Materials Literature
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Abstract The effects of molecular weight (MW) and MW distribution on the maximum tensile properties of polyethylene (PE), achieved by the uniaxial drawing of solution‐grown crystal (SGC) mats, were studied. The linear‐PE samples used had wide ranges of weight‐average ( M w = 1.5–65 × 10 5 ) and number‐average MWs ( M…
The development of the ferroelectric polarization of lead–zirconate–titanate (PZT) bulk ceramics under varying electric fields is examined. Repeated partial switching and backswitching results in a decrease of the switchable polarization, but has no effect on the effective strain. This is attributed to a stabilization…
Abstract Acrylic polymer/silica hybrids were prepared by emulsifier‐free emulsion polymerization and the sol–gel process. Acrylic polymer emulsions containing triethoxysilyl groups were synthesized by emulsifier‐free batch emulsion polymerization. The acrylic polymer/silica hybrid films prepared from the acrylic polym…
We observed thermally induced nanomechanical deflection of a hybrid inorganic nanowire (NW) synthesized by pulsed-laser deposition, the structure of which is a carbon nanotube template sandwiched by aluminum oxide and tungsten oxide thin layers. The hybrid NW was gradually bent at a specimen temperature ranging from r…
Microwave absorption (8 GHz to 12 GHz) studies have been made with carbon nanomaterials for the first time. Carbon nanomaterials are synthesized by the pyrolysis of camphor. It is observed that film of carbon prepared under certain synthetic condition, can absorb microwave of either some specific wavelengths e.g., 9.5…
The alkylation of m-cresol with isopropyl alcohol in the presence of novel superacidic catalysts named as UDCaT-4, UDCaT-5, and UDCaT-6 was investigated. The catalysts are modified versions of zirconia showing high catalytic activity, stability, and reusability in the presence of water as compared to conventional sulf…
Light-induced ordering processes were investigated in spin-coated films of a smectic main-chain polyester with mesogenic 4,4‘-dioxyazobenzene groups in the backbone. Spin-coating results in aggregation due to π−π stacking and out-of-plane orientation. Both are destroyed by UV exposure. However, they are rebuilt by sub…
The microwave (mw) plasma torch at atmospheric pressure has been studied for carbon nanotube (CNT) synthesis. The depositions were carried out on silicon substrates with 515 nm thin iron catalytic overlayers from the mixture of argon, hydrogen and methane. The optical emission spectroscopy of the torch showed the pres…
Absorption, fluorescence and decay properties of erbium-doped alkali tellurofluorophosphate glasses (RTFP) with the molar compositions of 50 (NaPO 3 ) 6 –10 TeO 2 –20 AlF 3 –19 RF–1 Er 2 O 3 (R = Li,Na or K) have been investigated in order to utilize these materials for the development of fibre amplifiers and lasers.…
This letter reports the formation of a reacted layer between Cu film and barrierless Si substrate during annealing. The Cu films with a minor WN phase are deposited by reactive cosputtering of Cu and W in an Ar∕N2 mixture gas. After annealing at 530 °C for 1 h, a ∼200-nm-thick reacted layer formed at the Cu(WN)∕Si int…
Powder x-ray diffraction patterns of magnetite (Fe 3 O 4 ) have been recorded at 90 K, below the Verwey transition, at three wavelengths in the pre- to mid-edge region of the 7.1 keV Fe K absorption. Simultaneous fitting of these profiles has been used to refine the anomalous scattering coefficients for the octahedral…
Porous anodic alumina membranes (PAAMs) have uniform and high-density nanopores, and the dimension and interval of the pores can be easily controlled by varying the anodization conditions. The application of PAAMs could widely impact the cost and efficiency of the liquid-based nanoscale separations. We report here the…
Ba(dmae)2 (dmaeH=N,N-dimethylaminoethanol, C4H11NO) reacts with Co(acac)2 (acac=2,4-pentanedionate) to produce the trinuclear coordination complex [Ba2Co(acac)4(dmae)3(dmaeH)] in an 85% yield. Spectroscopic and single-crystal X-ray diffraction experiments indicate that the complex possesses a structure in which two ba…
Abstract The treatment of nanoscopic silica grafted in the blend during the processing of silica‐filled styrene butadiene rubber was performed with silane, introduced at different concentrations, or at a constant concentration with a given length of alkyl chain. From swelling measurements in water and in solvent, the…
[chemical structure: see text]. A series of L-amino acid functionalized gold nanoparticles with oligo(ethylene glycol) (OEG) tethers of varying length are prepared. These studies show that the hydrophobic side chains of amino acids facilitate the structural retention of alpha-chymotrypsin (ChT) but the interior alkyl…
In the perfect magnesium aluminate spinel structure all the tetrahedral sites are occupied by Mg 2+ ions, while Al 3+ ions occupy all the octahedral sites. Real MgAl 2 O 4 , however, exhibits cation disorder (inversion), so that some Mg 2+ ions reside in octahedral sites with an equal number of Al 3+ ions in tetrahedr…
Abstract Polyurethane prepolymers are widely used in the reactive hot melt adhesives and moisture‐cured coatings. The chemically crosslinked moisture‐cured formulation based on PEG‐1000 and isophorone diisocyanate was prepared with NCO/OH ratio of 1.6:1.0. Trimethylol propane was used as a crosslinking agent. The exce…
Theoretical studies using density functional theory are carried out to understand the electronic structure and bonding and electronic properties of elemental $\ensuremath{\beta}$-rhombohedral boron. The calculated band structure of ideal $\ensuremath{\beta}$-rhombohedral boron $({\mathrm{B}}_{105})$ shows valence elec…
Unique inorganic-organic hybrid mesoporous materials incorporating arenetricarbonyl complexes [-C6H4M(CO)3-] (M = Cr, Mo) within their mesoporous frameworks have been successfully prepared by a simple CVD treatment of the phenylene-bridged organosilica mesoporous materials with metal hexacarbonyls [M(CO)6] (M = Cr, Mo…
Nanocomposites based on vinyl alcohol-containing polymers and nanostructured gold have been efficiently prepared by a UV photo-reduction process. The very fast process provided dispersed gold nanoparticles with average diameters ranging from 3 to 20 nm depending on the host polymer matrix and the irradiation time. Uni…