Materials Literature
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Long-lasting phosphorescence is observed in Ce3+-doped Ca2Al2SiO7 (CASM) and CaYAl3O7 (CYAM) crystals at room temperature. UV irradiation at 365 nm produces broadband emissions with peaks at 417 nm for CASM and 425 nm for CYAM, which persist for not less than 1 h after the removal of the irradiating light. Based on th…
Accurate atomic coordinates of the room-temperature (root3xroot3)R30degree and low-temperature (3x3) phases of 1/3 ML Sn on Ge(111) have been established by grazing-incidence x-ray diffraction with synchrotron radiation. The Sn atoms are located solely at T4-sites in the (root3xroot3)R30degree structure. In the low te…
A detailed structural model for the indium-induced Si(111)-(4x1) surface reconstruction has been determined by analyzing an extensive set of x-ray-diffraction data recorded with monochromatic ($\hbarω$ = 9.1 keV) synchrotron radiation. The reconstruction is quasi-one-dimensional. The main features in the structure are…
The Mn-terminated (001) surface of the stable anti-ferromagnetic insulating phase of cubic perovskite CaMnO$_3$ is found to undergo a magnetic reconstruction consisting on a spin-flip process at surface: each Mn spin at the surface flips to pair with that of Mn in the subsurface layer. In spite of very little Mn-O cha…
The structure and properties of a geometrically constrained magnetic wall in a constriction separating two wider regions are investigated theoretically. They are shown to differconsiderably from those of an unconstrained wall, so that the geometrically constrained magnetic wall truly constitutes a new kind of magnetic…
The aging of an industrial thermoplastic elastomer polyurethane (TPU)-coated fabric, based on a polyether diol and an aromatic diisocyanate, is studied in artificial weathering tests. It is noticed that the degradation of this TPU-coated fabric leads to a weight loss, to the formation of a reticulated layer in sample…
This paper describes the process optimization in injection molding of high-density polyethylene (HDPE). Both conventional injection molding and shear controlled orientation (SCORIM) were employed in processing. The process optimization was based on design of experiments and complemented with analysis of variance. Mech…
In search of a better understanding of catalyst effects on final product qualities of polypropylene, an attempt was made to establish a correlation between catalyst type, polymer chain structure of homopolymers, crystallization behavior, as well as final morphology and mechanical properties. Conventional Ziegler–Natta…
Polymeric granules were prepared by matrix encapsulation containing 20, 35 and 50% (w/w) of natural liquid pesticide viz., Azadirachta Indica A. Juss. (neem) seed oil (NSO) per dry weight of urea formaldehyde crosslinked starch (UF-St), guar gum (UF-GG) and UF-(St + GG) matrices. Results of swelling and cumulative rel…
Wood could provide better service in some applications if it were harder and more dimensionally stable. In this study, wood–polymer composites (WPC) made with different chemical combinations were evaluated for dimensional stability, ability to exclude water vapor and liquid water, and hardness. Pine, maple, and oak so…
Residual softwood was thermomechanically pretreated and used to produce composites with no synthetic binders. The lignocellulosic material was steam exploded with a thermomechanical aqueous vapor process in a continuous tubular reactor. The study attempts to use the intrinsic bonding capacity of the steamed fiber, whi…
This paper describes the process optimization in injection molding of high-density polyethylene (HDPE). Both conventional injection molding and shear controlled orientation (SCORIM) were employed in processing. The process optimization was based on design of experiments and complemented with analysis of variance. Mech…
Maximum entropy method (MEM) charge density analysis has been carried out on synchrotron X-ray powder diffraction data of a series of anhydrous sodalites, M 6 (AlSiO 4 ) 6, M = Na, Ag, Tl. Analysis of the MEM electron densities reveals the nature of the interactions in the structures. The sodium atoms are bonded to th…
The adsolubilization of 2-naphthol by tetradecyltrimethylammonium bromide (TTAB) and by mixtures of TTAB and hydrophobically modified polyacrylamide (HMPAM) on Na-kaolinite was investigated. At concentrations of TTAB in the region of the CMC, only small differences were found in the amounts of 2-naphthol adsolubilized…
We have designed, synthesized and characterized eight cavitand-based de novo four-helix bundles, where each helix contains the basis sequence EELLKKLEELLKKG. We find that each de novo protein is highly helical and extremely stable to the chemical denaturant guanidine hydrochloride (GuHCl). We studied the effect of the…
Previously a rough correlation between the logarithm of the most probable secondary β-relaxation time at the glass temperature T g, log[ τ β ( T g )], and the Kohlrausch−Williams−Watts (KWW) exponent, (1 − n ), of the primary α - relaxation correlation function exp[−( t / τ α ) 1- n ] was found when examining a whole…
The synthesis and in situ photopolymerization of reactive liquid crystals for the preparation of materials with different degrees of cross-linking is described. The molecular orientation of polymeric films can be controlled by orienting the monomeric photopolymerizable materials in the mesomorphic state. The birefring…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTElectrochemical and Chemical Oxidation of Gold(I) Thiolate Phosphine Complexes: Formation of Gold Clusters and DisulfideJinhua Chen, Tong Jiang, Gang Wei, Ahmed A. Mohamed, Craig Homrighausen, Jeanette A. Krause Bauer, Alice E. Bruce, and Mitchell R. M. BruceView Autho…
The lattice disordering transition (LDT) and the domain dissolution transition (DDT) of a highly asymmetric polystyrene- block -poly(ethylene- co -but-1-ene)- block -polystyrene (SEBS-8) triblock copolymer with a volume fraction of polystyrene (PS) block of 0.084 have been investigated by small-angle X-ray scattering…
The synthesis of diarylethyne-linked multiporphyrin arrays requires Pd-mediated coupling conditions that are performed in dilute solution in the absence of copper and that give reaction mixtures that are easily purified. We previously developed copper-free Pd-mediated coupling conditions (Pd 2 (dba) 3 and AsPh 3 in to…