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Electrospinning of Polycaprolactone in Dichloromethane/Dimethylformamide Solvent System

Narissara Kulpreechanan、Tanom Bunaprasert、Ratthapol Rangkupan2013-11-21Advanced materials research

Electrospinning of polycaprolactone (PCL) in a mixed solvent of dichloromethane (DCM)/dimethylformamide (DMF) with 1:1 volumetic mixing ratio was studied. The effects of solution concentration (5-30 %w/v), applied voltage (10-25 kV), solution flow rate (0.1-2.0 mL/h) and collecting distance (10, 20 cm) on fiber format…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Ion-Energy Dependency in Proton Irradiation Induced Chemical Processes of Poly(dimethylsiloxane)

Róbert Huszánk、S.Z. Szilasi、Dezső Szikra2013-11-21The Journal of Physical Chemistry C

In this paper, we present a study of chemical changes in poly(dimethylsiloxane) (PDMS) induced by proton irradiation of various energy and fluence. It has been found that the forming products vary as the energy of the proton changes, which means that the energy of the incident ions can influence the chemical mechanism…

Diamond and Carbon-based Materials ResearchIon-surface interactions and analysisPolymer Nanocomposite Synthesis and Irradiation

Angular and polarization properties of cross-holes nanostructured metallic filters

Romain Girard-Desprolet、Salim Boutami、S. Lhostis 等 4 位作者2013-11-21Optics Express

It has been shown in literature that cross-shaped holes arrays can be made insensitive to polarization at normal incidence, and can even feature good stability for off-normal incidence. In this work we look for the optimal design rules to obtain high spectral stability conditions in the visible for those structures, t…

Plasmonic and Surface Plasmon ResearchThin-Film Transistor TechnologiesOptical Coatings and Gratings

Redox Noninnocence in Coordinated 2-(Arylazo)pyridines: Steric Control of Ligand-Based Redox Processes in Cobalt Complexes

Pradip Ghosh、Subhas Samanta、Suman Roy 等 7 位作者2013-11-21Inorganic Chemistry

A series of cobalt complexes of ligands based on the 2-(arylazo)pyridine architecture have been synthesized, and the precise structure and stoichiometry of the complexes depend critically on the identity of substituents in the 2, 4, and 6 positions of the phenyl ring. The 2-(arylazo)pyridine motif can support either C…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Ordered nanostructures at two different length scales mediated by temperature: A triphenylene‐containing mesogen‐jacketed liquid crystalline polymer with a long spacer

Yufeng Zhu、Hai‐Jian Tian、Hongwei Wu 等 10 位作者2013-11-21Journal of Polymer Science Part A Polymer Chemistry

ABSTRACT A mesogen‐jacketed liquid crystalline polymer (MJLCP) containing triphenylene (Tp) moieties in the side chains with 12 methylene units as spacers (denoted as PP12V) was synthesized. Its liquid crystalline (LC) phase behavior was studied with a combination of solution 1 H NMR, solid‐state NMR, gel permeation c…

Liquid Crystal Research AdvancementsBlock Copolymer Self-AssemblyNanofabrication and Lithography Techniques

Controlling the charge state of single Mo dopants in a CaO film

Yi Cui、Niklas Nilius、Hans‐Joachim Freund 等 6 位作者2013-11-21Physical Review B

Recent experiments have demonstrated that tiny amounts of Mo impurities give rise to drastic changes in the adsorption characteristic of a wide-gap CaO(001) film. In this scanning tunneling microscopy (STM) and density functional theory paper, we elucidate the underlying mechanism by analyzing the energy levels of the…

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Subsurface nanodomains with in-plane polarization in uniaxial ferroelectrics via scanning force microscopy

Nikolay A. Pertsev、Andréi L. Kholkin2013-11-21Physical Review B

Ferroelectric nanodomains can be created by the application of a bias voltage to the sharp conducting tip of a scanning force microscope (SFM) contacting the sample surface. Since an inhomogeneous electric field created by an SFM tip has maximum intensity along the surface normal, in multiaxial ferroelectrics the pola…

Ferroelectric and Piezoelectric MaterialsForce Microscopy Techniques and ApplicationsAcoustic Wave Resonator Technologies

Effects of annealing temperature on the mechanical properties and sensitization of 5083-H116 aluminum alloy

Renyu Chen、Hsiao-Yeh Chu、Cheng-Chyuan Lai 等 4 位作者2013-11-21Proceedings of the Institution of Mechanical Engineers Part L Journal of Materials Design and Applications

This study elucidates how annealing temperature affects the mechanical properties and sensitization of 5083-H116 aluminum alloys. Nitric Acid Mass Loss Test was conducted to investigate the sensitization behavior of the annealed specimens. The results indicated that the mechanical properties were more sensitive to the…

Corrosion Behavior and InhibitionAluminum Alloy Microstructure PropertiesHydrogen embrittlement and corrosion behaviors in metals

Self-trapped exciton and core-valence luminescence in BaF2 nanoparticles

V. Vistovskyy、A. V. Zhyshkovych、Ya. M. Chornodolskyy 等 9 位作者2013-11-21Journal of Applied Physics

The influence of the BaF2 nanoparticle size on the intensity of the self-trapped exciton luminescence and the radiative core-valence transitions is studied by the luminescence spectroscopy methods using synchrotron radiation. The decrease of the self-trapped exciton emission intensity at energies of exciting photons i…

Advanced Chemical Physics StudiesLuminescence Properties of Advanced MaterialsInorganic Fluorides and Related Compounds

Rapid Transfer of Endothelial Cell Sheet Using a Thermosensitive Hydrogel and Its Effect on Therapeutic Angiogenesis

Seok Joo Kim、Indong Jun、Dong Wan Kim 等 9 位作者2013-11-21Biomacromolecules

In this study, thermosensitive hydrogels incorporated with multiple cell-interactive factors were developed as a substrate to form monolayer of human umbilical vein endothelial cells (HUVECs) that can be detached and transferrable to target sites as a cell-sheet in response to temperature change. The cell adhesive pep…

Angiogenesis and VEGF in CancerElectrospun Nanofibers in Biomedical Applications3D Printing in Biomedical Research

Direct observation of p,p′‐dimercaptoazobenzene produced from p‐aminothiophenol and p‐nitrothiophenol on Cu2O nanoparticles by surface‐enhanced Raman spectroscopy

Tingting You、Li Jiang、Penggang Yin 等 7 位作者2013-11-21Journal of Raman Spectroscopy

Surface‐enhanced Raman scattering of p ‐aminothiophenol and p ‐nitrothiophenol were obtained on the surface of Cu 2 O nanoparticles, showing novel spectral changes with morphology‐dependent and time‐dependent characteristics. The measured Raman signals were believed to partly originate from the newly produced surface…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsLaser-Ablation Synthesis of Nanoparticles

Weak Ferromagnetic Ordering of the Li+[TCNE]•– (TCNE = Tetracyanoethylene) Organic Magnet with an Interpenetrating Diamondoid Structure

Jae-Hyuk Her、Peter W. Stephens、Royce A. Davidson 等 8 位作者2013-11-21Journal of the American Chemical Society

Li[TCNE] (TCNE = tetracyanoethylene) magnetically orders as a weak ferromagnet (canted antiferromagnet) below 21.0 ± 0.1 K, as observed from the bifurcation of the field-cooled and zero-field-cooled magnetizations, as well as remnant magnetization. The structure, determined ab initio from synchrotron X-ray powder diff…

Magnetism in coordination complexesAdvanced Condensed Matter PhysicsOrganic and Molecular Conductors Research

Degradation of Methyl Paraoxon in the Presence of Mg2+-Al3+ Mixed Oxides

Lizandra Maria Zimmermann、Gizelle I. Almerindo、José R. Mora 等 6 位作者2013-11-21The Journal of Physical Chemistry C

Al 3+ -Mg 2+ mixed oxides were prepared by coprecipitation and characterized with scanning electron microscopy (SEM), energy dispersive X-ray fluorescence (EDXRF), temperature programmed desorption of CO 2 (CO 2 -TPD), and N 2 adsorption/desorption isotherms (BET and BJH methods). By increasing the MgO concentration u…

Energetic Materials and CombustionLayered Double Hydroxides Synthesis and ApplicationsThermal and Kinetic Analysis

Negative differential resistance and effect of defects and deformations in MoS2 armchair nanoribbon metal-oxide-semiconductor field effect transistor

Amretashis Sengupta、Santanu Mahapatra2013-11-21Journal of Applied Physics

In this work, we present a study on the negative differential resistance (NDR) behavior and the impact of various deformations (like ripple, twist, wrap) and defects like vacancies and edge roughness on the electronic properties of short-channel MoS2 armchair nanoribbon MOSFETs. The effect of deformation (3°–7° twist…

2D Materials and ApplicationsSemiconductor materials and devicesAdvancements in Semiconductor Devices and Circuit Design

Ultrasensitive RDX detection with commercial SERS substrates

S. Almaviva、S. Botti、L. Cantarini 等 8 位作者2013-11-21Journal of Raman Spectroscopy

Surface‐enhanced Raman spectroscopy (SERS) measurements on 1,3,5‐trinitroperhydro‐1,3,5‐triazine were performed with a table‐top micro‐Raman system exciting the analyte with a diode laser emitting at 785 nm. The main Raman features of 1,3,5‐trinitroperhydro‐1,3,5‐triazine were clearly identified, and a careful optimiz…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesSpectroscopy Techniques in Biomedical and Chemical Research

Optimized Slurries for Spray Drying: Different Approaches to Obtain Homogeneous and Deformable Alumina-Zirconia Granules

Valentina Naglieri、Dan Gutknecht、Vincent Garnier 等 6 位作者2013-11-21Materials

Spray drying is widely used for producing granulated feed materials for compaction process, which is the current industrial method for manufacturing alumina-zirconia femoral heads. The optimization of the granules compaction behavior requires the control of the slurry rheology. Moreover, for a dual-phase ceramic suspe…

Advanced ceramic materials synthesisGlass properties and applicationsInjection Molding Process and Properties

Nanoscale ionic materials based on hydroxyl-functionalized graphene

Liusuo Wu、Baoqing Zhang、Hao Lü 等 4 位作者2013-11-21Journal of Materials Chemistry A

Nanoscale ionic materials (NIMs) based on hydroxyl-functionalized graphene have been synthesized, which exhibit easily tunable flowing properties.

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesPolymer Nanocomposites and Properties

Fabrication, Characterization, and Evaluation in Drug Release Properties of Magnetoactive Poly(ethylene oxide)–Poly(l-lactide) Electrospun Membranes

Ioanna Savva、Andreani D. Odysseos、Loucas Evaggelou 等 8 位作者2013-11-21Biomacromolecules

The fabrication of electrospun magnetoactive fibrous nanocomposite membranes based on the water-soluble and biocompatible poly(ethylene oxide) (PEO), the biocompatible and biodegradable poly(L-lactide) (PLLA) and preformed oleic acid-coated magnetite nanoparticles (OA.Fe3O4) is reported. Visualization of the membranes…

Advanced Sensor and Energy Harvesting MaterialsNanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical Applications

The effect of sterilization methods on electronspun poly(lactide‐co‐glycolide) and subsequent adhesion efficiency of mesenchymal stem cells

Daikelly Iglesias Braghirolli、Daniela Steffens、Kerlin Quintiliano 等 8 位作者2013-11-21Journal of Biomedical Materials Research Part B Applied Biomaterials

The sterilization of scaffolds is an essential step for tissue engineering in vitro and, mainly, clinical biomaterial use. However, this process can cause changes in the structure and surface of the scaffolds. Therefore, the objective of this study was to investigate the effect of sterilization by ethanol, ultraviolet…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Fluorescent silk cocoon creating fluorescent diatom using a “Water glass-fluorophore ferry”

Tejas Sanjeev Kusurkar、Ishita Tandon、Niroj Kumar Sethy 等 7 位作者2013-11-21Scientific Reports

Fluorophores are ubiquitous in nature. Naturally occurring fluorophores are exceptionally stable and have high quantum yield. Several natural systems have acquired fluorescent signature due to the presence of these fluorophores. Systematic attempt to harvest these fluorophores from natural systems could reap rich comm…

Marine Sponges and Natural ProductsSilk-based biomaterials and applicationsDiatoms and Algae Research