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Reduction of OH-absorption in fluoride glasses

G. Mazé、Vincent Cardin、Marcel Poulain1984-01-01Journal of Lightwave Technology

The thermodynamics of hydrolysis reactions show that hydroxyle groups are not stable in glass melt at high temperature. A refining stage carded out at 1000°C for 1 h results in low-OH-content bulk glasses. Preforms were prepared by this method and drawn into fibers. The maximum absorption of 2.9 μm was 110 dB/km and a…

Advanced Fiber Optic SensorsPhotonic and Optical DevicesGlass properties and applications

Polymeric complexes from molybdenum trioxide, with notes on derivatives and related compounds

Richard Hider、C. J. Wilkins1984-01-01Journal of the Chemical Society Dalton Transactions

Molybdenum trioxide dissolves in dimethyl sulphoxide (dmso) to give a solution from which the polymeric complex [{MoO3(dmso)1.33}n](1a) may be crystallised. It also reacts with pyridine N-oxide (pyo), triphenylarsine oxide, and pyridine (py) to give insoluble polymeric complexes [{MoO3(pyo)}n](2), [{MoO3(AsPh3O)0.5}n]…

Polyoxometalates: Synthesis and ApplicationsOxidative Organic Chemistry ReactionsVanadium and Halogenation Chemistry

Mechanism of formation of the V-shaped segregation in the large section continuous cast bloom.

Hiroshi TOMONO、Yasuo HITOMI、Satoru Ura 等 6 位作者1984-01-01Transactions of the Iron and Steel Institute of Japan

A V-shaped segregation, found in a sulfur print of longitudinal strand section, has been macroscopically investigated. A simple model, using polyethylene particles of 2mm diameter, has been prepared to simulate formation of the V-shaped segregation.The results obtained are summarized as follows:(1) The V-shaped segreg…

Rheology and Fluid Dynamics StudiesTextile materials and evaluationsMaterial Properties and Processing

Textural and structural changes in transition alumina supports

J.P. Franck、E. Freund、Eric Quéméré1984-01-01Journal of the Chemical Society Chemical Communications

A γc alumina carrier is shown to be partly hydrated to bayerite or gibbsite in contact with an ammonia solution, or even water, at room temperature, and to boehmite when heated at 410K and a pressure of 0.3 MPa in water.

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisBauxite Residue and Utilization

Electron Transfer Reactions in Condensed Phases

M. Newton1984-01-01Annual Review of Physical Chemistry

Machine learning (ML) is transforming all areas of science. The complex and time-consuming calculations in molecular simulations are particularly suitable for an ML revolution and have already been profoundly affected by the application of existing ML ...Read More

Electrochemical Analysis and ApplicationsMachine Learning in Materials Science

Nitzschia cylindroformis sp. nov., a common and abundant nanoplankton diatom of the eastern subarctic Pacific

Grethe Rytter Hasle、Beatrice C. Booth1984-01-01Journal of Plankton Research

A new species of diatoms, intermediate between Nitzschia cylindrus (Grun.) Hasle and Nitzschia pseudonana Hasle is described. Differences in morphology of the three species are outlined. The new species has been recorded only between 37°N and 53°N in the Pacific Ocean while N. cylindrus is bipolar and N. pseudonana is…

Marine and coastal ecosystemsMarine Biology and Ecology ResearchDiatoms and Algae Research

Chemistry and development of mesophase in pitch

I.C. Lewis1984-01-01Journal de Chimie Physique

The chemical and physical processes involved in formation of mesophase pitch are described. Carbonaceous mesophase exhibits properties of both nematic liquid crystals and glass-like pitches. Mesophase development requires polymerization of aromatic pitch components to a sufficient molecular size, and a proper concentr…

Liquid Crystal Research Advancements

Adhesion in the Biologic Environment

Robert Baier1984-01-01Biomaterials Medical Devices and Artificial Organs

There are good reasons to believe that adhesion of particulate matter in all wet, salty, biochemically active circumstances follows a common pattern, and that such adhesion can be effectively controlled by adjusting the surface properties - especially surface energy--of the substrate involved. One of the most compelli…

Polymer Surface Interaction StudiesCalcium Carbonate Crystallization and InhibitionAcademic Writing and Publishing

Slow-Strain-Rate Stress Corrosion Testing of Aluminum Alloys

NJH Holrody、GM Scamans1984-01-01OpenAlex

An extensive program of slow-strain-rate stress corrosion testing of aluminum alloys in a wide variety of susceptibility conditions and environments produced results fully consistent with the expected behavior from service experience and the results of other established test methods. Tests were conducted both on labor…

Hydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and CreepNuclear Materials and Properties

The Temperature—Composition Phase Diagram of the GeSe—GeTe System

Heribert Wiedemeier、P. A. Siemers1984-01-01Humana Press eBooks

The temperature-composition phase diagram for the GeSe-GeTe system was determined between 25 and 675°C using high temperature X-ray powder diffraction techniques (1). The orthorhombic phase extends from 100 to 92 ± 3 mol% GeSe and is stable below 651 ± 5°C. For compositions between 86 ± 3 and 58 ± 3 mol% GeSe a hexago…

Nonlinear Optical Materials ResearchPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Preparation and properties of tetrathiafulvalene (ttf) and tetramethyltetraselenafulvalene salts of tin(IV) halide anions and X-ray crystal structure of [ttf]3[SnCl6]

Kensuke Kondo、Gen‐etsu Matsubayashi、Toshio Tanaka 等 5 位作者1984-01-01Journal of the Chemical Society Dalton Transactions

Tetrathiafulvalene (ttf) reacts with SnX4(X = Cl or Br) in MeCN to give [ttf]2[SnX6]. The corresponding tetramethyltetraselenafulvalene (tmtsf) salt also is obtained as an acetonitrile solvate, [tmtsf]2[SnCl6]·MeCN, by the reaction of tmtsf with SnCl4 in MeCN. On the other hand, electrocrystallization of ttf and tmtsf…

Organic and Molecular Conductors ResearchSolid-state spectroscopy and crystallographyOrganometallic Compounds Synthesis and Characterization

Effects of 50,000 h of thermal aging on graphite/epoxy and graphite/polyimide composites

J. Richard Kerr、J. F. Haskins1984-01-01AIAA Journal

Thermal effects on tensile strengths of advanced composite systems have been determined for exposure times of 100 to 50,000 hours (5.7 years). Exposures were conducted at both ambient and reduced pressures at two temperatures for each composite. At the completion of the various aging periods, specimens were removed fr…

Mechanical Behavior of CompositesFiber-reinforced polymer compositesGraphite, nuclear technology, radiation studies

An osmium tetrahydroborate complex with unusual dynamic behaviour: X-ray crystal structure of [Os(BH4)H3{P(c-C5H9)3}2](c-C5H9= cyclo-C5H9)

Peter W. Frost、Judith A. K. Howard、John L. Spencer1984-01-01Journal of the Chemical Society Chemical Communications

In the complex [Os(BH4)H3{P(c-C5H9)3}2](c-C5H9= cyclo-C5H9), prepared quantitatively from the reaction of [OsH6{P(c-C5H9)3}2] with BH3·thf, (thf = tetrahydrofuran), the tetrahydroborate ligand is bound to the metal by two bridging hydrogen atoms which, at 90 °C, exchange rapidly only with the hydride ligands on osmium.

Hydrogen Storage and MaterialsAsymmetric Hydrogenation and CatalysisBoron Compounds in Chemistry

Airflow Resistance of Mixtures of Shelled Corn and Fines

S. N. Grama、Carl J. Bern、Charles R. Hurburgh 等 4 位作者1984-01-01Transactions of the ASAE

ABSTRACT TESTS were carried out to define the effects on airflow resistance of adding various percentages of various sizes of fines to whole corn kernels. The relationship between clean corn multiplier and percentage fines was defined for seven size grades of fines. Effect of fines on fan power requirements for aerati…

Textile materials and evaluationsPlant Surface Properties and Treatments

Organic superconductors

A. I. Buzdin、L. N. Bulaevskiǐ1984-01-01Uspekhi Fizicheskih Nauk

X 537.312.62 . . , . . 1. 415 2. (TMTSF) 2 X (BEDT -TTF)X 416 ) (TMTSFUX 416 ) (BEDT -TTF)X 419 3. 419 ) 419 ) () 423 4. 425 5. 426 6. ( ) 431 7. 433 435 1.

Organic and Molecular Conductors Research

Ba5(GaS4)2: Das erste ortho-Thiogallat(III) / Ba5(GaS4)2: The First ortho-Thiogallate(III)

Β. Eisenmann、M. JAKOWSKI、Herbert Schäfer1984-01-01Zeitschrift für Naturforschung B

The new compound Ba 5 (GaS 4 ) 2 crystallizes in the orthorhombic system (space group: Cmca) with lattice constants a = 2249.4(12) pm, b = 1214.6(8) pm, c = 1188.7(8) pm. In the structure there are isolated GaS 4 5- -tetrahedra. According to stoichiometry and structure this compound belongs to the complex salts, and i…

Crystal Structures and PropertiesOrganometallic Compounds Synthesis and CharacterizationInorganic Chemistry and Materials

Efficient synthesis of 2-oxy-5,10,15,20-tetraphenylporphyrins from a nitroporphyrin by a novel multi-step cine-substitution sequence

Maria M. Catalano、Maxwell J. Crossley、Lionel G. King1984-01-01Journal of the Chemical Society Chemical Communications

(2-Nitro-5,10,15,20-tetraphenylporphyrinato)copper(II)(1) reacts with sodium benzylate or sodium methoxide in dimethylformamide by a novel aromatic nucleophilic substitution-nucleophilic addition sequence in which hydrogen is the leaving group to give the corresponding 2,2-dialkoxy-3-dihydroporphyrins which are effici…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsPorphyrin Metabolism and Disorders

Incipient Phenomena of Frost Formation

N. Seki、Shoichiro FUKUSAKO、Kuniyuki Matsuo 等 4 位作者1984-01-01Bulletin of JSME

Experiments have been performed to investigate the effect of cooled-plate characteristic on frost formation under the condition of forced convection. Two kinds of plates having the different contact angles to water, were utilized. Special attention was focused on the incipient phenomena of the effect of the plate cont…

Surface Modification and SuperhydrophobicityHeat Transfer and Optimization

Thermal cracking of kerosine

Carl E. Camp、P. S. Van Damme、Gilbert F. Froment1984-01-01Industrial & Engineering Chemistry Process Design and Development

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal cracking of kerosineCarl E. Van Camp, Paul S. Van Damme, and Gilbert F. FromentCite this: Ind. Eng. Chem. Process Des. Dev. 1984, 23, 1, 155–162Publication Date (Print):January 1, 1984Publication History Published online1 May 2002Published inissue 1 January 1984https…

Porphyrin and Phthalocyanine ChemistrySurface Chemistry and Catalysis