Materials Literature
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Results are presented for the self-diffusion properties of monodisperse n-alkanes and cis-1,4 polyisoprene (PI) oligomer melts, as obtained through detailed atomistic molecular dynamics (MD) simulations. The simulations have been conducted in the NVT statistical ensemble on model systems thoroughly pre-equilibrated th…
The friction and wear behavior of amorphous diamond-like nanocomposite (DLN) coatings (C:H:Si:0) in low speed, dry sliding contact has been investigated using a home-built in situ tribometer. Tests were performed under reciprocating sliding against sapphire and steel hemispheres in dry (∼4% RH) and moist (35 to 52% RH…
Numerous derivatives of BODIPY (4,4-difluoro-4-borata-3a-azonia-4a-aza-s-indacene) are frequently used as fluorescent probes in modern protein and lipid research. Present studies of purpose-synthesised molecules show that the BODIPY chromophore can form two different ground state dimers, denoted DI and DII. In practis…
Abstract I. Introduction 108 II. Structural Analysis 109 III. Copolymer Composition 111 A. Composition by the Direct Method 111 B. Composition by the Method Based on Statistics 111 C. Copolymer Composition by the Hard‐Ionization Method 113 IV. Copolymer Sequence 114 V. Molar Mass Determination 115 VI. MS as a Detector…
The chemical diffusion coefficient and oxygen-transfer coefficients of selected compositions in the series La<sub>1-x</sub>Sr<sub>x</sub>CoO<sub>3-δ</sub> were studied using the conductivity relaxation technique. Measurements were performed in the temperature range 600-850°C and oxygen partial pressure 10<sup>-4</sup>…
Three denitrifying strains of bacteria capable of degrading poly(3-hydroxybutyrate) (PHB) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) were isolated from activated sludge and characterized. All of the isolates had almost identical phenotypic characteristics. They were motile gram-negative rods with single p…
The results obtained in experiments on the growth of zinc oxide, ZnO, under hydrothermal conditions are generalized. The polar growth and nonstoichiometry of ZnO crystals are analyzed in terms of crystal chemistry with due regard for the physicochemical conditions of the growth medium. The effect of the Li+ and of di-…
Abstract Epoxidized oils, epoxidized triacylglycerols, and epoxidized fatty acid methyl esters were made by reaction with performic acid formed in situ . The extent of epoxidation was ca. 95% for all of the epoxidized samples, as determined by 1 H nuclear magnetic resonance. The epoxidized samples were reacted with an…
Electric Double-Layer Capacitance of Meso/Macroporous Activated Carbon Fibers Prepared by the Blending Method : I. Nickel-Loaded Activated Carbon Fibers in Propylene Carbonate Solution Containing LiClO4 Salt , Shiraishi, Soshi, Kurihara, Hideyuki, Shi, Lan, Nakayama, Takuya, Oya, Asao
Small wires of W, Ag, and Pt were placed within an electrochemical microcell above single sulfide inclusions to detect the pH, sulfide, and thiosulfate, respectively. In chloride-free electrolytes the onset of sulfide dissolution was accompanied by a decrease in pH of 0.5 units to 4.2, a value that is not low enough t…
The material studied is a planar wire-grid network loaded with orthogonal capacitors and inductors. Over a ground plane and excited by a localized single-frequency source, this metamaterial exhibits conical high-field regions called "resonance cones." The cones exhibit specular reflection from boundaries and, with two…
Bis-[triethoxysilylpropyl]tetrasulfide (or bis-sulfur silane) and bis-[trimethoxysilylpropyl] amine (or bis-amino silane) were deposited on 2024-T3 aluminum alloy (AA 2024-T3). The structures of the films were characterized using Fourier-transform infrared spectroscopy (FTIR) and electrochemical impedance spectroscopy…
In this letter, we present a technique for calculating the Raman gain spectra of germanosilicate fibers from their index profiles. The gain spectra depend on radial profiles of the guided optical modes and the glass composition, in particular the distribution of Si-O-Si and Ge-O-Si bridging bonds. We have obtained spe…
This work presents a mathematical model for charge/discharge of electrochemical capacitors that explicitly accounts for particle-packing effects in a composite electrochemical capacitor consisting of hydrous nanoparticles dispersed within porous activated carbon. The model is also used to investigate the effect of non…
Magnetization of MnAs1−xSbx was measured as functions of temperature and magnetic field for 0≤x≤0.4. The entropy change caused by a magnetic field, ΔSmag, was estimated on the basis of the Maxwell relation. The ΔSmag for 0≤x≤0.3 in a field change of 5 T reaches 25–30 J/K kg, which exceeds that of other materials by a…
The water exchange process was accelerated for nine-coordinate, monohydrated macrocyclic GdIII complexes by inducing steric compression around the water binding site; the increased steric crowding was achieved by replacing an ethylene bridge of DOTA4- by a propylene bridge; in addition to the optimal water exchange ra…
The constitutive formulation of the finite-strain thermoelasticity is revisited within the thermodynamic framework and the multiplicative decomposition of the deformation gradient into its elastic and thermal parts. An appealing structure of the Helmholtz free energy is proposed. The corresponding stress response and…
Immersion plating of metals (Ag, Cu, Ni) onto a porous silicon (PS) layer from aqueous and nonaqueous solutions has been studied. The modified PS layers after the immersion plating were analyzed by X-ray diffraction and X-ray photoelectron spectroscopy. Fourier transform infrared spectroscopy and scanning electron mic…
Requirements for reduced NOx emissions have required that emissions reduction technologies move beyond combustion controls alone. Post combustion NOx control technologies that are being applied to coalfired utility boilers include selective non catalytic reduction (SNCR), selective catalytic reduction (SCR), and combi…
High quality ZnO thin films have been grown on a Si(100) substrate by plasma enhanced chemical vapor deposition using a zinc organic source [Zn(C2H5)2] and carbon dioxide (CO2) gas mixtures at the low temperature of 180 °C. The dependence of ZnO thin film quality on the gas flow rate ratio of Zn(C2H5)2 to CO2 (GFRRZC)…