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Efficient Lewis Acid-Catalyzed Stereocontrolled Radical Polymerization of Acrylamides

Yutaka Isobe、Daigo Fujioka、Shigeki Habaue 等 4 位作者2001-06-26Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTEfficient Lewis Acid-Catalyzed Stereocontrolled Radical Polymerization of AcrylamidesYutaka Isobe, Daigo Fujioka, Shigeki Habaue, and Yoshio OkamotoView Author Information Department of Applied Chemistry Graduate School of Engineering, Nagoya University Furo-cho, Chiku…

Polyoxometalates: Synthesis and ApplicationsAdvanced Polymer Synthesis and CharacterizationCovalent Organic Framework Applications

Phonon Spectrum in a Nanoparticle Mechanically Coupled to a Substrate

Kelly R. Patton、Michael R. Geller2001-06-26arXiv

We calculate the vibrational density-of-states in an insulating nanoparticle that is in weak mechanical contact with a semi-infinite substrate. The work is motivated by a recent experiment by Yang et al., where the low-energy phonon density-of-states of Y2O3 nanoparticles doped with Eu was measured. Preliminary result…

Materials ScienceMesoscale and Nanoscale Physics

Production of ordered silicon nanocrystals by low-energy ion sputtering

Raul Gago、Luis Vazquez、Rodolfo Cuerno 等 6 位作者2001-06-26arXiv

We report on the production of ordered assemblies of silicon nanostructures by means of irradiation of a Si(100) substrate with 1.2 keV Ar ions at normal incidence. Atomic Force and High-Resolution Transmission Electron microscopies show that the silicon structures are crystalline, display homogeneous height, and spon…

cond-mat.stat-mechMaterials Science

Structure of a superconducting vortex pinned by a screw dislocation

Eugene M. Chudnovsky2001-06-26arXiv

Spatial dependence of the magnetic field and the superconducting current in a flux line pinned by a screw dislocation are computed. Interaction of a superconducting vortex with the chiral-symmetry breaking elastic strain of a screw dislocation results in a helical current along the axis of the dislocation. It is argue…

Materials ScienceSuperconductivity

Resonant peak splitting for ballistic conductance in magnetic superlattices

Z. Y. Zeng、L. D. Zhang、X. H. Yan 等 4 位作者2001-06-26arXiv

We investigate theoretically the resonant splitting of ballistic conductance peaks in magnetic superlattices. It is found that, for magnetic superlattices with periodically arranged $n$ identical magnetic-barriers, there exists a general $(n-1)$-fold resonant peak splitting rule for ballistic conductance, which is the…

Mesoscale and Nanoscale PhysicsMaterials Science

Field Effect Magnetization Reversal in Ferromagnetic Semiconductor Quantum Wells

Byounghak Lee、T. Jungwirth、A. H. MacDonald2001-06-26arXiv

We predict that a novel bias-voltage assisted magnetization reversal process will occur in Mn doped II-VI semiconductor quantum wells or heterojunctions with carrier induced ferromagnetism. The effect is due to strong exchange-coupling induced subband mixing that leads to electrically tunable hysteresis loops. Our mod…

Materials Science

Magnetic Susceptibility Study of the Heavy Rare Earth Stannate Pyrochlores

V. Bondah-Jagalu、S. T. Bramwell2001-06-26arXiv

The series of magnetic rare earth pyrochlore stannates R2Sn2O7 (R = rare earth, except Ce and Pm) have been investigated by powder susceptibility measurements down to T =1.8 K. The results are compared to results for the analogous titanate series, which are well-known frustrated magnets. Unlike the titanates, the whol…

Materials Science

Fragility of the spin-glass-like collective state to a magnetic field in an interacting Fe-C nanoparticle system

P. E. Jönsson、S. Felton、P. Svedlindh 等 5 位作者2001-06-26arXiv

The effect of applied magnetic fields on the collective nonequilibrium dynamics of a strongly interacting Fe-C nanoparticle system has been investigated. It is experimentally shown that the magnetic aging diminishes to finally disappear for fields of moderate strength. The field needed to remove the observable aging b…

Materials Sciencecond-mat.dis-nn

Optical properties of BN in cubic and layered hexagonal phases

Giancarlo Cappellini、Guido Satta、Maurizia Palummo 等 4 位作者2001-06-26Physical review. B, Condensed matter

Linear optical functions of cubic and hexagonal BN have been studied within first principles density functional theory in the local density approximation. Calculated energy-loss functions show reasonable agreement with experiments and previous theoretical results both for h-BN and for c-BN. Discrepancies arise between…

2D Materials and ApplicationsBoron and Carbon Nanomaterials ResearchGraphene research and applications

Physical Kinetics of Ferroelectric Hysteresis

S. Sivasubramanian、A. Widom2001-06-26arXiv

The physical kinetics of single domain ferroelectric materials are studied using Landau-Khalatnikov equation. The hysteretic curves are obtained numerically. The effective coercive electric field theoretically varies with the driving amplitude and frequency. The effects of thermal noise are explored using the Fokker-P…

Materials Sciencecond-mat.stat-mech

Strain Hardening at Large Strains as Predicted by Dislocation Based Polycrystal Plasticity Model

La ́szlo ́ S. To ́th、A. Molinari、Yuri Estrin2001-06-26Journal of Engineering Materials and Technology

A recent strain hardening model for late deformation stages (Estrin, Y., To´th, L.S., Molinari, A., and Bre´chet, Y., Acta Materialia, 1998, “A dislocation-based model for all hardening stages in large strain deformation,” Vol. 46, pp. 5509-5522) was generalized for the 3D case and for arbitrary strain paths. The mode…

Microstructure and mechanical propertiesHigh-Velocity Impact and Material BehaviorMetallurgy and Material Forming

Influence of Charge Density and Ionic Strength on the Multilayer Formation of Strong Polyelectrolytes

Roland Steitz、Werner Jaeger、Regine von Klitzing2001-06-26Langmuir

The influence of ionic strength and polymer charge density on the multilayer formation of strong polyelectrolytes is investigated by X-ray reflectivity. To a first approximation the adsorption behavior as a function of the degree of charge, f, is binary: For f ≤ 50% the films are one order of magnitude thinner than th…

Surface Modification and SuperhydrophobicityElectrostatics and Colloid InteractionsPolymer Surface Interaction Studies

Thin-Film Deposition of Organic−Inorganic Hybrid Materials

David B. Mitzi2001-06-26OpenAlex

Organic−inorganic hybrid films present special challenges and opportunities with respect to potential applications, as well as for the observation of interesting physical phenomena. Although the often disparate characteristics (e.g., solubility and thermal stability) of the two components provide a potential barrier t…

Polyoxometalates: Synthesis and ApplicationsMesoporous Materials and CatalysisPolymer Surface Interaction Studies

The complete genome of the crenarchaeon Sulfolobus solfataricus P2

Qunxin She、Rama Kant Singh、Fabrice Confalonieri 等 31 位作者2001-06-26OpenAlex

The genome of the crenarchaeon Sulfolobus solfataricus P2 contains 2,992,245 bp on a single chromosome and encodes 2,977 proteins and many RNAs. One-third of the encoded proteins have no detectable homologs in other sequenced genomes. Moreover, 40% appear to be archaeal-specific, and only 12% and 2.3% are shared exclu…

Enzyme Structure and FunctionBacterial Genetics and BiotechnologyPolyamine Metabolism and Applications

Integrated porous-silicon light-emitting diodes: A fabrication process using graded doping profiles

Giuseppe Barillaro、A. Diligenti、Francesco Pieri 等 5 位作者2001-06-25Applied Physics Letters

A fabrication process, compatible with an industrial bipolar+complementary metal–oxide–semiconductor (MOS)+diffusion MOS technology, has been developed for the fabrication of efficient porous-silicon-based light-emitting diodes. The electrical contact is fabricated with a double n+/p doping, achieving a high current i…

Silicon Nanostructures and PhotoluminescenceSemiconductor materials and devicesNanowire Synthesis and Applications

Surface-emitting, single-lobe operation from second-order distributed-reflector lasers with central grating phaseshift

Gunawan Witjaksono、D. Botez2001-06-25Applied Physics Letters

Surface-emitting diode lasers containing a second-order Bragg grating with a central phaseshift, Δφ, of values around π are found to fundamentally favor lasing in a mode of symmetric near-field amplitude profile, which in turn provides emission in a single-lobed beam orthonormal to the surface. Devices of 500 μm long…

Semiconductor Lasers and Optical DevicesAdvanced optical system designOptical Coatings and Gratings

Properties of highly (100) oriented Ba0.9Sr0.1TiO3/LaNiO3 heterostructures prepared by chemical solution routes

G.S. Wang、Jinguang Cheng、Xiangjian Meng 等 10 位作者2001-06-25Applied Physics Letters

Highly (100) oriented Ba0.9Sr0.1TiO3/LaNiO3 heterostructures have been grown on Si(100) using chemical solution routes. X-ray diffraction analysis shows that Ba0.9Sr0.1TiO3 thin films are high (100) orientation (α100=0.92). Atomic force microscopy investigation shows that they have large grains about 80–200 nm. A Pt/B…

Multiferroics and related materialsFerroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics Synthesis

Self-organized Cu–Ag nanocomposites synthesized by intermediate temperature ion-beam mixing

Raúl A. Enrique、Pascal Bellon2001-06-25Applied Physics Letters

We perform an investigation of ion-beam mixing in the immiscible system Ag–Cu based on cross-sectional transmission electron microscopy. Multilayered samples consisting of ten periods of (6.7 nm Cu/11.2 nm Ag) are irradiated at temperatures ranging from 25 to 225 °C with normally incident 1 MeV Kr ions to doses in the…

nanoparticles nucleation surface interactionsMaterial Dynamics and PropertiesIon-surface interactions and analysis

Two different mechanisms of formation of quantum dots in borosilicate glass

M. H. Yükselici2001-06-25Journal of Physics Condensed Matter

The nucleation and growth of Cd 1- x Zn x S and CdS x Se 1- x nanocrystals in borosilicate glass are investigated through optical absorption and resonant Raman scattering measurements. The optical absorption spectra are interpreted with the help of a quantized-state effective-mass model applied for heterogeneous and h…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsGlass properties and applications

Excitons in small hydrogenated Si clusters

A. R. Porter、M. D. Towler、R. J. Needs2001-06-25Physical review. B, Condensed matter

The excitonic states of four small hydrogenated Si clusters $({\mathrm{SiH}}_{4},{\mathrm{Si}}_{2}{\mathrm{H}}_{6},{\mathrm{Si}}_{5}{\mathrm{H}}_{12},$ and ${\mathrm{Si}}_{10}{\mathrm{H}}_{16})$ are studied using the diffusion quantum Monte Carlo approach. The importance of using accurate guiding wave functions is str…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceAdvanced Chemical Physics Studies