Materials Literature
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The in-plane thermoelectric power () of single-crystal graphite in the presence of a magnetic field applied parallel to the c direction was measured at temperatures (T) from 4.2°K up to 300°K. With an increase of the field intensity (H), the sharp negative dip of the versus T diagram previously found to be (0) = −…
The electric strength of polythene has been measured using impulse voltages of differing rise times. The mean value of electric strength increases from 5·6 MV cm −1 for a voltage rise time of 60 μs to 6·6 mV cm −1 when the voltage rise time is 80 μs. The dc strength is 6·4 mV cm −1 . The change in electric strength co…
Laboratory tests were conducted to determine the degradation of dc line and station insulation strength by icing. Curves are presented which relate flashover levels to the degree of icing and the resistivity of the ice, and comparisons are made between the ice test results and fog chamber and wet test data.
Abstract Die Verbindung CaGa 4 O 7 wurde dargestellt und ihre Struktur mit Hilfe von Einkristallen röntgenographisch bestimmt. CaGa 4 O 7 kristallisiert monoklin in der Raumgruppe C C2/c mit den Gitterkonstanten a = 13,06 5 , b = 9,07 9 , c = 5,60 0 Å; β = 105,15°. Ungewöhnlich ist die Sauerstoffkoordination des Calc…
Abstract The photo‐oxidative chain scission of isotactic polystyrene films has been studied as a function of the degree of crystallinity, SO 2 , and NO 2 pressures, and temperature. The rate of chain scission increases in the presence of SO 2 with extent of crystallinity. It is assumed to be faster due to strain in an…
Abstract The rate of adsorption of fractionated polyethylenimine (PEI) from water onto regenerated cellulose fibers was studied as a function of the polymer diffusion coefficient. Differences in polymer molecular weight, salt concentration, and pH were employed to vary the diffusion coefficient which was measured inde…
The thermal diffusivities of dense polycrystalline TiB2, ZrB2, and HfB2 were measured by a laser flash method over the temperature range 200°–1300°C. An investigation of the effects of radial heat flow was performed and a special sample shape was used to comply with the assumption of one-dimensional heat flow. The val…
Abstract A pyrolysis–gas chromatographic technique for measuring the amount of hydrogen chloride released during the high temperature pyrolysis of poly(vinyl chloride) resins, plastisols, copolymers and compounds containing inert fillers has been developed. The technique, which is also applicable to the analysis of ch…
The specific heats of a series of $\ensuremath{\alpha}$-phase Cu-Al and dilute magnetic Cu-Al (Fe) alloys with iron concentrations near 0.07 at.% have been measured over the temperature range 1-14 K. The alloys had aluminum concentrations of 0, 2.5, 5, and 10 at.%. The electronic specific-heat coefficient and the Deby…
The Raman spectra of [ 64 Zn(NH 3 ) 4 ]I 2 and its 68 Zn analog have been measured in the crystalline state. The Zn–N stretching vibrations have been assigned based on the observed metal isotope shifts. These shifts have been compared with theoretical values obtained from a complete normal coordinate analysis on the […
A pilot-scale corona reactor was adapted to process cotton sliver. Corona treatment improved cotton spinnability and increased yarn and fabric strength and abrasion resistance. Treatment effectiveness was greatest at 93-96°C with the injection of dilute chlorine gas into the corona cell. Dyeability was unaltered, cott…
Water dissolves in fused silica to give hydroxyl groups (OH) which give rise to a fundamental absorption band at 3700 cm−1. The reaction of water with silica may be represented formally as ≡Si-O-Si≡ +H2O→2≡Si-OH. Stevenson and Jack found the extinction coefficient of the above band was 77.5±5.1 mole−1 cm−1. Other less…
Six types of polycrystalline MgO, one nominally fully dense and the others having porosities of ∼1 to 2%, were tested in compression up to 1400°C. At 1200°C and above, all materials deformed plastically; two of the materials, both porous, also exhibited plastic flow at temperatures down to 800°C, and a third at 1000°C…
The lattice parameters of the cubic solid solutions from the system (U 1‐∞ Pu ∞ )N were measured at 25°C. The lattice constant, a 0 , of UN was 4.88918±0.00017 Å and that of PuN was 4.90476±0.00008 Å. The parameter of the solid solution does not depend linearly on the composition parameter, x. The X‐ray specimens cont…
Abstract Oxygen partial pressure in equilibrium with nonstoichiometric ceric oxide of a definite composition were determined by equilibration with pure oxygen, air, CO2, and CO2-H2 mixtures at 900, 1000, 1100, 1227, and 1300°C, using a thermobalance. The values for the activities and the relative partial enthalpies an…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRadiation Chemistry of Polymers Studied by Depression of Melting TemperatureR. P. Kusy and D. T. TurnerCite this: Macromolecules 1971, 4, 3, 337–341Publication Date (Print):May 1, 1971Publication History Published online1 May 2002Published inissue 1 May 1971https://pubs.acs.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOrganometellic Polymers. X. Solution Polymerization of 2-Ferrocenylethyl Acrylate and 2-Ferrocenylethyl MethacrylateCharles U. Pittman Jr., Robert L. Voges, and William R. JonesCite this: Macromolecules 1971, 4, 3, 291–297Publication Date (Print):May 1, 1971Publication Histo…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRotary Drum Granulation. An Experimental Study of the Factors Affecting Granule SizeMartin Butensky and Daniel HymanCite this: Ind. Eng. Chem. Fundamen. 1971, 10, 2, 212–219Publication Date (Print):May 1, 1971Publication History Published online1 May 2002Published inissue 1…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInitiation rate for shock-heated hydrogen-oxygen-carbon monoxide-argon mixtures as determined by OH induction time measurementsW. C. Gardiner Jr., M. McFarland, K. Morinaga, T. Takeyama, and Bennie Frank WalkerCite this: J. Phys. Chem. 1971, 75, 10, 1504–1509Publication Date…
L-threonine and L-lysine