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Hydrolytic degradation of poly(L‐lactic acid): Combined effects of UV treatment and crystallization

Hideto Tsuji、Kenta Shimizu、Yoshihiro Sato2012-01-22Journal of Applied Polymer Science

Abstract Amorphous and crystallized poly( L ‐lactic acid) (PLLA) films were prepared and the hydrolytic degradation of the ultraviolet (UV)‐treated and UV‐nontreated films was investigated. This study reveals that the combination of UV and thermal treatments can produce the PLLA materials having different hydrolytic d…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionAdditive Manufacturing and 3D Printing Technologies

Synthesis, film morphology, and performance of cationic fluorinated polyacrylate emulsion with core‐shell structure

Wei Xu、Qiufeng An、Lifen Hao 等 4 位作者2012-01-22Journal of Applied Polymer Science

Abstract A novel cationic fluorinated polyacrylate emulsion (CFBDH) was prepared by polymerization of dodecafluoroheptyl methacrylate (DFMA) with butyl acrylate (BA), dimethylaminoethyl methacrylate (DM), and 2‐hydroxypropyl acrylate (HpA) via seeded emulsion polymerization. Chemical structure, particle morphology, gl…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsSilicone and Siloxane Chemistry

Arabinose content of arabinoxylans contributes to flexibility of acetylated arabinoxylan films

Agnes Stépán、Anders Höije、Henk A. Schols 等 5 位作者2012-01-22Journal of Applied Polymer Science

Abstract Arabinoxylans (AX) from rye were partly debranched by chemical hydrolysis methods, and AXs differing in arabinosyl substitution were acetylated using chemical methods. The resulting materials are film forming, and these films underwent molecular structural analysis and were tested for their material propertie…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesLignin and Wood Chemistry

Polyethylene glycol-stabilized sulphur nanoparticles: an effective antimicrobial agent against multidrug-resistant bacteria

Samrat Roy Choudhury、Subhasree Roy、Arunava Goswami 等 4 位作者2012-01-22Journal of Antimicrobial Chemotherapy

OBJECTIVES: To elucidate the antibacterial efficacy of chemically synthesized and custom-made sulphur nanoparticles (SNPs) of two different sizes and surface modifications against a number of multidrug-resistant Gram-negative bacilli (GNB) harbouring the New Delhi metallo-β-lactamase 1 enzyme (NDM-1). METHODS: Antimic…

Enzyme function and inhibitionNitrogen and Sulfur Effects on BrassicaStructural mechanics and materials

Welding of Gold Nanoparticles on Graphitic Templates for Chemical Sensing

Mengning Ding、Dan C. Sorescu、Gregg P. Kotchey 等 4 位作者2012-01-22Journal of the American Chemical Society

Controlled self-assembly of zero-dimensional gold nanoparticles and construction of complex gold nanostructures from these building blocks could significantly extend their applications in many fields. Carbon nanotubes are one of the most promising inorganic templates for this strategy because of their unique physical,…

Carbon Nanotubes in CompositesGraphene research and applicationsGraphene and Nanomaterials Applications

Utilization of peanut shell powder as a novel filler in natural rubber

C. Sareena、M. T. Ramesan、E. Purushothaman2012-01-22Journal of Applied Polymer Science

Abstract This work focuses on the use of peanut shell powder (PSP) as filler in natural rubber (NR). Peanut, one of the food crops in the world, generates large amounts of waste namely peanut shell. Modified and unmodified PSP‐NR composites with varying particle size and dosages were prepared by an open mill mixing te…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Highly aligned electrospun nanofibers by elimination of the whipping motion

П. А. Киселев、Joan Rosell-Llompart2012-01-22Journal of Applied Polymer Science

Abstract This work shows how elimination of the whipping motion of electrospinning fibers leads to nearly perfect alignment of fibers collected onto fast‐rotating cylindrical collectors. The whipping motion is eliminated by using lower and more uniform electrical fields than are typically used in electrospinning pract…

Advanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical ApplicationsElectrohydrodynamics and Fluid Dynamics

First principles studies of a Xe atom adsorbed on Nb(110) surface

S. Dag、M. Shaughnessy、C. Y. Fong 等 5 位作者2012-01-22arXiv

We study adsorption sites of a single Xe adatom on Nb(110) surface using a density functional theory approach: The on-top site is the most favorable position for the adsorption. We compare the binding features of the present study to earlier studies of a Xe adatom on close-packed (111) surface of face-centered cubic m…

Mesoscale and Nanoscale PhysicsMaterials Sciencecond-mat.other

Synthesis of Silver Nanoparticles from Sargassum Tenerrimum and Screening Phytochemicals for Its Antibacterial Activity

P. Senthil Kumar、Subramani Selvi、A. Lakshmi Prabha 等 6 位作者2012-01-22Nano Biomedicine and Engineering

Synthesis of nanomaterials by biological approach is innovative, cheaper and environmental friendly and requires less-labor. In this regard, the present study focused on the synthesis of silver nanoparticles from the extract of Sargassum tenerrimum. Synthesized silver nanoparticles were wellcharacterized by UV-Visible…

Nanoparticles: synthesis and applicationsMoringa oleifera research and applicationsMarine and Coastal Ecosystems

Performance projection of graphene nanomesh and nanoroad transistors

Gyungseon Seol、Bala Kumar、Jing Guo2012-01-21Nano Research

We examine the performance limits of field-effect transistors (FETs) with chemically modified graphene as the channel materials. Graphene nanoroad (XNR) and graphene nanomesh (XNM) can be created through selective chemical modification by an X adsorbate (either H or F) on graphene, which generates a bandgap while cons…

Graphene research and applications2D Materials and ApplicationsQuantum and electron transport phenomena

Biosorption of lead(II) on modified barks explained by the hard and soft acids and bases (HSAB) theory

Cédric Astier、Vincent Chaleix、Céline Faugeron 等 6 位作者2012-01-21BioResources

Chemical modification of Douglas fir bark and its subsequent utilization in adsorption of Pb(II) from aqueous solutions was investigated. The polysaccharidic moiety of barks was functionalized by periodate oxidation and derivatized after reductive amination in the presence of aminated oligo-carrageenans. Pb(II) adsorp…

Polymer Surface Interaction Studies

Electrical Anharmonicity and Vibronic Couplings Contributions to Optical Nonlinearity of N-Benzyl-2-methyl-4-nitroaniline Crystal Studied by FT-IR, Polarized FT-NIR, Resonance Raman and UV–Vis Spectroscopy

Katarzyna Piela、Mariusz Szóstak2012-01-21The Journal of Physical Chemistry A

FT-IR and Raman spectra of the orthorhombic and monoclinic N-benzyl-2-methyl-4-nitroaniline (BNA) single crystals, powders, and BNA solutions were measured in the 15-4000 cm(-1) range, and complete assignments of bands to normal vibrations are proposed. The assignments have been reinforced by density functional theory…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchStructural and Chemical Analysis of Organic and Inorganic Compounds

Iridescence of a Marine Bacterium and Classification of Prokaryotic Structural Colors

Betty Kientz、Peter Vukusic、Stephen Luke 等 4 位作者2012-01-21Applied and Environmental Microbiology

Iridescence is a property of structural color that is occasionally encountered in higher eukaryotes but that has been poorly documented in the prokaryotic kingdom. In the present work, we describe a marine bacterium, identified as Cellulophaga lytica, isolated from the surface of an anemone, that exhibits bright green…

Microbial Community Ecology and PhysiologyDiatoms and Algae ResearchMicrobial Metabolism and Applications

Structural and electrical properties of Sr(Ti, Fe)O3-δ materials for SOFC cathodes

Sebastian Molin、Weronika Lewandowska-Iwaniak、B. Kusz 等 5 位作者2012-01-21Journal of Electroceramics

Doped strontium titanates are very versatile materials. Iron doped SrTiO 3 can be used, for example, as a material for resistive gas sensors and fuel cell electrodes. In this paper, two compositions based on Fe doped SrTiO 3 were studied as possible candidates for cathode application in SOFCs. Namely, SrTi 0.65 Fe 0.3…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Enhancing intracellular taxane delivery: current role and perspectives of nanoparticle albumin-bound paclitaxel in the treatment of advanced breast cancer

Valentina Guarneri、Maria Vittoria Dieci、PierFranco Conte2012-01-21Expert Opinion on Pharmacotherapy

INTRODUCTION: Docetaxel and paclitaxel are among the most active agents for the treatment of breast cancer. These first-generation taxanes are extremely hydrophobic; therefore, solvents are needed for its parenteral administration. Albumin nanoparticle technology allows for the transportation of such hydrophobic drugs…

Nanoparticle-Based Drug DeliveryCancer Treatment and PharmacologyPlant-Derived Bioactive Compounds

Three-Dimensional Orientation Sensors by Defocused Imaging of Gold Nanorods through an Ordinary Wide-Field Microscope

Tao Li、Qiang Li、Yi Xu 等 9 位作者2012-01-21ACS Nano

Gold (Au) nanoparticles, particularly nanorods, are actively employed as imaging probes because of their special nonblinking and nonbleaching absorption, scattering, and emitting properties that arise from the excitation of surface plasmons. Herein, we report a novel sensing method that detects feature orientation at…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Comment on "Charge-parity symmetry observed through Friedel oscillations in chiral charge-density waves" by J. Ishioka et al

Jasper van Wezel2012-01-21arXiv

In their publication [Phys. Rev B, 84, 245125 (2011)], Ishioka et al. discuss the recently discovered chiral charge density wave state in 1T-TiSe2 in terms of a parameter H_CDW, whose sign is suggested to correspond to the handedness of the chiral order. Here we point out that H_CDW, as defined by Ishioka et al., cann…

Materials ScienceStrongly Correlated Electrons

Monte Carlo simulation of defects in hard-sphere crystal grown on a square pattern

Atsushi Mori、Yoshihisa Suzuki、Shigeki Matsuo2012-01-21arXiv

Monte Carlo simulations of hard-sphere (HS) crystal grown on a square patterned wall under gravity have been performed. While previous simulations were performed with step-wise controlled gravity, in the present simulations constant gravity has been applied from the first. In the case in which a flat wall is used as t…

Materials ScienceSoft Condensed Matter

Polarization of graphene in a strong magnetic field beyond the Dirac cone approximation

Shengjun Yuan、Rafael Roldán、Mikhail I. Katsnelson2012-01-21arXiv

In this paper we study the excitation spectrum of graphene in a strong magnetic field, beyond the Dirac cone approximation. The dynamical polarizability is obtained using a full $π$-band tight-binding model where the effect of the magnetic field is accounted for by means of the Peierls substitution. The effect of elec…

Mesoscale and Nanoscale PhysicsMaterials Sciencephysics.comp-ph

2D transport and screening in topological insulator surface states

S. Adam、E. H. Hwang、S. Das Sarma2012-01-21arXiv

We study disorder effects on the surface states of the topological insulator Bi$_2$Se$_3$ close to the topologically protected crossing point. Close to charge neutrality, local fluctuations in carrier density arising from the random charged disorder in the environment result in electron and hole puddles that dominate…

Mesoscale and Nanoscale PhysicsMaterials Science