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Incorporation of spin-5/2 chain into 2D network with conformational pure e,a-cis-cyclohexane-1,4-dicarboxylato linker

Yan‐Zhen Zheng、Xiao‐Ming Chen2012-01-01Dalton Transactions

A two-dimensional coordination network, (2)(∞)[Fe(III) (OH)(e,a-cis-1,4-chdc)] (1,4-chdc: cyclohexane-1,4-dicarboxylate), featuring one-dimensional iron(III)-hydroxy chains that are transversely bridged by 1,4-chdc in its pure e,a-cis conformation have been isolated. The magnetic study shows a typical spin-5/2 Heisenb…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesOrganic and Molecular Conductors Research

Estimation of doses received by operators in the 1958 RB reactor accident using the MCNP5 computer code simulation

M. Pešíć2012-01-01Nuclear Technology and Radiation Protection

A numerical simulation of the radiological consequences of the RB reactor reactivity excursion accident, which occurred on October 15, 1958, and an estimation of the total doses received by the operators were run by the MCNP5 computer code. The simulation was carried out under the same assumptions as those used in the…

Nuclear reactor physics and engineeringNuclear Physics and ApplicationsGraphite, nuclear technology, radiation studies

Preparation of Soy Protein Isolate Modified by Glutaric Dialdehyde and its Application in Rubber Composite

Qing Fang、Dan Zhou、Wen Chi Han 等 6 位作者2012-01-01Key engineering materials

Soy protein has been considered as a kind of natural polymer and an ecological material that was widely used in many fields such as food industry. In this paper, the soy protein isolate (SPI) was modified by glutaric dialdehyde and characterized by IR spectra, scanning electron microscopy (SEM) and X-ray diffraction (…

biodegradable polymer synthesis and propertiesFiber-reinforced polymer compositesMechanical Engineering and Vibrations Research

2D Numerical Model for Identification of Oxygen Reduction Reaction Mechanisms in Patterned Cathodes of La0.6Sr0.4Co0.2Fe0.8O3-δ

Lincoln J. Miara、Soumendra N. Basu、Uday B. Pal 等 4 位作者2012-01-01Journal of The Electrochemical Society

Patterned cathodes of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ (LSCF-6428) were deposited on 8 mol% yttria-doped stabilized zirconia (YSZ) substrates with a Gd-doped ceria barrier layer by rf-magnetron sputter deposition. Patterns were generated with triple phase boundary (TPB) lengths ranging from 50 to 1200 cm −1 . Electro…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Irradiation effect on natural quartz from Zambia

S. Insiripong、C. Kedkaew、Kheamrutai Thamaphat 等 6 位作者2012-01-01Procedia Engineering

The effects of high gamma-irradiation doses (50-300 kGy) on natural quartz crystals have been investigated by ESR technique. The ESR spectrum carried out at low temperature (120 K) displayed lines group of Al center. The higher amount of gamma doses affected ESR spectra by increasing of intensity, especially the incre…

Glass properties and applicationsRadiation Effects and DosimetryMineralogy and Gemology Studies

Dry Synthesis and Photoresponse of Single-Crystalline Cu2O Nanorod Arrays

Ruey‐Chi Wang、Chien-Hsien Li2012-01-01Journal of The Electrochemical Society

Growth of aligned nanorod arrays on substrates are important for their device applications, but only dispersive Cu 2 O nanorods were prepared by wet processes for previous researches. In the work, single-crystalline Cu 2 O nanorod arrays were directly grown on substrates for the first time via a NaOH-assisted dry proc…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

A facile and one-step colorimetric determination of hydrazine during formation of size-controlled amidosulfonic acid capped gold nanoparticles

Wenhua Gao、Jing Xi、Yun‐Sheng Chen 等 6 位作者2012-01-01Analytical Methods

A facile and one-step colorimetric detection of hydrazine has been developed for the first time during the formation of size-controlled amidosulfonic acid capped gold nanoparticles (AA-AuNPs). Hydrazine served not only as a target analyte but also a reductant to react with chloroauric acid (HAuCl4). In order to obtain…

Advanced biosensing and bioanalysis techniquesBiosensors and Analytical DetectionAdvanced Nanomaterials in Catalysis

Tunable Mie Scattering from Electrodeposited Cu2O Nanoparticles

Talia Gershon、Niraj Lal、Jeremy J. Baumberg 等 4 位作者2012-01-01Journal of The Electrochemical Society

Mie scattering centers comprised of high-refractive-index Cu 2 O are prepared using a rapid one-step electrodeposition procedure. The deposition of cubic nanoparticles is facilitated by a high-pH precursor solution, which allows for low Cu 2 O nucleation density and large grain size. The scattering resonant frequency…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Formation of FexOy hollow nanospheres inside cage type mesoporous materials: a nanocasting pathway

Hongxiao Jin、Chiya Wang、Bo Hong 等 9 位作者2012-01-01RSC Advances

FexOy hollow nanospheres were synthesized inside cage type mesoporous silica LP-FDU-12 through nanocasting. The sample was reduced to Fe3O4 and then further oxidized to γ-Fe2O3 with little changes in morphology and size. The Verwey transition is observed in the Fe3O4 hollow nanosphere system for the first time with ma…

Nanoparticle-Based Drug DeliveryMesoporous Materials and CatalysisIron oxide chemistry and applications

Nanoscopic NaCl crystals as water-soluble porogens for polymer membranes

S. Range、Matthias Epple2012-01-01RSC Advances

Nanoscopic NaCl was prepared by elimination from sodium malonate and phenacyl chloride with a particle diameter of 100 nm. The NaCl crystals were added to either poly(D,L)lactide or polysulfone (dissolved in dichloromethane) as water-soluble porogens. The dispersion was applied to silicon wafers by dip-coating. After…

Microfluidic and Capillary Electrophoresis ApplicationsMesoporous Materials and CatalysisPolymer Surface Interaction Studies

In Situ Electrochemical Thinning of Barrier Oxide Layer of Porous Anodic Alumina Template

P Chowdhury、S. Boominatha Sellarajan、M. Krishnan 等 6 位作者2012-01-01Advanced Science Letters

We present three different in-situ post anodization electrochemical techniques to thin down the barrier oxide layers. These techniques include exponential voltage decay, exponential voltage decay with steps and exponential current decay. Faster rate of voltage drops in case of exponential voltage decay results in pore…

Semiconductor materials and devicesAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Effect of Ultra High Molecular Weight Polyacrylonitrile (UHMW-PAN) on the Rheological Behavior of PAN/DMSO Solution

Hui Yu Jiang、Qian Yin、Mei Hua Zhou 等 4 位作者2012-01-01Advanced materials research

The effects of ultra high molecular weight Polyacrylonitrile (UHMW-PAN) on the rheological behavior of PAN/DMSO solution have been investigated using a cone-plate rheometer in this work. The rheological behavior was characterized by steady shear and oscillation test It is observed from the measurements that, the rheol…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Electrostatically controlled isolation of debundled single-walled carbon nanotubes from nanoplatelet dispersant

Xi Zhang、Hung‐Jue Sue、Riichi Nishimura2012-01-01Journal of Materials Chemistry

Individually dispersed single-walled carbon nanotubes (SWCNTs) were isolated and stabilized from electrostatically tethered nanoplatelets in aqueous solution, following nanoplatelet-assisted exfoliation. SWCNT isolation was achieved by precipitating nanoplatelets with cations and by concurrent usage of appropriate sur…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesNanotechnology research and applications

Converse-piezoelectric effect on current-voltage characteristics of symmetric ferroelectric tunnel junctions

XiaoYan Lu、Wenwu Cao、Wenhua Jiang 等 4 位作者2012-01-01Journal of Applied Physics

Current-voltage characteristics of symmetric ferroelectric tunnel junction were studied in an ultrathin ferroelectric barrier with the consideration of the thickness and strain dependent converse-piezoelectric effect. With proper boundary conditions, large piezoelectric strain can be achieved in the ferroelectric barr…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

The Application of Basalt Fiber in Building Materials

Rui Hong Wu2012-01-01Advanced materials research

As a new building materials, mechanical properties﹑physical properties and chemical properties of basalt fibers are studied in the paper. Compared with other building materials, the basalt fibers have better tensile strength than the E-glass fibers, greater failure strain than the carbon fibers as well as good resista…

Natural Fiber Reinforced Composites

Electrodeposition of Y2O3–Au composite coatings for SOFC interconnects:in situmonitoring of film growth by surface enhanced Raman spectroscopy

Benedetto Bozzini、Elisabetta Tondo、Patrizio Raffa 等 4 位作者2012-01-01Transactions of the IMF

In this paper, the authors report in situ surface enhanced Raman spectroscopy (SERS) experiments carried out during the electrochemical deposition of Y2O3/Au from chloride salts dissolved in hydroalcoholic solutions containing chitosan as a binder. This composite was recently proposed by the authors as an electronical…

Electrocatalysts for Energy ConversionCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Tautomerism in 11-Hydroxyaklavinone: A DFT Study

Lemi Türker2012-01-01The Scientific World JOURNAL

The antharquinone-based chromophore of 11-hydroxyaklavinone is present in the structure of an anticancer agent, daunomycin. On the other hand, aklavinone is the parent aglycone of certain anthracycline antibiotics that possess anti-cancer activity too. The structures of aklavinone and its 11-hydroxy derivative have ma…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Patient selection and preparation strategies for the use of contrast material in patients with chronic kidney disease

Poul Erik Andersen2012-01-01World Journal of Radiology

The prevalence of chronic kidney disease and peripheral arterial disease is increasing. Thus, it is increasingly problematic to image these patients as the number of patients needing a vascular examination is increasing accordingly. In high-risk patients with impaired kidney function, intravascular administration of i…

Advanced MRI Techniques and ApplicationsAcute Kidney Injury ResearchLanthanide and Transition Metal Complexes

Developments in Simulating Built up Edge Formation in Steel Machining

T.H.C. Childs2012-01-01Procedia CIRP

A Johnson-Cook type damage law, with pressure and temperature coefficients from published literature, is applied to simulations of carbon steel chip formation in general engineering built up edge (bue) conditions. Secondary shear zone damage and strain-rate contours are predicted with incipient bue appearance. The mod…

Advanced machining processes and optimizationAdvanced Surface Polishing TechniquesHigh-Velocity Impact and Material Behavior

Alteration of Bacterial Cellulose Properties by Diacetylglycerol

Myrtha Karina、Lucia Indrarti、Rike Yudianti 等 5 位作者2012-01-01Procedia Chemistry

Bacterial cellulose (BC) was altered by means of 0.5-2.5% w/v diacetylglycerol in acetone-water through impregnation process provided DGBC composites. Results from the scanning electron microscope images, revealed that diacetylglycerol filled the pores of BC, leads to the significant enhanced in hydrophilicity and cau…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry