Materials Literature
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We studied the optoelectronic properties of six possible structures of the (ZnO)(60) cluster using density functional theory (DFT). Vertical ionization energies and electron affinities are calculated through total energy differences, while the optical absorption spectra are obtained by using hybrid time-dependent DFT.…
The transversal conductance through thin multi-layered films of reduced graphene oxide was studied as a function of temperature in a solid-state device setup designed for molecular electronic measurements. Upon cooling to cryogenic temperatures, the resistivity of the films increased by about three orders of magnitude…
Atom probe tomography has been used to investigate nanoscale features in the yttrium oxide dispersion strengthened steel ODS Eurofer, which is a perspective structural material for the reactor cores. In the initial material, a large number (∼2 × 10 24 m −3 ) of ultrafine (∼2.5 nm in diameter) clusters enriched in yttr…
We have designed and fabricated a novel photodetector that is composed of sandwich-structured n-type zinc oxide nanorods arrays, p-type polyaniline thin film, and dye-modified n-type ZnO nanorods arrays. When the photodetector is alternatively illuminated by ultraviolet and visible light from the same direction, it ou…
Carbon nanotubes may be applied in different fields including biomedicine and mechanical engineering. It is important to understand the potential hazards of carbon nanotubes. In the present study, the toxicological effects of the pristine multi-walled carbon nanotubes (p-MWCNTs) and taurine functionalized multi-walled…
The peroxidase family of natural enzymes facilitate H2O2 reduction by one electron transfer through aromatic substrates, if chromogenic, they can be used in the colorimetric detection of H2O2 and subsequently glucose in tandem with glucose oxidase. Au nanoparticles encapsulated within porous silica exhibited peroxidas…
Effects of carbonation temperature and compacting pressure on basic properties of calcite block were studied using Ca(OH)2 compact made with 0.2-2.0 MPa and their carbonation at 200-800ºC for 1 h. Microporous calcite was obtained only when carbonated at 600ºC using Ca(OH)2 compact made with 0.2 MPa even though thermog…
The development of carbon nanotubes based materials has been impeded by both their difficult dispersion in the polymer matrix and their high cost. The discovery of graphene and the subsequent development of graphene-based polymer nanocomposites is an important addition in the area of nanoscience and technology. In thi…
A novel approach is presented for the synthesis of block-copolymers that resemble the architecture of a core cross-linked micelle. The polymers are synthesized from a combination of catalytic chain transfer polymerization (CCTP), thiol-Michael addition chemistry and reductive amination. A hydrophobic hyperbranched cor…
The roles of CdS nanocrystals (quantum dots) stabilized by oleic acid ligands in toluene were investigated in the 1,1'-oxalyldiimidazole chemiluminescence (ODI-CL) reaction generated under various environmental conditions. CdS excited by high-energy intermediates formed in ODI-CL reaction emitted dim CL. Also, CdS act…
This paper presents the report of corrosion prevention study carried out on plain carbon steel lined with calcite, magnesium carbonate and dolomite as coats. Eight samples each of the steel were dipped into solutions of CaCO 3 , CaCO 3 and MgCO 3 , and MgCO 3 . Pipe borne water obtained from Obafemi Awolowo University…
The performance of polymeric nanomaterials relies greatly upon their properties which are intimately related to the methods of fabrication of the materials. Among various synthetic polymers, the polymers of 2-hydroxyetyhyl methacrylate (PHEMA) maintain a prime position in biomedical field due to their useful physicoch…
The unique ability of shape memory alloys (SMAs) to remember and recover their original shape after large deformation offers vast potential for their integration in advanced engineering applications. SMAs can generate recoverable shape changes of several percent strain even when opposed by large stresses owing to reve…
This paper presents a comparison among classical elasticity, nonlocal elasticity, and modified couple stress theories for free vibration analysis of Timoshenko beams. A study of the influence of rotary inertia and nonlocal parameters on fundamental and higher natural frequencies is carried out. The nonlocal natural fr…
以八硝基苯基硅倍半氧烷(ONPS)为原料, 5% Pd/C 和FeCl3 为催化剂, 水合肼为还原剂, 在四氢呋喃溶液中反应 1 h 合成了八氨基苯基硅倍半氧烷(OAPS). 相比文献中已有的其它合成方法, 该方法合成过程简单且稳定, 催化效率高、产率高、周期短. 通过FTIR, 1H NMR, GPC 对产物进行了表征, 证明了硝基已完全转化. 通过催化剂的控制, 分离出ONPS 向OAPS 转化过程中的一种含有羟胺和二羟胺基团的中间体. 分析了OAPS 合成机理, 提出了ONPS 和水合肼的反应历程. 认为ONPS 中的硝基先经过2 电子转移转化为二羟胺化合物, 然后经过脱水加氢生成羟胺化合物, 最后再经过脱水加氢生成OAPS…
It is advantageous to produce cotton of the highest quality while minimizing the effect and presence of trash within the cotton lint. In addition, cotton trash comingled with the lint adversely affects the quality and profit margin associated with producing, harvesting, and processing cotton. The popularity of High Vo…
In order to suppress surface charge accumulation on the epoxy resin insulation and to investigate the influence of treatment time on the charge accumulation, epoxy samples are surface fluorinated for the different times of 10 min, 30 min and 60 min in a laboratory vessel using an F2/N2 mixture. Attenuated total reflec…
Graphene has become one of the most exciting topics of nano-material research in recent years because of its unique thermal properties. Nitrogen doping and vacancy defects are utilized to modify the characteristics of graphene in order to understand and control the heat transfer process of graphene. We use nonequilibr…
Zinc oxide (ZnO) is a promising material in nanotechnology applications, for example in nano-electronics and nano-robotic technology. The objectives of our work are to study the effect of thickness on the structural, optical, electrical and mechanical properties of ZnO thin films. ZnO thin films were coated using chem…
Extract of Annona muricata L. leaves was investigated as a corrosion inhibitor of mild steel in 1 N HCl using conventional weight loss, electrochemical polarization, electrochemical impedance spectroscopy, and scanning electron microscopic studies. The weight loss results showed that the extract of Annona muricata L l…