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Sedimentation Coefficients of Linear and Cyclic Wormlike Coils with Excluded-Volume Effects

Horace B. Gray、Victor A. Bloomfield、John E. Hearst1967-02-15The Journal of Chemical Physics

The sedimentation coefficient for the Kratky—Porod wormlike coil is calculated with the effects of excluded volume taken into account. The statistical length of native DNA is found to be 900 Å. The hydrodynamic diameter of the Watson—Crick helix is 26–27 Å. Sedimentation coefficients are calculated to decrease by abou…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesElectrostatics and Colloid Interactions

Electron Spin Resonance and Optical Absorption Studies of Cr3+ in a Phosphate Glass

Robert J. Landry、J.T. Fournier、Charles G. Young1967-02-15The Journal of Chemical Physics

Optical absorption and electron spin resonance (ESR) spectra of a chromium-doped phosphate glass have been studied as a function of Cr2O3 concentration. While the optical spectrum appears to be independent of chromium-ion density, the ESR spectrum exhibits a pronounced concentration dependence. The spectra have been a…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Glass Transition in o -Terphenyl

R. J. Greet、David Turnbull1967-02-15The Journal of Chemical Physics

Volumetric and thermal measurements on its undercooled liquid indicate that o-terphenyl undergoes a glass transition in the vicinity of −30°C. This glass temperature is about 60°C higher than that predicted by correlations applicable to simple molecular glass formers. The viscosity of the undercooled liquid was measur…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesGlass properties and applications

Optical Properties of SomeF-Aggregate Centers in LiF

J. Nahum、D. A. Wiegand1967-02-15Physical Review

Detailed studies have been made of the emission and associated excitation and absorption spectra of x-irradiated LiF. By studies of changes in the spectra during periods in the dark and during subsequent reirradiation, and by use of the Mollwo-Ivey relationships, it has been possible to identify optical bands associat…

Luminescence Properties of Advanced MaterialsOrganic Light-Emitting Diodes ResearchInorganic Fluorides and Related Compounds

Electrical and Optical Properties of Amorphous Germanium

A. H. Clark1967-02-15Physical Review

Measurements of density, optical absorption, resistivity, photoconductivity, and Hall effect have been made on amorphous Ge films ranging in thickness from 1 to 23 \ensuremath{\mu}. The density was found to be 3.9\ifmmode\pm\else\textpm\fi{}0.4g/${\mathrm{cm}}^{3}$. The absorption coefficient (measured at room tempera…

Glass properties and applicationsPhase-change materials and chalcogenidesSemiconductor materials and interfaces

Extrinsic Recombination Radiation from Natural Diamond: Exciton Luminescence Associated with theN9Center

D.R. Wight、P. J. Dean1967-02-15Physical Review

A luminescence system with no-phonon lines at 5.251 and 5.261 eV (at 100\ifmmode^\circ\else\textdegree\fi{}K), observed in the edge luminescence spectra of natural diamonds containing relatively low concentrations of nitrogen in "platelet" form, has been identified with the so-called $N9$ center which is responsible f…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Excitation Spectrum of Aluminum Acceptors in Diamond under Uniaxial Stress

P. A. Crowther、P. Dean、W.F. Sherman1967-02-15Physical Review

A high-resolution survey of the 0.30-0.37-eV spectra, attributed to transitions at acceptor centers, obtained from several natural $p$-type semiconducting diamonds at 80\ifmmode^\circ\else\textdegree\fi{}K, is presented. Effects on the spectrum of destruction of the normal site symmetry (${T}_{d}$) by uniaxial compres…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Magnetic Susceptibility Measurements of Rutile and the Magnéli Phases of the Ti-O System

L.K. Keys、L. N. Mulay1967-02-10Physical Review

Magnetic-susceptibility measurements of the Magn\'eli phases of the Ti-O system show a change from weak covalent bond formation, through antiferromagnetic to paramagnetic-like behavior with increasing oxygen concentration. The reciprocal molar susceptibility plotted versus temperature indicates collective electron eff…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsInorganic Chemistry and Materials

Ferroelectric "Soft" Mode in KTaO3

C. H. Perry、T. McNelly1967-02-10Physical Review

The far infrared reflectivity of KTa${\mathrm{O}}_{3}$ has been studied as a function of temperature from 12 to 463\ifmmode^\circ\else\textdegree\fi{}K. The results have been analyzed by means of a Kramers-Kronig method, and indicate a "soft" mode, lowering its frequency as the temperature is lowered towards the "Curi…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Nature of Ferroelectricity in KNO3

Arthur Chen、F. Chernow1967-02-10Physical Review

The lattice parameters of KN${\mathrm{O}}_{3}$ were measured in the temperature region of the ferroelectric transition. The changes in the lattice parameters as the crystal undergoes the paraelectric-to-ferroelectric transition have been interpreted as being due to the electrostriction effect. The dielectric constants…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Optical Phonons in Electron Spin Relaxation

Chao‐Yuan Huang1967-02-10Physical Review

An approximate dispersion curve for the optical branch of the lattice vibration is used to estimate the spin-lattice relaxation time attributed to optical phonons. The relaxation rate is found to be ${{T}_{1}}^{\ensuremath{-}1}\ensuremath{\propto}\mathrm{exp}(\ensuremath{-}\frac{\ensuremath{\hbar}{\ensuremath{\omega}}…

Quantum and electron transport phenomenaSpectroscopy and Quantum Chemical StudiesSolid-state spectroscopy and crystallography

Absolute Measurements of Total Cross Sections for the Scattering of Low-Energy Electrons by Atomic and Molecular Oxygen

Gabriel Sunshine、B. B. Aubrey、Benjamin B. Bederson1967-02-05Physical Review

The atom-beam recoil technique has been used to measure absolute total cross sections for the scattering of electrons by atomic and molecular oxygen at 22 energies between 0.5 and 11.3 eV, with additional data obtained up to 100 eV. In this method, a modulated electron beam cross-fires an atom beam, whose attenuation…

Plasma Diagnostics and ApplicationsX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Multivariable Studies of Nonwoven Fabrics

S. C. Winchester、John C. Whitwell1967-02-01Journal of Engineering for Industry

The performance characteristics of nonwoven fabrics have been studied as a function of fiber properties, binder properties, and web construction. The particular type of non-woven selected for study was a web of random-laid base fibers in which randomly placed thermoplastic fibers provide the bonds. The responses studi…

Mechanical Behavior of CompositesTextile materials and evaluationsMaterial Properties and Processing

Electron Diffraction and Micrographic Study of the High-Temperature Changes in Illite and Montmorillonite Under Continuous Heating Conditions

Robert B. Furlong1967-02-01Clays and Clay Minerals

Abstract Transmission and diffraction electron micrographs were made of illite and montmorillonite to study the changes that take place as the clays were heated continuously to 1200°C. In both of the clay minerals studied, expulsion of a highly fluid material occurred subsequent to dehydroxylation and prior to the dev…

Geological and Geochemical AnalysisSoil and Unsaturated FlowClay minerals and soil interactions

Self-Diffusion and Transport Mechanisms in Cubic Lithium Sulphate

Arnold Kvist、Ulf Trolle1967-02-01Zeitschrift für Naturforschung A

The self-diffusion coefficient of the lithium ion in cubic lithium sulphate has been measured from 640 to 790°C. From electrical conductivity and electromigration experiments it has been found that several cations are moving in phase and the mean value of the number of ions in each group has been estimated to be about…

Solid-state spectroscopy and crystallography

Negative Photoconductivity in Gold-Doped Silicon

John R. Barrett、G.C. Gerhard1967-02-01Journal of Applied Physics

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation J. R. Barrett, G. C. Gerhard; Negative Photoconductivity in Gold‐Doped Silicon. Journal of Applie…

Semiconductor materials and devicesSilicon and Solar Cell TechnologiesElectron and X-Ray Spectroscopy Techniques

The Martensitic Transformation in Cobalt

R. T. Johnson、R. D. Dragsdorf1967-02-01Journal of Applied Physics

The properties of the fcc to hcp transformation in cobalt single-crystal whiskers have been determined. Studies of the crystallographic properties and dislocation structure using optical, standard x-ray diffraction, and high-resolution x-ray diffraction topographic techniques are herein reported. It is shown that the…

Microstructure and mechanical propertiesTitanium Alloys Microstructure and PropertiesAdvanced materials and composites

Mean-square atomic displacements in zinc

T. H. K. Barron、R. W. Munn1967-02-01Acta Crystallographica

The mean-square atomic displacements (u~,) and (u~ z ) are calculated in the range 0-600K from thermodynamic and inelastic neutron-scattering data. Thermodynamic data alone give (2u~ + z u~), which is separated into its components 2(u~) and (u~) with the aid of the lattice-dynamical model of DeWames, Wolfram & Lehman…

Electrostatics and Colloid InteractionsX-ray Diffraction in CrystallographyThermodynamic and Structural Properties of Metals and Alloys

Elasticity and Anelasticity of Uranium Oxides at Room Temperature: I, Stoichiometric Oxide

ROBERTO J. FORLANO、A. W. Allen、R. J. BEALS1967-02-01Journal of the American Ceramic Society

The elastic modulus and internal friction of stoichiometric uranium oxide at room temperature were studied using a dynamic method. The elastic modulus of stoichiometric urania at room temperature increases with increasing density. When the volume fraction porosity is less than 0.1, either linear or exponential equatio…

Radioactive element chemistry and processingNuclear Materials and PropertiesNuclear materials and radiation effects