Materials Literature
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Abstract Die Titelverbindung entsteht aus Kupfer(I)‐trimethylsiloxid durch thermische Abspaltung von Hexamethyldisiloxan. Ihre Struktur wurde röntgenographisch bestimmt (Raumgruppe C 2/ m , Z = 2) und bis R = 0.079 verfeinert. Die Verbindung stellt ein voluminöses, kugelförmiges Molekül dar, das im inneren Teil achtze…
Magnetism of LaNi 1- x Fe x O 3 (0≤ x ≤0.2) is investigated from 7 K to 300 K. The susceptibility of LaNiO 3 is temperature independent. The increment of the susceptibility, Δ χ, by Fe doping obeys the Curie-Weiss law at high temperatures. The effective number of Bohr magnetons is about 4 µ B per Fe ion. The asymptoti…
Tissue extracts from the digestive tract of the wood-boring bivalve Bankia gouldi were tested for their ability to degrade celluloses and wood to soluble sugars. Tissue extracts showed high levels of glucose production from cellobiose, demonstrating the presence of β-glucosidase. The crystal structure of cellulose det…
Small-angle scattering intensities were observed for amorphous Pd80Si20, which was irradiated by fast neutrons to a fluence of 5 × 1020 neutrons cm−2. A broad hump was observed at 2 sin θ/λ = 0.05 Å−1. The structural inhomogeneities produced by the neutron irradiation are discussed with the aid of the results of wide-…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic Raman spectra of hexahalogenoosmate(IV) ions in the resonant conditionKenichi Ikeda and Shiro MaedaCite this: Inorg. Chem. 1978, 17, 10, 2698–2701Publication Date (Print):October 1, 1978Publication History Published online1 May 2002Published inissue 1 October 1978…
Kittel's free energy expression with all the fourth order cross terms of two sublattice polarizations was dealt with. Phase diagrams of four phases, the nonpolar, polar, antipolar, and semipolar phase, were calculated for various sets of expansion coefficients. For a set of coefficients, the semipolar phase is absolut…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectron-transfer kinetics of chlorotetrakis(p-chlorophenyl)porphinatomanganese(III) in dimethyl sulfoxide-imidazole mixturesK. M. Kadish, M. Sweetland, and J. S. ChengCite this: Inorg. Chem. 1978, 17, 10, 2795–2797Publication Date (Print):October 1, 1978Publication History…
The complex dielectric constant of Fe has a large imaginary part and small real part throughout most of the visible region (∊i ≫ |∊r|). Under this condition a thin film of Fe(≤ 20 nm), bounded by a dielectric, can support a surface polariton. For p-polarized fields the antisymmetric solution to the dispersion relation…
Electron and hole drift mobilities have been measured in Ge x Se 1- x glasses ( x =0.15, 0.2 and 0.4) by means of the time of flight technique. The hole mobility (8.5-1.6×10 -2 cm 2 /V·sec, 300 K) is smaller than the electron mobility (1.0-7.4×10 -1 cm 2 /V·sec, 300 K) in contrast with the cast of other chalcogenide g…
Abstract Nonstoichiometric iron (III) oxichloride is capable of intercalating a large number of guest molecules with Lewis base character, e.g. dimethylsulfoxide, formamide, hexa-methylphosphortriamide, or alkylamines, while the reactions of stoichiometric FeOCl are restricted to pyridine and its derivatives only. The…
Abstract ABA‐type “tapered” block copolymers of α‐methylstyrene (monomer A) and butadiene were prepared using four commercially available dilithio initiators. Polymerizations were run at 25°C in benzene solvent, or at 40°C with butadiene dissolved in neat α‐methylstyrene. Although α‐methylstyrene has a rather low ceil…
Article Crystal structure of LiH2PO4, structural topology and hydrogen bonding in the alkaline dihydrogen orthophosphates was published on October 1, 1978 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 146, issue 1-6).
Abstract Different samples of high‐density polyethylene provided different nucleation densities which were assessed by optical microscopy and light scattering. Crystallizations were carried out under controlled cooling rates using a microscope hot stage and DSC from which crystallization temperatures were obtained. It…
The Fermi surface touching the Brillouin zone boundary not only stabilises the BCC crystal structure, but also promotes ferromagnetism in Heusler alloys.
Results are presented and analyzed for mixtures of normal and deuterated polyethylene. Some of the results are used to determine single-chain radii of gyration in bulk polyethylene. The radii of gyration are found to be smaller for solution-crystallized samples than for melt-crystallized samples and smaller for slowly…
Voltage oscillations observed in switching VO2 needles are associated with traveling semiconductor domains driven by the Peltier effect at their boundaries. The model is supported by the dependence on current of the two time constants characterizing the rectangular synchronous oscillations.
Staphylococcus epidermidis ATCC 14990 possesses an l-lactate dehydrogenase dependent on nicotinamide adenine dinucleotide (NAD) which is activated by fructose 1,6-bisphosphate (fructose-1,6-P2). Molecular weight studies with purified l-lactate dehydrogenase showed that fructose-1,6-P2 is necessary to stabilise the tet…
Abstract The degradation of ammonium polymethacrylate and polymethacrylamide has been studied by a combination of thermal analysis methods (TVA and TG) and examination of volatile and involatile products by infrared analysis. It is shown that total reaction comprises an initial cyclization and further fragmentation of…
An idealized composite model of a square biaxially loaded coated fabric is proposed. The model consists of straight linearly elastic yarns embedded in a thin layer of a linearly elastic isotropic coating material with the system loaded in the plane of the membrane. Governed by the assumptions of small strains, equatio…
Heat-capacity and magnetic-susceptibility measurements at low temperatures on single crystals of RbCo${\mathrm{Cl}}_{3}$\ifmmode\cdot\else\textperiodcentered\fi{}2${\mathrm{H}}_{2}$O are described here which indicate that this material is the first reported example of a magnet which can be formally described as having…