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Electron Irradiation and Recovery of Tungsten

H. H. Neely、D.W. Keefer、A. Sosin1968-01-01physica status solidi (b)

Abstract Damage rates and recovery of 99.99% pure tungsten have been investigated after electron irradiation near 4 ° K by means of electrical resistivity. The damage rate data tend to a value of T 0 = 38 to 42 eV. The recovery of the residual electrical resistivity shows three major stages: Stage I from 4.2 to 100 °…

Fusion materials and technologiesNuclear Materials and PropertiesAdvanced Materials Characterization Techniques

Mechanism of Ultraviolet Stabilization of Polymers

M. Heskins、J. E. Guillet1968-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMechanism of Ultraviolet Stabilization of PolymersM. Heskins and J. E. GuilletCite this: Macromolecules 1968, 1, 1, 97–98Publication Date (Print):January 1, 1968Publication History Published online1 May 2002Published inissue 1 January 1968https://doi.org/10.1021/ma60001a018R…

Surface Modification and SuperhydrophobicityPolymer crystallization and propertiesPolymer Science and PVC

Preparation and Luminescence of Selected Eu3+-Activated Rare Earth-Oxygen-Sulfur Compounds

James Haynes、Jesse J. Brown1968-01-01Journal of The Electrochemical Society

The hydrated sulfate, sulfate, oxysulfate, and oxysulfide compounds of yttrium, lanthanum, gadolinium, and lutetium were prepared using precipitation techniques and controlled atmosphere high temperature heat treatments. The temperature stability range in air for each compound was investigated by DTA and TGA methods.…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesSolid-state spectroscopy and crystallography

Phosphors Based on Rare Earth Phosphates

R.C. Ropp1968-01-01Journal of The Electrochemical Society

Spectral properties of rare earth phosphate phosphors are presented and compared to rare earth oxide phosphors studied previously. It is shown that hanging to a phosphate host does not affect the wavelengths produced, but has a major effect on the total energy efficiency as well as the intensity of the emission lines…

Luminescence Properties of Advanced MaterialsPhotorefractive and Nonlinear OpticsRadiation Detection and Scintillator Technologies

Viscosity and Its Temperature Dependence in Molten BeF2

Cornelius T. Moynihan、S. Cantor1968-01-01The Journal of Chemical Physics

The viscosity of molten beryllium fluoride has been measured with coaxial-cylinder viscometers over five orders of magnitude (limits: 979°C, 28.6 P; 574°C, 2.24 × 106 P). Over the experimental range of shear stresses, BeF2 behaves as a Newtonian fluid. Like SiO2, its high-temperature analog, BeF2 shows an Arrhenius te…

Material Dynamics and PropertiesGlass properties and applicationsInorganic Fluorides and Related Compounds

Melting Relationships in the System $$NaAlSi_{3}O_{8}-NaF-H_{2}O$$ to 4 Kilobars Pressure

A. F. Koster van Groos、Peter J. Wyllie1968-01-01The Journal of Geology

The phase relationships in the systems $$NaF-H_{2}O$$ and $$NaAlSi_{3}O_{8}-NaF-H_{2}O$$ were determined between 600° and 900° C. at pressures up to 4 kb., and those in the anhydrous system $$NaAlSi_{3}O_{8}-NaF$$ were determined at 1 atm. The phases encountered were albite, villiaumite (NaF), liquid, and vapor. The l…

Geological and Geochemical AnalysisGlass properties and applicationsCO2 Sequestration and Geologic Interactions

Electron Spin Resonance Spectra of Gamma-Ray-Irradiated Phosphate Glasses and Compounds: Oxygen Vacancies

R. A. Weeks、P. J. Bray1968-01-01The Journal of Chemical Physics

The electron spin resonance spectra of γ-ray-irradiated glassy and polycrystalline phosphorus pentoxide and alkali phosphates with molar ratios of phosphorus pentoxide to alkali oxide ranging from 3.33 to 0.625 have been observed at 10 and 35 Gcps and at 300° and 78°K. Well-resolved hyperfine doublets were observed in…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid-state spectroscopy and crystallography

The crystal structure of alamosite, PbSiO31

M. L. Boucher、Donald R. Peacor1968-01-01Zeitschrift für Kristallographie

Alamosite, PbSiO 3 , has space group P 2/ n with cell parameters for the reduced cell a = 11.23 Å, b = 7.08 Å, c = 12.26 Å, and β = 113° 15′, with Z = 12. The structure has been determined using three-dimensional counterdiffractometer data. Refinement converged with R = 11.1%, including a number of reflections omitted…

Crystal Structures and PropertiesClay minerals and soil interactionsX-ray Diffraction in Crystallography

Five coordination in 3d metal complexes

Luigi Sacconi1968-01-01Pure and Applied Chemistry

Abstract

Metal complexes synthesis and propertiesMagnetism in coordination complexesOrganometallic Compounds Synthesis and Characterization

Mechanism of Branching and Kinking during VLS Crystal Growth

Ricarda Wagner、C. J. Ooherty1968-01-01Journal of The Electrochemical Society

The morphology of the solid‐liquid interface and the contact angle configuration of the liquid alloy droplet determine the direction of growth of crystals prepared by the vapor‐liquid‐solid (VLS) technique. There are four different processes by which both growth kinks and branches can be formed. A change in solid‐liqu…

Solidification and crystal growth phenomenananoparticles nucleation surface interactions

Effect of temperature on the dielectric relaxation in polycrystalline ferrites

F. Haberey、H. P. J. Wijn1968-01-01physica status solidi (b)

Abstract The dielectric constant and the conductivity of polycrystalline ferrites are measured at temperatures between 100 and 400°K and at various frequencies. Different activation energies are obtained for the d.c. and the h.f. conductivity of the samples. Both positive and negative temperature coefficients of the c…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materials

Ultra-violet absorption spectrum of isocyanic acid

R. N. Dixon、G. H. Kirby1968-01-01Transactions of the Faraday Society

The absorption spectrum of HNCO between 2000 and 2800 Å has been photographed with high resolution and absorption paths of up to 8 m atm. None of the bands are completely sharp, but many show coarse rotational structure. Long progressions of bands are assigned to excitation of an NCO bending vibration. The rotational…

Porphyrin and Phthalocyanine ChemistryAnalytical Chemistry and SensorsCatalysis and Oxidation Reactions

Formation of and interrelation between some .mu.-peroxo binuclear cobalt complexes. II.

Masayasu Mori、John A. Weil、Mibuo Ishiguro1968-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFormation of and interrelation between some .mu.-peroxo binuclear cobalt complexes. II.Masayasu Mori, John A. Weil, and Mibuo IshiguroCite this: J. Am. Chem. Soc. 1968, 90, 3, 615–621Publication Date (Print):January 1, 1968Publication History Published online1 May 2002Publis…

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and Applications

Size and Shape of Montmorillonite Particles Saturated with Na/Ca Ions (Inferred from Viscosity and Optical Measurements)

I. Shainberg、H. Otoh1968-01-01Israel Journal of Chemistry

Abstract The viscosity and light transmittance of montmorillonite suspensions saturated with Na + , Ca ++ and known mixtures of these ions in the adsorbed phase were investigated. Introduction of a small fraction of Na + (10% – 15%) into the exchange complex of Ca—clay, does not result in the breakdown of the tactoids…

Polymer Nanocomposites and PropertiesSoil and Unsaturated FlowClay minerals and soil interactions

Chemistry of soil minerals. Part V. Low temperature hydrothermal transformations of kaolinite

R. M. Barrer、J. F. Cole、H. Sticher1968-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

Raw kaolinite has been investigated as a possible starting material for low-temperature hydrothermal growth of zeolites and felspathoids. It proved to be convenient and versatile in this role, being readily transformed into a range of known and new zeolites and salt-inclusion felspathoids with a Si/Al ratio around 1·0…

Concrete and Cement Materials ResearchZeolite Catalysis and SynthesisClay minerals and soil interactions

Optical Absorption by Polarons in Rutile (TiO2) Single Crystals

V. N. Bogomolov、D. N. Mirlin1968-01-01physica status solidi (b)

Abstract The optical absorption in rutile single crystals doped with Nb and other impurities as well as partially reduced is investigated in the temperature range 10 to 900°K. It is shown that the spectrum and the magnitude of the optical absorption by current carriers can be satisfactorily explained in terms of the s…

Glass properties and applicationsMultiferroics and related materialsCrystal Structures and Properties

The electronic properties and stereochemistry of the copper(II) ion. Part III. Some penta-ammine complexes

Anthony A. G. Tomlinson、B. J. Hathaway1968-01-01Journal of the Chemical Society A Inorganic Physical Theoretical

The electronic, e.s.r., and i.r. spectra, and some magnetic moments of a number of stable penta-ammine complexes of the copper(II) ion are reported. The spectra are shown to be consistent with a square-based pyramidal configuration for the Cu(NH3)52+ cation, but not consistent with a trigonal bipyramidal configuration…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Particle Size and Optical Properties of Montmorillonite in Suspension

A. Banin、N. Lahav1968-01-01Israel Journal of Chemistry

Abstract The light absorption spectra of monoionic montmorillonite suspensions with Li, Na, K, Rb, NH 4 , Cs, Mg, Ca and Ba as adsorbed ions were studied in the wavelength range 200–800 mμ. Theoretical analysis of the spectra showed that in the visible range, only scattering is responsible for light intensity attenuat…

Photochemistry and Electron Transfer StudiesClay minerals and soil interactionsIron oxide chemistry and applications

Electrical properties of linear polyacetylene

D. J. Berets、Derek Smith1968-01-01Transactions of the Faraday Society

Linear polymer of acetylene was prepared in which the oxygen content was as low as 0.7 %. The electrical conductivity and Seebeck voltage but not the energy gap depended on the extent of oxidation of the samples. Adsorbed donor and acceptor gases affected electrical conductivity but not e.s.r. spin assay. It was concl…

Organic Electronics and PhotovoltaicsFuel Cells and Related MaterialsConducting polymers and applications