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Laboratory Studies Relating Mineral Quality of Water to Corrosion of Steel and Cast Iron
The influence of combinations of various normal mineral components in domestic waters on the rate of corrosion of cast iron and steel and on the development of tuberculation is reported. Tests were conducted with air saturated waters at room temperature with velocities of 0.1-1.0 fps and with pH controlled by carbon d…
PHOTOCHEMICAL REACTIONS OF KETONES IN SOLUTION
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPHOTOCHEMICAL REACTIONS OF KETONES IN SOLUTIONN. C. Yang and Ding-Djung H. YangCite this: J. Am. Chem. Soc. 1958, 80, 11, 2913–2914Publication Date (Print):June 1, 1958Publication History Published online1 May 2002Published inissue 1 June 1958https://pubs.acs.org/doi/10.1021…
METALLOGRAPHY OF TITANIUM ALLOYS
Because of the importance of mnetalography to the technolagy of titanium and because of the current interest in titanium technology, it is essential that the metallurgists working with titanium understand its metallography. In this report emphasis is placed on the microstructures of titanium and its alloys. The report…
Cyclisationen Von Langkettigen Dithiolen. Versuche zur Darstellung sich umfassender Ringe mit Hilfe von Einschlußverbindungen
Abstract Langkettige Dithiole unterschiedlicher Kettenlänge mit verschieden substituierten, mittelständigen aromatischen Ringen lassen sich zu makrocyclischen Disulfiden (Ringgliederzahl 18, 20, 24 und 28) mit Ansa‐Struktur dehydrocyclisieren. Alle untersuchten Dithiole geben Einschlußverbindungen mit α‐ bzw. β‐ Cyclo…
Thin Sections
Knowledge of the thickness of sections is important for proper interpretation of electron micrographs. Therefore, the thicknesses of sections of n-butyl methacrylate polymer were determined by ellipsometry, and correlated with the color shown in reflected light. The results are: gray, thinner than 60 mmicro; silver, 6…
Bound—Rubber Formation in Diene Polymer Stocks
Abstract The phenomenon of insolubilization of rubber by carbon black has been known for at least twenty-seven years. There have been many attempts during this time to establish a relationship between insolubilization, or bound rubber formation, and reinforcement of rubber by carbon black. It was postulated, as far ba…
A Two-Dimensional Load-Extension Tester for Fabrics and Film
Fabrics in use are rarely subjected to extensions in only one direction, though fabric load-extension testing is normally done in this way. A two-dimensional tester has been constructed with which load-extension curves for both weft and warp directions (or any other mutually perpendicular directions) are recorded simu…
Heat and ultraviolet aging of poly(vinyl chloride)
F?ur poly~vinyl chloride) polymers l?repared with different initiators were exposed to ultravIOlet radIant energy and to heat, III a vacuum and in air.The gaseous products evo!ved were analyzed by mass spectrometry.Changes in chemical structure were followed by Illfrared spectrophotometry.Benzene was among the product…
Origin of the Magnetic Anisotropy Energy of Antiferromagnetic Cr2O3
The magnetic anisotropy constant Cr 2 O 3 arising from the dipolar interactions among the chromic ions was calculated to be -0.059 cm -1 per ion at absolute zero, and the magnetic anisotropy constant due to the crystalline field combined with the spin-orbit coupling was estimated from the fine-structure coupling const…
Shape of Liquid Immiscibility Volume in the System Barium Oxide‐Boric Oxide‐Silica
The shape of the immiscibility volume in the system BaO‐B 2 O 3 ‐SiO 2 is determined from data on seventeen compositions. The ternary critical solution curve originates at the critical point in the binary system BaO‐B 2 O 3 , located at 1225°C. and 15 weight % BaO. It extends almost linearly to its terminus on the sil…
Methods for Increasing The Corrosion Resistance of Metal Alloys
A detailed investigation is made of the general laws governing the increase of corrosion resistance of metallic systems by means of alloying. The role of local cells in alloy corrosion is considered briefly. Some attention is given also to the control characteristics of corrosion processes. Other topics discussed incl…
Electrical and Optical Properties of Synthetic Calcium Titanate Crystal
The optical density of a flame fusion single crystal plate of CaTiO3 is reported. The refractive indices for the visible region are given, with nD = 2.403±0.02. The results of dielectric constant and loss measurements over the temperature range from 90 to 430°K reveal no unusual behavior. A room-temperature dielectric…
The crystal structure of KHSO4(mercallite)
The structure of KttSO 4 has been determined and refined in two projections. The two ttSO~-groups in the asymmetric unit are differently linked by hydrogen bridges: one set forms 'dimers' across a symmetry centre; the other is linked into infinite chains along a glide plane. All hydrogen bridges are approximately alon…
Separation of Orthohydrogen from Parahydrogen and of Paradeuterium from Orthodeuterium by Preferential Adsorption
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSeparation of Orthohydrogen from Parahydrogen and of Paradeuterium from Orthodeuterium by Preferential AdsorptionClarence M. Cunningham, Douglas S. Chapin, and Herrick L. JohnstonCite this: J. Am. Chem. Soc. 1958, 80, 10, 2382–2384Publication Date (Print):May 1, 1958Publicat…
Theory of Dilute Polymer Solution. I. Excluded Volume Effect
A statistical theory of the excluded volume effect in a polymer molecule is developed, making use of a pearl necklace model with a continuous medium approximation. For the mean square end-to-end distance 〈R2〉 and the mean square radius of gyration 〈S2〉, the theory leads to the same expressions as Zimm, Stockmayer, and…
Specific volume and degree of crystallinity of semicrystalline poly(chlorotrifluoroethylene), and estimated specific volumes of the pure amorphous and crystalline phases
Specific Volume and Degree of Crystallinity of Semicrystalline Poly (chlorotrifluoroethylene), and Estimated Specific Volumes of
Effect of Environmental Nuclei in Electron Spin Resonance Spectroscopy
Occasionally an electron paramagnetic resonance absorption line is accompanied by satellite lines which result from a weak magnetic dipole-dipole interaction coupling the electron spin to a neighboring nuclear spin. The satellites correspond to a change in spin state of the neighbor nucleus concurrent with the change…
Verarbeitungs‐ und Verwendungsmöglichkeiten von Fluorcarbon‐Kunststoffen
Abstract Berichtet wird von den Anfängen der Fluorchemie und der ersten Darstellung von Polytetrafluoräthylen und Polytrifluorchloräthylen. Die strategische Bedeutung und die Kombination von Eigenschaften lassen erkennen, daß besonders Polytetrafluoräthylen ein unentbehrliches Hilfsmittel in vielen Industriezweigen wi…