423. Experiments towards the synthesis of corrins. Part II. The preparation and reactions of Δ 1 -pyrroline 1-oxides
R. Bonnett, R. F. C. Brown, V. M. Clark, I. O. Sutherland and A. Todd, J. Chem. Soc., 1959, 2094 DOI: 10.1039/JR9590002094
Materials Literature
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Preparation and Aromatization of Poly-1,3-cyclohexadiene1
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation and Aromatization of Poly-1,3-cyclohexadiene1C. S. Marvel and Gordon E. HartzellCite this: J. Am. Chem. Soc. 1959, 81, 2, 448–452Publication Date (Print):January 1, 1959Publication History Published online1 May 2002Published inissue 1 January 1959https://pubs.acs…
The coercive force and rotational hysteresis of elongated ferromagnetic particles
The coercive force of an infinite ferromagnetic cylinder is calculated as a function of the radius and of the inclination of the axis to the applied field. For this calculation it is assumed that only curling and rotation in unison take place ; and that whenever the curling is associated with a discontinuous jump, the…
Electrolytic Iron Powder from a Caustic Soda Solution
Conditions for electrolytic deposition of iron powder from a slurry of iron III oxide in caustic soda solutions were investigated. The variables that influence the deposition the most were temperature (90°C), caustic soda concentration (600–800 g/l), and low current densities. Results from pilot‐plant studies were in…
6—THE MECHANICS OF TWISTED YARNS : TENSILE PROPERTIES OF CONTINUOUS-FILAMENT YARNS
The theories ofthe extension of yarns which have been proposed by Gegauff1 Platt 2,3, and Hearle4 and the assumptions on which they are based are considered. Experimental studies of the tensile properties of twisted continuous-filament yarns are reviewed. A range of yarns has been twisted, and their tensile properties…
Structural polytypism of lead iodide and its relationship to screw dislocations
We’ve built this digital research platform to provide academics everywhere with fast, stable and secure digital access to our library of over 110,000 scholarly books and 800,000 journal articles. We’ve tested the platform in close cooperation with leading academic institutions. If you have any questions or you notice…
Tricalcium Silicate and Its Stability Within the System CaO‐SiO 2
A portion of the system CaO‐SiO 2 has been reinvestigated by high‐temperature microscopy. Direct observations at the liquidus establish a primary‐phase region for tricalcium silicate, which is shown in a revised phase diagram to melt incongruently. The tricalcium silicate primary‐phase field extends from the eutectic…
The crystal structure of polyheptamethylene pimelamide (nylon 77)
Abstract During the course of an investigation of polyamide series it became necessary to obtain more ample knowledge of the structure of a polyamide with odd number of CH 2 groups. As an example of this series the crystal structure of polyheptamethylene pimelamide (nylon 77) has been determined by X‐ray analysis acco…
9—TENSILE AND TEARING STRENGTH OF COTTON CLOTHS
Tensile strength and tearing strength are discussed separately. A relation between cloth tensile strength, yarn strength and the parameters of cloth construction and yarn construction is suggested. Tearing strength is shown to be dependent mainly on the spacing and strength of the threads being torn and the force requ…
Nature of the Reactions of Monocalcium Phosphate Monohydrate in Soils: I. The Solution That Reacts with the Soil
Abstract The dissolution of monocalcium phosphate monohydrate (MCP) in water was followed over a 17‐day period; and the resulting solution was compared with solubility isotherms of the system CaO‐P 2 O 5 ‐H 2 O at 25°C. Shaking excess MCP with water at room temperature resulted in rapid dissolution during the first fe…
Batteries with Solid Ion Exchange Electrolytes
Highly conducting ion exchange polymers can be employed as solid electrolytes in batteries. Their resistivities are intermediate between aqueous electrolytes and the usual inorganic solid electrolytes. Cells containing pairs of metal electrodes behave reversibly. Their emf's form an additive series for the examples te…
The thermal decomposition of nesquehonite MgCO 3 · 3H 2 O and magnesium ammonium carbonate MgCO 3 ·(NH 4 ) 2 CO 3 · 4H 2 O
THE THERMAL DECOI'OSITI0N OF NESQUEHONITE MgCO3 THE THERMAL DECOI'OSITI0N OF NESQUEHONITE MgCO3 3H20 AND MAGNESIUM AMMONIUM CARBONATE 4H2O BY R. M. DELL* AND S. W. WELLERt Houdry Process Corporation, Marcus Hook, Pa., U.S.A. Received 25th February, 1959 A study has been made of the thermal decomposition
Phase Equilibria and Manganese-Activated Fluorescence in the System Zn[sub 3](PO[sub 4])[sub 2]-Mg[sub 3](PO[sub 4])[sub 2]
Determination of the phase relationships on the join by the quench method has enabled the previously designated "gamma zinc phosphate" to be identified as a solid solution of zinc orthophosphate in magnesium orthophosphate. takes 95 mole % into solid solution at 1000°C. takes a small amount of into solid solution (abo…
THE ELECTROCHEMICAL BEHAVIOR OF THE NICKEL – NICKEL OXIDE ELECTRODE: PART I. KINETICS OF SELF-DISCHARGE
The nickel – nickel oxide electrode forms the positive plate in the charged nickel–cadmium battery. After "charging" the electrode to a chemical state represented by the non-structural formula NiO x , where x can vary from about 1.4 to 1.8 depending on the current density and temperature, loss of oxygen and a fall of…
Recombination of atoms at surfaces. Part 6.—Recombination of oxygen atoms on silica from 20°C to 600°C
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Current concepts in the theory of foaming
J. A. Kitchener and C. F. Cooper, Q. Rev. Chem. Soc., 1959, 13, 71 DOI: 10.1039/QR9591300071
769. The stereochemistry of B subgroup metals. Part II. The inert pair
L. E. Orgel, J. Chem. Soc., 1959, 3815 DOI: 10.1039/JR9590003815
Block polymers of ethylene oxide and its analogues with styrene
D. H. Richards and M. Szwarc, Trans. Faraday Soc., 1959, 55, 1644 DOI: 10.1039/TF9595501644
An internal friction study of polytetrafluoroethylene
Abstract A torsion pendulum has been used to measure the internal friction of polytetrafluoroethylene. The crystallinity of the specimens varied form 48 to 92%, and the measurements were made over a wide temperature range. The site of each relaxation was assigned by observing the variation of relaxation strength and p…
The Influence of Noble Metal Alloy Additions on the Electrochemical and Corrosion Behavior of Titanium
Alloying of titanium with small amounts of noble metals markedly improves its corrosion resistance in reducing‐type acids without any impairment of its high resistance to oxidizing media. The mixed potentials of titanium noble metal alloys are more noble than the critical potential for passivity of titanium in the sam…