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Grain Size Effects on the Ferroelectric and Piezoelectric Properties of Na 0.5 K 0.5 NbO 3 Ceramics Prepared by Pechini Method

Shaoxin Huo、Songliu Yuan、Zhaoming Tian 等 5 位作者2011-12-12Journal of the American Ceramic Society

A series of lead‐free ceramics of Na 0.5 K 0.5 NbO 3 with different grain sizes (800–2000 nm) were synthesized by Pechini method, and the effects of grain size on the microstructure, dielectric, ferroelectric, and piezoelectric properties were investigated. It was found that all the ceramics are of single phase with o…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Systematic Investigation of Dispersions of Unmodified Inorganic Nanoparticles in Organic Solvents with Focus on the Hansen Solubility Parameters

Jan U. Wieneke、Björn Kommoß、Oxana Gaer 等 5 位作者2011-12-12Industrial & Engineering Chemistry Research

Dispersions of unmodified nanoparticles (titanium dioxide, hydroxyapatite) were prepared by redispersion of nanoparticle powders in organic solvents using an ultrasound treatment. The dispersion quality was judged by dynamic light scattering (DLS) measurements and visual evaluation. Whereas “bad” solvents led to no or…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous SolutionsAdsorption, diffusion, and thermodynamic properties of materials

Heat Treatment To Modify the Structural and Physical Properties of Chitosan-Based Films

Sandra Rivero、María Ángel García、Adriana Pinotti2011-12-12Journal of Agricultural and Food Chemistry

This work was focused on studying the changes undergone by heat-treated chitosan films with and without tannic acid addition by monitoring both microstructure and physical properties. Once the films were submitted to different heat treatments, they exhibited higher barrier properties as well as lower water uptake, sol…

Nanocomposite Films for Food PackagingConducting polymers and applicationsPolydiacetylene-based materials and applications

Transition of creep mechanism in nanocrystalline metals

Yun-Jiang Wang、Akio Ishii、Shigenobu Ogata2011-12-12Physical Review B

Understanding creep mechanisms with atomistic details is of great importance to achieve the mechanical and thermodynamical stabilities of nanocrystalline (NC) metals over a wide temperature range. Here we report a molecular dynamics analysis of creep in NC copper dominated by competing deformation mechanisms. We found…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsAluminum Alloys Composites Properties

Magic sized ZnS quantum dots as a highly sensitive and selective fluorescence sensor probe for Ag + ions

Abhijit Mandal、Anirban Dandapat、Goutam De2011-12-12The Analyst

A green and simple chemical synthesis of magic sized water soluble blue-emitting ZnS quantum dots (QDs) has been accomplished by reacting anhydrous Zn acetate, sodium sulfide and thiolactic acid (TLA) at room temperature in aqueous solution. Refluxing of this mixture in open air yielded ZnS clusters of about 3.5 nm in…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Band-gap narrowing in α-(CrxFe1-x)2O3 solid-solution films

Hisanori Mashiko、Takayoshi Oshima、Akira Ohtomo2011-12-12Applied Physics Letters

We report on structural and optical properties for the (0001)-oriented α-(CrxFe1-x)2O3 (0 ≤ x ≤ 1) epitaxial films prepared on c-sapphire substrates by using pulsed-laser deposition. Pure corundum phase with atomically flat surface was obtained in the entire composition range. Optical absorption spectra for the films…

Iron oxide chemistry and applicationsCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Polyethylene Crystallization Nucleated by Carbon Nanotubes under Shear

Marilyn L. Minus、Han Gi Chae、Satish Kumar2011-12-12ACS Applied Materials & Interfaces

Polyethylene crystallization under shear has been studied in the presence of single-wall, few-wall, and multiwall carbon nanotubes (SWNT, FWNT, and MWNT). Polyethylene crystal d-spacings for (110) and (200) planes in polyethylene/carbon nanotubes (CNT) are smaller than in the control polyethylene without CNT and the p…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Photoconductive gain in solar-blind ultraviolet photodetector based on Mg0.52Zn0.48O thin film

Shun Han、Zhenzhong Zhang、Jiying Zhang 等 13 位作者2011-12-12Applied Physics Letters

An ultraviolet photodetector was fabricated on MgZnO thin film grown by metal-organic chemical vapor deposition. The peak response of the device centers at 238 nm and cutoff wavelength is 253 nm. The peak responsivity is 129 mA/W at 15 V bias, and the UV/visible reject ratio is 4 orders of magnitude. Internal gain is…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Elegant Approach to the Synthesis of a Unique Heteroleptic Cyclometalated Iridium(III)-Polyoxometalate Conjugate

Benjamin Matt、Jamal Moussa、Lise‐Marie Chamoreau 等 7 位作者2011-12-12Organometallics

A novel heteroleptic cyclometalated iridium(III) complex with one picolinic acid derivative bearing a pendant terminal alkynyl tether has been prepared following a new synthetic route. This pendant alkynyl tether can be further engaged in palladium C–C coupling reactions, allowing its grafting to a Keggin-type polyoxo…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

Aluminum–organophosphorus hybrid nanorods for simultaneously enhancing the flame retardancy and mechanical properties of epoxy resin

Jiajun Ma、Yang Junxiao、Yawen Huang 等 4 位作者2011-12-12Journal of Materials Chemistry

New aluminum–organophosphorus hybrid nanorods (AOPH-NR) have been prepared by reacting aluminum hydroxide (ATH) with dibenzylphosphinic acid (DBPA) with aluminum hydroxide (ATH) and used to prepare nanocomposites with epoxy resin. In order to determine the structure–property relationship of these composites, several o…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesSynthesis and properties of polymers

Protein-based nanotubes for biomedical applications

Teruyuki Komatsu2011-12-12Nanoscale

This review presents highlights of our latest results of studies directed at developing protein-based smart nanotubes for biomedical applications. These practical biocylinders were prepared using an alternate layer-by-layer (LbL) assembly of protein and oppositely charged poly(amino acid) into a nanoporous polycarbona…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesProtein purification and stability

Serum proteins prevent aggregation of Fe2O3and ZnO nanoparticles

M A Wells、Aamir Abid、Ian M. Kennedy 等 4 位作者2011-12-12Nanotoxicology

Aggregation of metal oxide nanoparticles in aqueous media complicates interpretation of in vitro studies of nanoparticle-cell interactions. We used dynamic light scattering to investigate the aggregation dynamics of iron oxide and zinc oxide nanoparticles. Our results show that iron oxide particles aggregate more read…

Nanoparticles: synthesis and applicationsBlood properties and coagulation

Towards the upper bound of electrochemical performance of ACNT@polyaniline arrays as supercapacitors

Fan Huang、De Chen2011-12-12Energy & Environmental Science

A strategy in the rational design of the aligned carbon nanotube @ polyaniline (ACNT@PANI), arrayed on metal foils as supercapacitors, has been demonstrated towards the upper bound of the specific capacitance, namely a high surface area and nanometre thickness of PANI, good accessibility of ions and a low contact resi…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesConducting polymers and applications

ONTOGENY, HOMOLOGY, AND TERMINOLOGY—WALL MORPHOGENESIS AS AN AID TO CHARACTER RECOGNITION AND CHARACTER STATE DEFINITION FOR PENNATE DIATOM SYSTEMATICS1

Eileen J. Cox2011-12-12Journal of Phycology

This article reviews current knowledge of wall morphogenesis in pennate diatoms in relation to the way characters are defined and described for taxonomic and systematic analyses. It argues that an understanding of ontogeny is essential for the accurate identification of character homologies, which in turn must underpi…

Paleontology and Stratigraphy of FossilsProtist diversity and phylogenyDiatoms and Algae Research

Maximum asymmetry in strain induced mechanical instability of graphene: Compression versus tension

Yu Zhang、Feng Liu2011-12-12Applied Physics Letters

We demonstrate that graphene, as the thinnest possible solid membrane of only one atomic layer thick, exhibits the maximum asymmetry in tensile versus compressive strain induced mechanical instability. Using continuum mechanics analysis and molecular dynamics simulations, we show that for graphene nanoribbons (sheets)…

Carbon Nanotubes in CompositesGraphene research and applicationsForce Microscopy Techniques and Applications

Microwave-assisted syntheses of highly CO 2 -selective organic cage frameworks (OCFs)

Yinghua Jin、Bret A. Voss、Ryan McCaffrey 等 6 位作者2011-12-12Chemical Science

A series of organic cage frameworks (OCFs) were successfully synthesized through microwave-assisted Sonogashira coupling of 3-D molecular cage building blocks with various diacetylene linkers. These novel framework materials exhibited unprecedented, high ideal selectivity (up to 213/1) in adsorption of CO2 over N2 und…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesCovalent Organic Framework Applications

Evaluating Self Healing Capability of Bituminous Mastics

Jian Qiu、Mfc van de Ven、Shaopeng Wu 等 5 位作者2011-12-12Experimental Mechanics

The self-healing capability of bituminous materials has been known for many years. Researches were mostly focused on the self healing behaviour during load repetitions. The tests are either time consuming and/or complex. In this paper, a simple self healing test procedure is presented combining the fracture-healing-re…

Asphalt Pavement Performance EvaluationPolymer composites and self-healingMicrobial Applications in Construction Materials

Bonding Assembled Colloids without Loss of Colloidal Stability

Hanumantha Rao Vutukuri、Johan C. P. Stiefelhagen、Teun Vissers 等 5 位作者2011-12-12Advanced Materials

A facile method is demonstrated for bonding assembled colloids without loss of colloidal stability by thermal annealing. Examples include both close-packed and non-close-packed structures. The confocal microscopy image shows a cross-section of a 3D labyrinthine structure after it was made permanent. The 3D network is…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPickering emulsions and particle stabilization

Mechanical and Environmental Stability of Polymer Thin-Film-Coated Graphene

Chao Yan、Kwang-Seop Kim、Seoung-Ki Lee 等 8 位作者2011-12-12ACS Nano

A uniform polymer thin layer of controllable thickness was bar-coated onto a chemical vapor deposition (CVD) grown monolayer graphene surface. The effects of this coating layer on the optical, electric, and tribological properties were then investigated. The thin polymer coating layer did not reduce the optical transm…

Graphene research and applicationsAdvanced Sensor and Energy Harvesting MaterialsDiamond and Carbon-based Materials Research

High transport critical current densities in textured Fe-sheathed Sr1−xKxFe2As2+Sn superconducting tapes

Zhaoshun Gao、Lei Wang、Chao Yao 等 9 位作者2011-12-12Applied Physics Letters

We report the realization of grain alignment in Sn-added Sr1−xKxFe2As2 superconducting tapes with Fe sheath prepared by ex-situ powder-in-tube method. At 4.2 K, high transport critical current densities Jc of 2.5 × 104 A/cm2 (Ic = 180 A) in self-field and 3.5 × 103 A/cm2 (Ic = 25.5 A) in 10 T have been measured. These…

Corporate Finance and GovernanceCorporate Taxation and AvoidanceIron-based superconductors research