Materials Literature
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Abstract An der Oberfläche von Festkörpern sind häufig strukturfremde Atome oder Atomgruppierungen gebunden. Die Chemie dieser „End‐Gruppen”︁ an der Festkörperoberfläche wird an einigen Beispielen besprochen. Bei Diamant und graphitischem Kohlenstoff und auch noch bei Siliciumdioxid sind die Fremdatome covalent gebund…
"Osmium black," a pigment very useful for cytological staining in both light and electron microscopy, may be deposited selectively at the tissue-binding sites of other metal ions by bridging OsO(4) to the tissue bound metal ion through a multidentate ligand.
Abstract The changes in dimensions and linear thermal expansion coefficients of several polycrystalline graphites irradiated at 170 and 200 °C are presented. The results are compared with the changes in these parameters which were observed in very highly oriented pyrolytic polycrystalline graphite and were discussed i…
Abstract Measurements are reported of the principal strains and changes in principal thermal expansion coefficients of various grades of pyrolytic graphite after fast-neutron bombardment at constant temperatures in the range 150 to 650 °C. The pyrolytic graphites used in these studies possess properties approaching th…
The phase diagrams of Na2WO4 and Na2MoO4 have been determined to 40–45 kbar. Two new high-pressure phases have been found for Na2WO4. The 440°C transition in Na2MoO4 consists of two transitions very close together. A further new high-pressure phase has been found. Crystallographic data are given for Na2WO4 I and Na2Mo…
Three-dimensional neutron-diffraction data have been collected for both the room-temperature (paraelectric) and the low-temperature (ferroelectric) phases of ammonium sulfate. Both phases are ordered. The transition, occurring at 223°K and involving a change from Space Group Pnam at room temperature to Space Group Pna…
Electron bombardment of ZnSe at 80\ifmmode^\circ\else\textdegree\fi{}K results in the production of two fluorescence bands at 5460 and 5850 \AA{}. The threshold for damage at 80\ifmmode^\circ\else\textdegree\fi{}K is 240 keV. When the sample is cooled to 4.2\ifmmode^\circ\else\textdegree\fi{}K following bombardment at…
A ferroelectric crystal can be considered as a (slight) modification of a certain nonferroelectric ideal crystal which is referred to as the "prototype" of the ferroelectric crystal; in crystallographical symmetry, the prototype should be higher than the ferroelectric crystal and equal to the paraelectric phase if pos…
Polycrystalline copper and aluminum were bombarded below 6\ifmmode^\circ\else\textdegree\fi{}K with monoenergetic electrons with energies in the range 0.15 to 2.1 MeV. The production rates of electrical resistivity were measured and the threshold energies for atom displacement were found to be 19\ifmmode\pm\else\textp…
Infrared-reflectivity measurements were made from 200 ${\mathrm{cm}}^{\ensuremath{-}1}$ to 800 ${\mathrm{cm}}^{\ensuremath{-}1}$ at temperatures ranging from 7.5 to 1060\ifmmode^\circ\else\textdegree\fi{}K for LiF and from 8 to 1950\ifmmode^\circ\else\textdegree\fi{}K for MgO. The reflection spectra were analyzed by m…
Abstract Cationic copolymerization of 1,3‐dioxolane with styrene was performed in toluene solution at 25°C. using boron fluoride etherate as catalyst. Determination of formaldehyde units in the copolymer showed that the two monomer units formed somewhat longer sequences in the copolymer chain than calculated on the as…
Formulas are derived for the calculation of surface tension and thermal expansion of organic liquids in terms of diamagnetic susceptibility, polarizability and density at a given temperature on the basis of KIRKWOODS potential of dispersion forces. The calculations are valid for normal liquids only. In combination wit…
Abstract Die Biegewechselfestigkeit von verschieden wärmebehandelten Mehrstoff‐Kupfer‐Aluminium‐Legierungen wurde in Luft, in destilliertem Wasser und künstlichem Seewasser mittels glatter und gekerbter Proben bestimmt. Die Korrosionswechselfestigkeit liegt für künstliches Seewasser am niedrigsten. Ein Einfluß des Gef…
The Reststrahl reflection characteristics in the wavelength region 1–25µ of silica films, a few thousand ångstroms in thickness, have been studied. The films were grown on silicon wafers under controlled conditions. The reflection maxima in the Si-O stretching and Si-O bending bands, which are observed with crystallin…
Abstract Complexes of saturated nitriles with metal chlorides polymerize readily. In this paper, the polymerization of acetonitrile was carried out with more nitrile, than was needed to form the complex with metal chlorides. The conversion of the polymer increased in comparison with the case of the polymerization of t…
This paper describes a simple loop plotter, which uses the transverse Kerr effect and is suitable for observation of hysteresis loops for ferromagnetic films of widely varying coercivity and surface finish. Examples are given of its application to a nickel-iron specimen of (i) large area and smooth surface and (ii) sm…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystallization of Massive Amorphous BoronJ. S. Gillespie Jr.Cite this: J. Am. Chem. Soc. 1966, 88, 11, 2423–2425Publication Date (Print):June 1, 1966Publication History Published online1 May 2002Published inissue 1 June 1966https://pubs.acs.org/doi/10.1021/ja00963a011https:…
The luminescences of chromium acetylacetonate and the nitro- and haloderivatives dissolved in three different isomorphous crystalline hosts have been studied as a function of temperature. The lifetimes and relative quantum yields were determined and evidence for two thermally activated nonradiative processes has been…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Kinetic Study of the Formation of the Ferrous-Nitric Oxide ComplexK. Kustin, I. A. Taub, and E. WeinstockCite this: Inorg. Chem. 1966, 5, 6, 1079–1082Publication Date (Print):June 1, 1966Publication History Published online1 May 2002Published inissue 1 June 1966https://pub…
High densities of faulted dislocation loops and stacking-fault tetrahedra have been observed in quenched copper and silver. In copper, the loops are polygonal with edges along <110> directions and vary in size up to 11 500 Å. On annealing, these large loops develop many additional edges along <110> directions. In silv…