Materials Literature
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Abstract A series of AB x ‐type triarylphosphine oxide monomers, bis‐(4‐fluorophenyl)‐(4‐hydroxyphenyl)phosphine oxide ( 4a ), bis‐(3,4‐difluorophenyl)‐(4‐hydroxyphenyl)phosphine oxide ( 4b ), and 4‐hydroxyphenyl‐bis‐(3,4,5‐trifluorophenyl)phosphine oxide ( 4c ) were prepared, characterized, and polymerized under nucl…
Abstract This Letter demonstrates a unique negative lateral shift of a Gaussian beam transmitted through a slab with both negative permittivity and permeability, which is distinctly different from a shift caused by a regular dielectric slab. The incident beam is modeled as a tapered wave with a Gaussian spectrum. The…
In this letter, we compare the properties of bulk and epitaxial ZnO. The ZnO thin films were grown on GaN templates and on ZnO single crystals by vapor phase deposition using Zn and NO2 as precursors. We use high-resolution x-ray diffraction to resolve the structural properties. The rocking curves of the bulk crystal…
Evaluation of thermal efficiency is of great importance for verifying the design optimization of microbolometer-based sensors. In this work, a measurement technique has been developed to determine the thermal efficiency of a microbolometer without using structural and material parameters. The microbolometer thermal ef…
A simulated-annealing direct-space approach has been applied to predict the crystal structures of a series of metallo-organic complexes containing Zn, Cu and Ni. The prediction methodology generates a set of energetically reasonable crystal structures among which the actual structure is present, but it is not always p…
Measurements of the self-diffusion coefficients D and the oxygen-17 and deuterium spin–lattice relaxation times T1 in light and heavy water have been extended into the supercooled region to a maximum pressure of 400 MPa and to a minimum temperature of 240 K and partly to even lower temperatures. With these measurement…
Polyurethane (PU) elastomers from castor oil based polyol, polyethylene glycol (PEG) of various molecular weight (200, 400, and 600) and toluene diisocyanate were prepared in the form of transparent sheets. The sorption, mechanical and thermal properties have been studied. The solubility parameter, molecular weight be…
Abstract The synthesis of the new chromophores 2‐{4‐[4‐( N , N ‐dihydroxyethylamino)‐phenylazo]‐phenyl}‐6‐nitrobenzoxazole ( 1 ) and 4‐[4‐( N , N ‐dihydroxyethylamino)phenylazo]‐benzoic acid ( 2 ) is described. Three homopolymers obtained by the polycondensation of 1 with propyloxy‐terephthalic acid and 1 and 2 with 2…
The effects of woven structures on fluid flow through the basic weaves of multifilament woven filter cloths were studied numerically by using the fluid-flow software fluent™. From results of the numerical solution, the flow pattern and the resistance to flow in the interstices were obtained. Results of this work show…
New supramolecular A2B2 co-polymers formed in solution from a rigid diporphyrin monomer (the A2 unit) and a short flexible dipyridine monomer (the B2 unit) are reported; NMR experiments show that complete binding occurs at mM concentrations; UV titrations reveal that the dipyridine unit and a monomeric control ligand…
Core level photoemission spectra from a free-standing bundle of single-wall carbon nanotubes have been measured using a high-flux soft x-ray spectromicroscope. The good signal-to-noise ratio for the C 1s emission provides information on fundamental quantities such as the core-hole lifetime and binding energy, free fro…
We grow multiwall carbon nanotube (CNT) films using thermal chemical vapor deposition at atmospheric pressure using a mixture of acetylene and nitrogen from a 4-nm-thick Ni film catalyst. CNTs are characterized using electron microscopy and Rutherford backscattering spectrometry. CNTs grown with this method are extrem…
The interaction of q = 0 delta- and lambda-Tb and Eu complexes with poly(dAdT), poly(dGdC) and calf-thymus DNA has been examined by absorption, emission and chiroptical spectroscopy and is sensitive to complex helicity, base-pair type and the nature of the lanthanide excited state.
The first attempt is undertaken to consider systematically topological structures of zirconosilicates and their analogs (60 minerals and 34 synthetic phases), where the simplest structure units are MO(6) octahedra and TO(4) tetrahedra united by vertices ([TO(4)]:[MO(6)] = 1:1-6:1). A method of analysis and classificat…
Brief treatment of azuliporphyrins 5 with nickel(II) or palladium(II) acetate in refluxing DMF afforded excellent yields of the related chelates; these novel organometallic compounds retain cross-conjugated borderline aromatic structures as judged by UV-Vis and NMR spectroscopy, and X-ray crystallography.
An efficient algorithm for hydrodynamical interaction of many deformable drops subject to shear flow at small Reynolds numbers with triply periodic boundaries is developed. The algorithm, at each time step, is a hybrid of boundary-integral and economical multipole techniques, and scales practically linearly with the n…
New L-lysine derivatives with a positively charged terminal can gel water below 1 wt%; particularly, 1a and 2a form a hydrogel at 0.3 wt% corresponding to approximately 12,300 and 12,500 waters/gelator molecule, respectively.
The thermal conductivities \ensuremath{\kappa} of high-density amorphous (HDA) ice and low-density amorphous (LDA) ice were measured under pressure. The results for HDA show typical glasslike behavior, i.e., positive $d\ensuremath{\kappa}/dT,$ whereas LDA exhibits crystal-like behavior, indicating that phonon-phonon s…
A unique negative lateral shift is demonstrated in this letter for a Gaussian beam reflected from a grounded slab with both negative permittivity and permeability, which is distinctly different from a shift caused by a regular grounded slab. The incident beam is modeled as a tapered wave with a Gaussian spectrum. The…
We report the first investigation of the photo-response of the conductivity of a new class of organic semiconductors based on functionalized pentacene. These materials form high quality single crystals that exhibit a thermally activated resistivity. Unlike pure pentacene, the functionalized derivatives are readily sol…