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A Chemical Diffusion‐Controlled Electrode Reaction at the Compact La1 − x Sr x MnO3/Stabilized Zirconia Interface in Oxygen Atmospheres

Junichiro Mizusaki、Takatoshi Saito、Hiroaki Tagawa1996-10-01Journal of The Electrochemical Society

In order to elucidate how the oxide‐ion electron mixed conduction in an oxide cathode affects the kinetics of the cathode reaction in solid oxide fuel cells, a compact layer was prepared as a working electrode on the electrolyte of 3 mole percent doped by a laser flash evaporation method, and electrochemical measureme…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides

Effects of pressure on order-disorder reactions

Robert M. Hazen、Alexandra Navrotsky1996-10-01American Mineralogist

Other| October 01, 1996 Effects of pressure on order-disorder reactions Robert M. Hazen; Robert M. Hazen Carnegie Institution of Washington, Geophysical Laboratory and Center for High Pressure Research, Washington, DC, United States Search for other works by this author on: GSW Google Scholar Alexandra Navrotsky Alexa…

High-pressure geophysics and materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Pyrochlore from Weathered Carbonatite at Lueshe, Zaire

Frances Wall、C. T. Williams、A. R. Woolley 等 4 位作者1996-10-01Mineralogical Magazine

Abstract A detailed study of weathered pyrochlore in the laterite above carbonatite at Lueshe, NE Zaire, has been made in order to determine its chemical and textural variations. Pyrochlore in fresh carbonatite at Lueshe is close to an ideal formula of (Ca,Na) 2 Nb 2 O 6 (OH,F) (where a general formula is A 2−x B 2 O…

Geological and Geochemical AnalysisRadioactive element chemistry and processingNuclear materials and radiation effects

Stress Analysis of Contact Deformation in Quasi‐Plastic Ceramics

Anthony C. Fischer‐Cripps、Brian R. Lawn1996-10-01Journal of the American Ceramic Society

A stress analysis is made of Hertzian contact deformation in relatively tough ceramics with heterogeneous microstructures, where the response is essentially quasi‐plastic rather than ideally elastic‐brittle. Contact data for two such heterogeneous ceramics, a micaceous glass‐ceramic with modest hardness and a silicon…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Finite deformations and the dynamic measurement of radial strains in compression Kolsky bar experiments

K.T. Ramesh、S Narasimhan1996-10-01International Journal of Solids and Structures

A novel technique has been developed for the direct non-contact measurement of the radial deformations of a specimen during a compression Kolsky bar (split-Hopkinson pressure bar) experiment. Application of the new technique makes possible an analysis of the compression Kolsky bar experiment in terms of finite deforma…

High-pressure geophysics and materialsEnergetic Materials and CombustionHigh-Velocity Impact and Material Behavior

Pressure generation and measurement in the rapid vaporization of water on a pulsed-laser-heated surface

Hee K. Park、Dongsik Kim、Costas P. Grigoropoulos 等 4 位作者1996-10-01Journal of Applied Physics

The transient pressure generated by the interaction of short-pulsed laser light with the liquid–solid interface is studied quantitatively. A KrF excimer laser beam of tens of nanoseconds pulse duration irradiates water on a solid surface and induces rapid thermal expansion and explosive vaporization. The pressure puls…

Laser Material Processing TechniquesUltrasound and Cavitation PhenomenaNuclear Physics and Applications

Grafted polymer brushes in polymeric matrices

Gary S. Grest1996-10-01The Journal of Chemical Physics

A molecular dynamics simulation of polymeric brushes immersed in a melt of mobile polymer chains is presented. The brush height and monomer density profiles are presented for chains of length N grafted at one end to a solid surface immersed in a melt of polymers of the same type. As the chain length P of the free chai…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesForce Microscopy Techniques and Applications

Light modulation with resonant grating–waveguide structures

A. Sharon、H.G. Weber、Herbert Engel 等 6 位作者1996-10-01Optics Letters

Resonant grating-waveguide structures formed with InP/InGaAsP semiconductor materials were tested to show light modulation at a wavelength of 1.55 microm. Narrow, subnanometer resonant spectral bandwidths and a ratio of ref lected intensities between resonance and away from resonance of greater than 50 were measured.…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Transcriptional regulation of the Rhodococcus rhodochrous J1 nitA gene encoding a nitrilase.

Hidetsugu Komeda、Yumiko Hori、Maki Kobayashi 等 4 位作者1996-10-01Proceedings of the National Academy of Sciences

The 1.4-kb downstream region from a nitrilase gene (nitA) of an actinomycete Rhodococcus rhodochrous J1, which is industrially in use, was found to be required for the isovaleronitrile-dependent induction of nitrilase synthesis in experiments using a Rhodococcus-Escherichia coli shuttle vector pK4 in a Rhodococcus str…

Enzyme Catalysis and ImmobilizationEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Diatoms as indicators of river quality in the Nepalese Middle Hills with consideration of the effects of habitat‐specific sampling

Ingrid Jüttner、H. Rothfritz、S. J. Ormerod1996-10-01Freshwater Biology

1. Using a replicated survey design at the catchment scale, we compared the composition and diversity of diatom communities in three stream groups in the Middle Hills of Nepal: semi‐natural reference (Arun Valley), enriched by agricultural runoff (Likhu Khola) and grossly polluted by sewage (Kathmandu Valley). We samp…

Freshwater macroinvertebrate diversity and ecologyDiatoms and Algae ResearchAquatic Invertebrate Ecology and Behavior

Nanoindentation investigation of the Young’s modulus of porous silicon

Daniel Bellet、P. Lamagnère、A. Vincent 等 4 位作者1996-10-01Journal of Applied Physics

Young’s modulus of porous silicon samples, with porosity ranging from 36% to 90%, is measured by the nanoindentation technique. The analysis of the nanoindentation data, including the specific problem linked with porous materials, is presented. The Young’s modulus values Ep thus obtained appear to be drastically depen…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Optical Switching of Y‐Hydride Thin Film Electrodes: A Remarkable Electrochromic Phenomenon

P. H. L. Molten、M. Kremers、R. Griessen1996-10-01Journal of The Electrochemical Society

The optical appearance of yttrium thin film electrodes can be electrochemically switched from mirrorlike to highly transparent by making use of the hydride‐forming properties of Y. A strong alkaline solution is a suitable electrolytic environment for obtaining stable electrochromic electrodes. The presence of a thin P…

Perovskite Materials and ApplicationsTransition Metal Oxide NanomaterialsOxidative Organic Chemistry Reactions

Conservative modeling of 3-D electromagnetic fields, Part I: Properties and error analysis

J. Torquil Smith1996-10-01Geophysics

Abstract Conservation of electric current and magnetic flux can be explicitly enforced by modeling Maxwell's equations on a staggered grid, where the different field components are sampled at points offset relative to each other. A staggered finite-difference (SFD) approximation gives divergence-free magnetic fields a…

Magnetic Properties and ApplicationsElectromagnetic Simulation and Numerical MethodsMagnetic Field Sensors Techniques

Formation of Organogels by Intermolecular Hydrogen Bonding between Ureylene Segment

Kenji Hanabusa、Kouji Shimura、Kazunori Hirose 等 5 位作者1996-10-01Chemistry Letters

Abstract Low-molecular weight compounds having ureylene segment was able to cause physical gelation in organic solvents. The main driving force for gelation was intermolecular hydrogen bonding between ureylene units.

Crystallography and molecular interactionsNonlinear Optical Materials ResearchSupramolecular Self-Assembly in Materials

Proton‐Controlled Switching of Luminescence in Lanthanide Complexes in Aqueous Solution: pH Sensors Based on Long‐Lived Emission

A. Prasanna de Silva、H. Q. Nimal Gunaratne、Terence E. Rice1996-10-01Angewandte Chemie International Edition in English

The green luminescence of the terbium complex 1 is increased by a factor of 16 when the amino groups in the side chains are protonated. Because its luminescence has a lifetime of 0.62 ms, this complex can serve as an effective pH sensor in intrinsically fluorescent environments.

Molecular Sensors and Ion DetectionMagnetism in coordination complexesLanthanide and Transition Metal Complexes

VIDEO MICROSCOPY OF MONODISPERSE COLLOIDAL SYSTEMS

Cherry A. Murray、David G. Grier1996-10-01Annual Review of Physical Chemistry

▪ Abstract Colloidal suspensions of uniformly sized microspheres can serve as powerful model systems for investigating many-body processes in condensed-matter physics. The ensemble of microspheres in such suspensions undergoes disorder-order transitions from fluids to crystals in direct analogy with the structural tra…

Material Dynamics and PropertiesPickering emulsions and particle stabilizationElectrostatics and Colloid Interactions

Initiation and Formation of Porous GaAs

Patrik Schmuki、J. Fraser、Carissima M. Vitus 等 5 位作者1996-10-01Journal of The Electrochemical Society

The present work deals with localized dissolution processes (pit and pore initiation and growth) of p‐ and n‐type (100) GaAs. Pit and pore growth can be electrochemically initiated on both conduction types in chloride‐containing solutions and leads after extended periods of time to the formation of a porous GaAs struc…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceAnodic Oxide Films and Nanostructures

Nucleation and growth during recrystallisation of aluminium alloys investigated by local texture analysis

Olaf Engler1996-10-01Materials Science and Technology

This paper presents a systematic survey on the formation of recrystallisation textures in cold rolled Al alloys. In particular, the nucleation of new grains in cube bands, grain boundaries, shear bands, and the deformation zones around large pProceedings of Conference 'Texture on a Mircoscale' as well as their subsequ…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesMetallurgy and Material Forming

Semiconductor nanotube formation by a two‐step template process

Patrick Hoyer1996-10-01Advanced Materials

Multistep template synthesis offers an easy and general route to complicated nanostructures. A two‐step replication procedure is described that can be used to prepare nanotubes of titanium dioxide (see Figure) or other semiconducting materials. The requirements placed on the starting material, the synthesis route, and…

Quantum Dots Synthesis And PropertiesNanowire Synthesis and ApplicationsAnodic Oxide Films and Nanostructures

Rapid switching solid state electrochromic devices based on complementary conducting polymer films

Shawn A. Sapp、Gregory A. Sotzing、Jerry L. Reddinger 等 4 位作者1996-10-01Advanced Materials

New electrochromic materials (ECMs) must exhibit rapid response times, long‐term stability, and a large difference in percentage transmittance between the bleached and colored states. The design, fabrication, and characterization of fast, solid‐state, dual conducting polymer EC devices that utilize PEDOT (see Figure)…

Conducting polymers and applicationsTransition Metal Oxide NanomaterialsAnalytical Chemistry and Sensors