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Synthesis of Platinum Cluster Chains on DNA Templates: Conditions for a Template-Controlled Cluster Growth

Ralf Seidel、Lucio Colombi Ciacchi、Michael Weigel 等 5 位作者2004-06-25The Journal of Physical Chemistry B

We investigate the conditions which should be fulfilled to grow chains of nanosized noble metal clusters on DNA templates according to a selectively heterogeneous, template-controlled mechanism. A long incubation of double-stranded DNA molecules with Pt(II) complexes is necessary to obtain a template-directed formatio…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

Homogeneous Crystallization of Poly(Ethylene Oxide) Confined to Droplets: The Dependence of the Crystal Nucleation Rate on Length Scale and Temperature

Michael V. Massa、Kari Dalnoki‐Veress2004-06-25Physical Review Letters

We present a study of homogeneous nucleation in polymer crystallization. Crystal nucleation is observed within discrete droplets of poly(ethylene oxide) that are formed by the dewetting of a thin film. The samples provide an ensemble of impurity-free droplets, with length scales that can easily be measured. Droplet cr…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Unidirectional hemp and flax EP‐ and PP‐composites: Influence of defined fiber treatments

Andrzej K. Błędzki、Hans‐Peter Fink、K. Specht2004-06-25Journal of Applied Polymer Science

Abstract In some technical areas, mainly in the automotive industry, glass fiber reinforced polymers are intended to be replaced by natural fiber reinforced polymer systems. Therefore, higher requirements will be imposed to the physical fiber properties, fiber‐matrix adhesion, and the quality assurance. To improve the…

Natural Fiber Reinforced CompositesElectromagnetic wave absorption materialsTribology and Wear Analysis

Structures and Analysis of Highly Homologous Psychrophilic, Mesophilic, and Thermophilic Adenylate Kinases

Euiyoung Bae、George N. Phillips2004-06-25Journal of Biological Chemistry

The crystal structures of adenylate kinases from the psychrophile Bacillus globisporus and the mesophile Bacillus subtilis have been solved and compared with that from the thermophile Bacillus stearothermophilus. This is the first example we know of where a trio of protein structures has been solved that have the same…

Protein Structure and DynamicsEnzyme Structure and FunctionEnzyme function and inhibition

Electron Transport Through Molecules: Gate Induced Polarization and Potential Shift

San-Huang Ke、Harold U. Baranger、Weitao Yang2004-06-25arXiv

We analyze the effect of a gate on the conductance of molecules by separately evaluating the gate-induced polarization and the potential shift of the molecule relative to the leads. The calculations use ab initio density functional theory combined with a Green function method for electron transport. For a general view…

Mesoscale and Nanoscale PhysicsMaterials Science

Strong electron correlation effects in non-volatile electronic memory devices

Marcelo J. Rozenberg、Isao H. Inoue、Maria Jose Sanchez2004-06-25arXiv

We investigate hysteresis effects in a model for non-volatile memory devices. Two mechanisms are found to produce hysteresis effects qualitatively similar to those often experimentally observed in heterostructures of transition metal oxides. One of them is a novel switching effect based on a metal-insulator transition…

Materials ScienceStrongly Correlated Electrons

Mesoscopic Transport in Chemically Doped Carbon Nanotubes

Sylvain Latil、Stephan Roche、Didier Mayou 等 4 位作者2004-06-25Physical Review Letters

Electronic quantum transport is investigated in boron- and nitrogen-doped carbon nanotubes using tight-binding methods correlated to ab initio calculations. The present technique accurately accounts for both effects of dopants, namely, charge transfer and elastic scattering. Generic transport properties such as conduc…

Carbon Nanotubes in CompositesGraphene research and applicationsSemiconductor materials and interfaces

Block Copolymers under Cylindrical Confinement

Hongqi Xiang、Kyusoon Shin、Taehyung Kim 等 6 位作者2004-06-25Macromolecules

Microphase-separated block copolymers were introduced as melts into nanoscopic cylindrical pores in alumina membranes via capillary action. The geometric confinement of both lamellar and cylindrical microdomain morphologies of styrene/butadiene block copolymers, PS- b -PBD, was investigated by transmission electron mi…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Chemistry of Thiacalixarenes

Pavel Lhoták2004-06-25OpenAlex

Abstract For Abstract see ChemInform Abstract in Full Text.

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesInorganic and Organometallic Chemistry

Scaling of Excitons in Carbon Nanotubes

Vasili Perebeinos、J. Tersoff、Phaedon Avouris2004-06-25arXiv

Light emission from carbon nanotubes is expected to be dominated by excitonic recombination. Here we calculate the properties of excitons in nanotubes embedded in a dielectric, for a wide range of tube radii and dielectric environments. We find that simple scaling relationships give a good description of the binding e…

Carbon Nanotubes in CompositesFullerene Chemistry and ApplicationsMechanical and Optical Resonators

Mechanical properties and structural characteristics of PP/PP‐g‐SBR nanocomposites prepared by dynamical photografting

Weizhi Wang、Mouzheng Fu、Baojun Qu2004-06-24Polymers for Advanced Technologies

Abstract Poly(propylene) (PP)/PP grafted styrene‐butadiene rubber (PP‐g‐SBR) nanocomposite was prepared by blending PP with PP‐g‐SBR using dynamical photografting. The crystal morphological structure, thermal behavior, and mechanical properties of PP/PP‐g‐SBR nanocomposites have been studied by photoacoustic Fourier t…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Hydrothermal Route to InAs Semiconductor Nanocrystals

Jun Lu、Shuo Wei、Weichao Yu 等 5 位作者2004-06-24Inorganic Chemistry

Spherical InAs nanocrystals of 30-50 nm were hydrothermally synthesized at 120 degrees C, which showed a 100 meV-blueshift of band gap absorption and phonon confinement of optical vibration mode. The study of hydrothermal formation mechanism indicated that crystalline InAs could be obtained in an extended pH range (ap…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Dissolution of milled-silicate rock fertilisers in the soil

Joko Priyono、R. J. Gilkes2004-06-24Soil Research

Dissolution of dry-milled basalt, dolerite, gneiss, and K-feldspar added to 23 soils has been related to milling time and soil properties. The rocks milled for 10, 60, and 120 min were mixed with 23 type of soils from south-western Australia at a rock/soil ratio of 1/100 (≈10 t/ha), wetted to 110% field capacity, then…

Soil Carbon and Nitrogen DynamicsSoil and Unsaturated FlowClay minerals and soil interactions

SPEDEN: reconstructing single particles from their diffraction patterns

Stefan P. Hau-Riege、Hanna Szoke、Henry N. Chapman 等 10 位作者2004-06-24Acta Crystallographica Section A Foundations of Crystallography

SPEDEN is a computer program that reconstructs the electron density of single particles from their X-ray diffraction patterns, using a single-particle adaptation of the holographic method in crystallography [Szöke, Szöke & Somoza (1997). Acta Cryst. A53, 291-313]. The method, like its parent, is unique because it does…

Advanced Electron Microscopy Techniques and ApplicationsEnzyme Structure and FunctionCrystallography and Radiation Phenomena

Structure determination ofSi(001)−c(4×2)surfaces at80Kand electron beam effect below40Kstudied by low-energy electron diffraction

Seigi Mizuno、Tetsuroh Shirasawa、Yuichiro Shiraishi 等 4 位作者2004-06-24Physical Review B

We have studied the structures of the $\text{Si}(001)\text{\ensuremath{-}}c(4\ifmmode\times\else\texttimes\fi{}2)$ surfaces using low-energy electron diffraction analysis at $80\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. The asymmetric dimer model was optimized, and obtained structural parameters were almost identical wit…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Monte Carlo simulation of the Compton scattering technique applied to characterize diagnostic x‐ray spectra

S. Gallardo、J. Ródenas、G. Verdú2004-06-24Medical Physics

The quality control of x-ray tubes for medical radiodiagnostic services is very important for such devices. Therefore, the development of new procedures to characterize the x-ray primary beam is highly interesting in order to obtain an accurate assessment of the actual photon spectrum. The Compton scattering technique…

Radiation Dose and ImagingRadiation Shielding Materials AnalysisAdvanced X-ray and CT Imaging

Spin polarization of the transport current at the free surface of bulkNiMnSb

S. K. Clowes、Y. Miyoshi、Y. Bugoslavsky 等 8 位作者2004-06-24Physical Review B

The point contact Andreev reflection employing niobium tips was used to determine the degree of transport current spin polarization $({P}_{t})$ at the free surface of bulk $\text{NiMnSb}$ at $4.2\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. The data was analyzed within the framework of a modified version of the Blonder, Tin…

Quantum and electron transport phenomenaMagnetic and transport properties of perovskites and related materialsHeusler alloys: electronic and magnetic properties

Self-assembled uniaxial and biaxial multilayer structures in chiral smectic liquid crystals frustrated between ferro- and antiferroelectricity

В. П. Панов、N. M. Shtykov、Atsuo Fukuda 等 8 位作者2004-06-24Physical Review E

With a view to obtain a molecular model for the subphases produced by the frustration between ferro- and antiferroelectricity in chiral smectic liquid crystals, we report results on two compounds and observe (i) the staircase character of uniaxial Sm C(*)(alpha) itself in the bulk and (ii) the multipeaked characterist…

Liquid Crystal Research AdvancementsOptical Polarization and EllipsometryMolecular spectroscopy and chirality

Shear-Induced Mesophase Organization of Polyanionic Rigid Rods in Aqueous Solution

Takafumi Funaki、Tatsuo Kaneko、Kanji Yamaoka 等 8 位作者2004-06-24Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVNoteShear-Induced Mesophase Organization of Polyanionic Rigid Rods in Aqueous SolutionTakafumi Funaki, Tatsuo Kaneko, Kanji Yamaoka, Yutaka Ohsedo, Jian Ping Gong, Yoshihito Osada, Yuzo Shibasaki, and Mitsuru UedaView Author Information Division of Biological Sciences, Graduate School…

Liquid Crystal Research AdvancementsPolymer Nanocomposites and PropertiesPolymer composites and self-healing