritical Carbon Dioxide

Qiaofeng Lan、Jian Yu、Jun Zhang 等 4 位作者2011-06-22Macromolecules

The crystallization behavior of thin bisphenol A polycarbonate (PC) films after treatment in supercritical CO 2 (ScCO 2 ) was investigated by using polarized optical microscopy (POM) and atomic force microscopy (AFM). Experimental results indicated that the crystallization ability in thin PC film of 259 nm thick was h…

Polymer crystallization and propertiesPhase Equilibria and ThermodynamicsPolymer Foaming and Composites

Theory of Programmable Hierarchic Self-Assembly

Alexei V. Tkachenko2011-06-22Physical Review Letters

We present a theoretical analysis of the inverse problem in self-assembly. A particular scheme is proposed for building an arbitrary desired nanostructure out of self-assembled building blocks ("octopus" nanoparticles). The conditions for robust self-assembly of the target structure are identified. This includes the m…

Gold and Silver Nanoparticles Synthesis and ApplicationsSupramolecular Self-Assembly in MaterialsPickering emulsions and particle stabilization

Structural and Size Effects on the Spectroscopic and Redox Properties of CdSe Nanocrystals in Solution: The Role of Defect States

Matteo Amelia、Stefania Impellizzeri、Simone Monaco 等 7 位作者2011-06-22ChemPhysChem

Two series of CdSe quantum dots (QDs) with different diameters are prepared, according to frequently used protocols of the same synthetic procedure. For each sample the photophysical properties and the potentials for the first reduction and oxidation processes in organic solution are determined. The band gap obtained…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Carbon Nanotubes Enhance Cytotoxicity Mediated by Human Lymphocytes In Vitro

Zhao Sun、Zhe Liu、Jie Meng 等 12 位作者2011-06-22PLoS ONE

With the expansion of the potential applications of carbon nanotubes (CNT) in biomedical fields, the toxicity and biocompatibility of CNT have become issues of growing concern. Since the immune system often mediates tissue damage during pathogenesis, it is important to explore whether CNT can trigger cytotoxicity thro…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsAnesthesia and Neurotoxicity Research

Graphene Magnetoresistance Device in van der Pauw Geometry

Jianming Lü、Haijing Zhang、Wu Shi 等 9 位作者2011-06-22Nano Letters

We have fabricated extraordinary magnetoresistance (EMR) device, comprising a monolayer graphene with an embedded metallic disk, that exhibits large room temperature magnetoresistance (MR) enhancement of up to 55,000% at 9 T. Finite element simulations yield predictions in excellent agreement with the experiment and s…

Advancements in Battery MaterialsGraphene research and applicationsGraphene and Nanomaterials Applications