Materials Literature
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For the first time, Au/Ti micro- and nanotubes were prepared by rolling initially planar, strained Au/Ti bifilms, freed from the Si substrates by wet selective etching of underlying Al sacrificial layers. Conducting metal tubes with diameters ranging from 20 µm to 40 nm were made from 10 µm wide and 10 cm long metal s…
Novel polyelectrolyte microcapsules are developed using alternating layer-by-layer (LBL) adsorption of oppositely charged polyelectrolytes onto charged templates followed by core removal. These capsules have a continuous wall with a hollow interior and exhibit tunable permeability, which can be utilized for both susta…
ZnO nanoparticles were synthesized and successfully incorporated in Ce 3+ -doped SiO 2 matrix by a sol–gel method. Photoluminescence intensities were compared for ZnO nanoparticles, Ce 3+ -doped SiO 2 (SiO 2 :Ce 3+ ) and ZnO encapsulated in SiO 2 :Ce 3+ (ZnO–SiO 2 :Ce 3+ ) fabricated from sol–gels. Green emission from…
Highly manufacturable 64Mbit PRAM has been successfully fabricated using N-doped Ge/sub 2/Sb/sub 2/Te/sub 5/ (GST) and optimal GST etching process. Using those technologies, it was possible to achieve the low writing current of 0.6 mA and clear separation between SET and RESET resistance distributions. The 64Mb PRAM w…
The crystal structures of two hydrazinium-based germanium(IV) and tin(IV) selenide salts are determined. (N(2)H(5))(4)Ge(2)Se(6) (1) [I4(1)cd, a = 12.708(1) Angstroms, c = 21.955(2) Angstroms, Z = 8] and (N(2)H(4))(3)(N(2)H(5))(4)Sn(2)Se(6) (2) [P, a = 6.6475(6) Angstroms, b = 9.5474(9) Angstroms, c = 9.8830(10) Angst…
In the present work we analyze the magnetic entropy change $\ensuremath{\Delta}{S}_{\mathrm{M}}$ of the ${\mathrm{Pr}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}\mathrm{Mn}{\mathrm{O}}_{3}$ manganites, for a wide range of Ca concentrations $(0.20\ensuremath{\leqslant}x\ensuremath{\leqslant}0.95)$. The results for the samples…
We analyzed the programming dynamics in phase-change memory (PCM) cells. The chalcogenide phase-change mechanism and phase distribution in the programmed cell is studied by both experiments and a numerical model, which self-consistently addresses the electrical-thermal conduction phase transition. We show that the res…
We report on a photolabile protecting (caging) group that is new for carboxylic acids. Unlike previously used caging groups for carboxylic acids, it can be photolyzed rapidly and efficiently in the visible wavelength region. The caging group 7-N,N-diethyl aminocoumarin (DECM) was used to cage the gamma-carboxyl group…
We find strong evidence for a metal-insulator (MI) transition in macroscopic single wall carbon nanotube (SWNT) conductors. This is revealed by systematic measurements of resistivity and transverse magnetoresistance (MR) in the ranges 1.9--300 K and 0--9 Tesla, as a function of $p$-type redox doping. Strongly ${\mathr…
Polar behavior was found in Sr1−xMnxTiO3(x=0.005–0.02) ceramic system. Radio-frequency dielectric measurements showed a diffuse maximum at 25–65 K shifting to higher temperatures with increasing measurement frequency and amount of Mn. The observation of hysteretic behavior in the P versus E curves shows the existence…
Single-crystalline ZnO microtubes were synthesized by a simple metal-vapor deposition method. The ZnO microtubes, which had outer diameters in the range of 0.3−2 μm and wall thickness in the range of 100−500 nm, indicated a faceted hexagonal shape. In addition, it was found that there were many incomplete ZnO microtub…
During the past centuries, industrial processes and energy conversion plants have shown no or little care for environmental quality. The result is a huge accumulation of pollution and hazardous by-products, left as a heritage for the present and future generations. Recuperation of by-products or thermal energy is not…
A multinuclear NMR study of the interaction between phenylboronic acid (PBA) and sialic acid (Neu5 Ac) has been performed. The latter compound is known to be overexpressed on the cell surface of tumor cells. The results of this investigation suggest that the binding of PBA to sialic acid is pH dependent. 17O NMR exper…
A near ballistic carbon nanotube field-effect transistor (CNTFET) that integrates an ultra-short channel, low-barrier metal contacts, and a thin high-K gate insulator is modeled and analyzed using self-consistent quantum simulations. Numerical simulations, which solve a quantum transport equation self-consistently wit…
We briefly review the status of the application of carbon nanotubes (CNTs) for future interconnects and present results concerning possible integration schemes. Growth of single nanotubes at lithographically defined locations (vias) has been achieved which is a prerequisite for the use of CNTs as future interconnects.…
A series of heterodinuclear Cu(II)Ln(III) and Ni(II)Ln(III) complexes, [M(II)L(1)Ln(III)(NO(3))(3)] (M = Cu or Ni; Ln = Ce-Yb), with the hexadentate Schiff base compartmental ligand N,N'-ethylenebis(3-ethoxysalicylaldiimine) (H(2)L(1)) have been synthesized and characterized. The X-ray crystal structure determinations…
Single-phase RyMxCo4−xSb12(x=0–3.0,y=0–0.7) compounds filled by Ce, Ba, and Y, and substituted by Fe and Ni are synthesized by using the solid-state reaction method and melting reaction method. The structure and the thermoelectric properties of RyMxCo4−xSb12 are investigated systematically. The thermal parameter (B) o…
Abstract Summary: In this article, the properties of a polylactide and starch composite (PLA/starch) and an acrylic acid grafted polylactide and starch composite (PLA‐ g ‐AA/starch) were compared. The composite containing PLA‐ g ‐AA was found to have much better dispersion and homogeneity of starch in the polymer matr…
Carbon nanotubes, carbon nanobelts, and carbon nanoparticles can be prepared directly from active carbon powders by a polyoxometalates (POMs)-assisted mild hydrothermal process. After the hydrothermal reaction the POMs are changed into heteropoly blues, which can be converted into the POMs by a small amount of H2O2 so…
Magnetic susceptibility, heat capacity and electrical resistivity measurements have been carried out on a new ruthenate, La2RuO5 (monoclinic, space group P21/c) which reveal that this compound is a magnetic semiconductor with a high magnetic ordering temperature of 170K. The entropy associated with the magnetic transi…