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Piezoelectric Properties of Ba and Ca Doped SrBi2Nb2O9Based Ceramic Materials

Akira Ando、Masahiko Kimura、Yukio Sakabe2003-02-15Japanese Journal of Applied Physics

The crystalline structure and dielectric and piezoelectric properties of SrBi 2 Nb 2 O 9 (SBN)-based materials were investigated with the substitution of Ca and Ba ions into the Sr site in this study. X-ray diffraction analysis revealed that these substitutes formed solid solutions throughout the compositions. The Ca…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Effect of Annealing on Thermoelectric Properties of Bismuth Telluride Compounds

Osamu Yamashita、Shōichi Tomiyoshi2003-02-15Japanese Journal of Applied Physics

The thermoelectric properties of the p -type (Bi 0.25 Sb 0.75 ) 2 Te 3 doped with 3 wt% excess Te and the n -type Bi 2 (Te 0.94 Se 0.06 ) 3 doped substantially with 0.07 wt% I and 0.02 wt% Te which were grown by the Bridgman method at a rate of 6 cm/h were measured before and after annealing, where the annealing was d…

Advanced Thermoelectric Materials and DevicesAdvanced Semiconductor Detectors and MaterialsThermodynamic and Structural Properties of Metals and Alloys

Renormalized Ellipsometry for Determining the Anisotropic Refractive Indices of Nematic Liquid Crystals

Norihiko Tanaka、Mumehiro Kimura、Tadashi Akahane2003-02-15Japanese Journal of Applied Physics

Renormalized transmission ellipsometry was applied to the precise measurement of anistropic refractive indices of nematic liquid crystals. It is quite beneficial for electrical industry that the conventional sandwich-type liquid crystal cell becomes an applicable sample and experimental measurement can be carried out…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyOptical Polarization and Ellipsometry

The Lowest Photoexcited Triplet State of Subphthalocyanine in Solid and Fluid Environments. Time-Resolved Electron Paramagnetic Resonance Studies

Seigo Yamauchi、Akihiro Takahashi、Yohei Iwasaki 等 8 位作者2003-02-15The Journal of Physical Chemistry A

Time-resolved EPR spectra of the lowest excited triplet state of boron subphthalocyanine chloride have been measured in toluene at various temperatures (5−360 K). On the basis of the observed and simulated spectra, electronic structure and molecular motion of the triplet state ( 1 T) were analyzed, both in solid and f…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Low-Temperature Synthesis Multiwalled Carbon Nanotubes by Microwave Plasma Chemical Vapor Deposition Using CH4–CO2Gas Mixture

Mi Chen、Chieng‐Ming Chen、Shih-Chen Shi 等 4 位作者2003-02-15Japanese Journal of Applied Physics

Vertically aligned carbon nanotubes (CNTs) with multiwalled structures were successfully grown on a Fe-deposited Si substrate at low temperatures below 300°C by microwave plasma chemical vapor deposition using of a CH 4 –CO 2 gas mixture. The low temperature would be beneficial for reducing the diameter of CNTs but it…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

New Stacking Variations of the Charge and Orbital Ordering in the Metal-Ordered Manganite YBaMn2O6

Hiroshi Kageyama、Tomohiko Nakajima、Masaki Ichihara 等 6 位作者2003-02-15Journal of the Physical Society of Japan

For the paramagnetic insulating phase in the metal-ordered manganite YBaMn2O6, the so-called CE-type of charge/orbital ordered state was observed within the monoclinic ab-plane, which is most commonly observed for the ordinary half doped manganites. However, TEM revealed a 4-fold periodicity along the c-axis, suggesti…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Possible Charge Ordering Patterns of the Paramagnetic Insulating States in (TMTTF)2X

Toshikazu Nakamura2003-02-15Journal of the Physical Society of Japan

ESR investigations were performed for a series of quasi-one-dimensional organic conductors, (TMTTF) 2 X . The ESR linewidth shows abrupt jumps or humps in the paramagnetic insulating region. The (TMTTF) 2 X salts are roughly divided into three groups according to the anisotropy of the ESR linewidth at low temperatures…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchN-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Efficient 355-nm generation in CsB_3O_5 crystal

Houichi Kitano、Tatsunosuke Matsui、Kazunobu Sato 等 7 位作者2003-02-15Optics Letters

We demonstrate UV generation in CSB3O5 (CBO) crystals grown by the top-seeded solution growth technique. 355-nm UV light was generated by use of a type II CBO crystal as a sum frequency of the fundamental light and the second harmonic of a nanosecond Nd:YVO4 laser. A 3.0-W output of the third-harmonic was obtained at…

Crystal Structures and PropertiesPhotorefractive and Nonlinear OpticsSolid State Laser Technologies

Oxidation States of Gold in MgO-Supported Complexes and Clusters: Characterization by X-ray Absorption Spectroscopy and Temperature-Programmed Oxidation and Reduction

Javier Guzmán、Bruce C. Gates2003-02-15The Journal of Physical Chemistry B

X-ray absorption near edge structure (XANES) spectroscopy, temperature-programmed reduction (TPR), and temperature-programmed oxidation (TPO) were used in combination to determine the oxidation states of gold in clusters and complexes supported on MgO. The samples were also characterized by X-ray absorption fine struc…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanocluster Synthesis and Applications

Characterization of the Cu+ Sites in High-Silica Zeolites Interacting with the CO Molecule: Combined Computational and Experimental Study

Markéta Davidová、Dana Nachtigallová、Roman Bulánek 等 4 位作者2003-02-15The Journal of Physical Chemistry B

Interactions of the CO molecule with the Cu + sites within MFI and FER matrices were investigated by means of the combined quantum mechanics/interatomic potential function method. CO molecules strongly interact with both dominant Cu + site types (on the channel wall and on the channel intersection) in high-silica zeol…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceZeolite Catalysis and Synthesis

Organically Templated Linear and Layered Iron Sulfates

Geo Paul、Amitava Choudhury、C.N.R. Rao2003-02-15Chemistry of Materials

Linear and layered organically templated iron sulfates have been prepared under hydrothermal conditions. The linear iron sulfates, with the compositions [H 3 N(CH 2 ) 2 NH 3 ][FeF 3 (SO 4 )], I, [C(NH 2 ) 3 ] 2 [FeF(SO 4 ) 2 ], II, [H 3 N(CH 2 ) 2 NH 2 (CH 2 ) 2 NH 3 ][FeF(SO 4 ) 2 ], III, and [H 2 N(CH 2 ) 4 NH 2 ][F…

Crystal Structures and PropertiesClay minerals and soil interactionsChemical Synthesis and Characterization

13C Solid-State NMR Study of Polyelectrolyte Multilayers

R. N. Smith、Linda Reven、Christopher J. Barrett2003-02-15Macromolecules

Polyelectrolyte multilayers have been prepared by consecutively adsorbing poly(diallyldimethylammonium chloride) (PDADMAC) and poly(sodium 4-styrenesulfonate) (PSS) from aqueous solution onto colloidal silica (70−100 nm in diameter), with a total of five bilayers being prepared. The multilayer growth was followed by e…

Conducting polymers and applicationsPolymer Surface Interaction StudiesElectrophoretic Deposition in Materials Science

Global Phase Diagram of the Magnetic Field-Induced Organic Superconductors λ-(BETS)2FexGa1-xCl4

Shinya Uji、Taichi Terashima、C. Terakura 等 14 位作者2003-02-15Journal of the Physical Society of Japan

Organic alloys λ-(BETS) 2 Fe x Ga 1- x Cl 4 show superconductivity only under very high magnetic fields parallel to the conducting layer for x ≥0.47. As x decreases, the field induced superconducting phase shifts towards lower fields and a striking field-induced insulator to superconductor transition is observed below…

Physics of Superconductivity and MagnetismOrganic and Molecular Conductors ResearchIron-based superconductors research

Coexistence of Charge Order and Spin–Peierls Lattice Distortion in One-Dimensional Organic Conductors

Makoto Kuwabara、Hitoshi Seo、Masao Ogata2003-02-15Journal of the Physical Society of Japan

The electronic properties of quarter-filled organic materials showing spin-Peierls transition are investigated theoretically. By studying the one-dimensional extended Peierls-Hubbard model analytically as well as numerically, we find that there is a competition between two different spin-Peierls states due to the tetr…

Organic Electronics and Photovoltaics2D Materials and ApplicationsOrganic and Molecular Conductors Research

Liquid-Phase Synthesis of EuS Nanocrystals and Their Physical Properties

Supitcha Thongchant、Yasuchika Hasegawa、Yuji Wada 等 4 位作者2003-02-15The Journal of Physical Chemistry B

The first EuS nanocrystals were prepared by the reaction of europium metal and H 2 S in liquid ammonia. X-ray diffraction (XRD) patterns and TEM images supported the formation of nanoscaled EuS crystals with average size of 20.4 nm. The nanocrystals showed blue shift compared with previously reported EuS films. The Cu…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCrystal Structures and Properties

Nonlinear photoluminescence from van Hove singularities in multiwalled carbon nanotubes

Margaret Brennan Fournet、Jonathan N. Coleman、Anna Drury 等 6 位作者2003-02-15Optics Letters

Van Hove singularities (VHS) in the density of states of multiwalled carbon nanotubes (MWNTs) have been observed by optical spectroscopy for the first time to the authors' knowledge. Additionally, unexpected visible luminescence has been observed on photoexcitation at 1064 nm. This luminescence is believed to arise fr…

Carbon Nanotubes in CompositesFullerene Chemistry and ApplicationsMechanical and Optical Resonators

Influences of Potential Barrier Scattering on the Thermoelectric Properties of Sintered n-Type PbTe with a Small Grain Size

Kengo Kishimoto、Kazuo Yamamoto、T. Koyanagi2003-02-15Japanese Journal of Applied Physics

Sintered degenerate n-type PbTe samples with a grain size down to about 0.2 µm were prepared and their thermoelectric properties subsequently measured. Accordingly, the effects of grain size on thermoelectric properties were investigated. For samples with a grain size above ∼0.5 µm, the Seebeck coefficient and thermoe…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsAdvanced Thermodynamics and Statistical Mechanics

Oxygen Nonstoichiometry in Layered Cobaltite Ca3Co4Oy

Jun‐ichi Shimoyama、Shigeru Horii、Kenji Otzschi 等 5 位作者2003-02-15Japanese Journal of Applied Physics

Oxygen nonstoichiometry of Ca 3 Co 4 O y was precisely measured by thermogravimetry. Combining the result of thermal decomposition analysis, this compound was found to be expressed as (CoO 2 ) 1.62 (Ca 2 CoO 3-δ ) with δ=0–0.14. The observed oxygen nonstoichiometry in the present system was much larger than those of o…

Catalytic Processes in Materials ScienceMagnetic and transport properties of perovskites and related materialsThermal Expansion and Ionic Conductivity

Dielectric and Piezoelectric Properties of Pb(In1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3Ternary Ceramic Materials near the Morphotropic Phase Boundary

Yasuharu Hosono、Yohachi Yamashita、Hideya Sakamoto 等 4 位作者2003-02-15Japanese Journal of Applied Physics

Dielectric and Piezoelectric Properties of Pb(In1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 Ternary Ceramic Materials near the Morphotropic Phase Boundary, Hosono, Yasuharu, Yamashita, Yohachi, Sakamoto, Hideya, Ichinose, Noboru

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Origins of Mechanical Strength and Elasticity in Thermally Reversible, Acrylic Triblock Copolymer Gels

Peter L. Drzal、Kenneth R. Shull2003-02-15Macromolecules

Thermoreversible gels were formed by dissolving a poly(methyl methacrylate)−poly( tert -butyl acrylate)−poly(methyl methacrylate) triblock copolymer in a variety of alcohols, including ethanol, 1-butanol, 2-ethylhexanol, and 1-octanol. The gels exhibit an ideal and reversible solid/liquid transition in each of these s…

Material Dynamics and PropertiesPolymer Nanocomposites and PropertiesSurfactants and Colloidal Systems