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Electrocaloric Effects in Some Ferroelectric and Antiferroelectric Pb(Zr, Ti)O3 Compounds

P.D. Thacher1968-03-01Journal of Applied Physics

Variations of sample temperature arising from the electrocaloric effect, antiferroelectric to ferroelectric transitions, and hysteresis-loss heating have been recorded together with the hysteresis loops for four different ceramic ferroelectrics near room temperature. Both the electric-field dependence and the temperat…

Ferroelectric and Piezoelectric MaterialsMaterial Dynamics and PropertiesAcoustic Wave Resonator Technologies

The Degradation of Poly(ethylene terephthalate)

Lothar H. Buxbaum1968-03-01OpenAlex

Abstract The penetration of new markets by polyester fibers has emphasized the need for increased stability of the polyester toward a variety of degradative reactions. Extensive studies of the nature of the thermal, hydrolytic, oxidative, and radiation‐induced degradation reactions have been reported. The interpretati…

Microplastics and Plastic PollutionFiber-reinforced polymer compositesPolymer crystallization and properties

Comparison of kinetic and diffusional models for solid‐gas reactions

Masatoshi Ishida、C. Y. Wen1968-03-01OpenAlex

Abstract A comparison of the kinetic and diffusional models for solid‐gas reactions occurring in a spherical particle is presented. The similarities and differences of the unreacted‐core shrinking model and the homogeneous model are examined in light of the rate‐controlling factors. In view of the similarity of the tw…

Industrial Gas Emission ControlCatalysts for Methane ReformingCatalytic Processes in Materials Science

Raman Spectrum of Strontium Titanate

W. G. Nilsen、J. G. Skinner1968-03-01OpenAlex

The Raman spectrum of single-crystal SrTiO3 has been investigated as a function of temperature down to about 25°K. The lattice dynamics of this crystal have been extensively studied in recent years primarily because of its unusual dielectric and acoustic properties. Both nominally pure and impure samples were examined…

Electronic and Structural Properties of OxidesFerroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear Optics

Molybdovanadophosphoric acids and their salts. I. Investigation of methods of preparation and characterization

George A. Tsigdinos、Calvin J. Hallada1968-03-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolybdovanadophosphoric acids and their salts. I. Investigation of methods of preparation and characterizationGeorge A. Tsigdinos and Calvin J. HalladaCite this: Inorg. Chem. 1968, 7, 3, 437–441Publication Date (Print):March 1, 1968Publication History Published online1 May 2…

Catalysis and Oxidation ReactionsChemical Synthesis and CharacterizationPolyoxometalates: Synthesis and Applications

X-ray scattering factors computed from numerical Hartree–Fock wave functions

D. T. Cromer、J. B. Mann1968-03-01OpenAlex

X-ray scattering factors for neutral atoms from He to Lw and for most of the chemically significant ions through Lu3+ have been computed from numerical Hartree–Fock wave functions. The results are given in the form of coefficients for an analytic function.

Advanced Chemical Physics StudiesX-ray Diffraction in CrystallographyNuclear Physics and Applications

Infrared Spectra of Steroids

Yu. N. Levchuk1968-02-28Russian Chemical Reviews

CONTENTS I. Features of the chemical structure of steroids 155 II. Correlation of the infrared spectra of steroids with their structure 156 III. Use of infrared spectroscopy in steroid chemistry 164

Chemical Thermodynamics and Molecular StructureNonlinear Optical Materials ResearchAnalytical Methods in Pharmaceuticals

The Masking of Reactions

F P Sudakov1968-02-28Russian Chemical Reviews

CONTENTS I. Introduction 142 II. Classification of masking processes 143 III. Methods for calculating the efficiency of masking 144 IV. Masking and the selectivity of reactions 148 V. The most common masking agents 149 VI. Characteristic examples of the practical application of masking 153

Polymer Science and PVCPigment Synthesis and PropertiesMaterial Properties and Applications

Morphometric Variation and Function in the Baculum, with Comments on Correlation of Parts

C. A. Long、Tamara M. Frank1968-02-20Journal of Mammalogy

Probable functions of the baculum are reviewed. Consideration of vectors of resistance of the vaginal orifice and of forces of the baculum reveals possible reasons for the specialization of the bacular tip in some carnivores and rodents. Coefficients of variation of length and some other measurements of some bacula of…

Comparative Animal Anatomy StudiesMorphological variations and asymmetryDiatoms and Algae Research

NMR Studies of Diffusion in Glassy and Crystalline Lithium Borates

S. G. Bishop、P. J. Bray1968-02-15The Journal of Chemical Physics

The 7Li NMR spectra from several lithium borate glasses have been examined as a function of temperature and found to narrow abruptly with increasing temperature in the range of temperatures from 250° to 475°K. The observed narrowing is a manifestation of the phenomenon of motional narrowing, and is attributed to diffu…

Glass properties and applicationsAdvanced NMR Techniques and ApplicationsNMR spectroscopy and applications

Crystal structure of β-Cu2P2O7

B. E. Robertson、C. Calvo1968-02-15Canadian Journal of Chemistry

The crystal structure of β-CU 2 P 2 O 7 has been determined by X-ray methods. The crystals are monoclinic with a = 6.827(8) Å, b = 8.118(10) Å, c = 4.576(6) Å, β = 108.85(10)°, Z = 2, and space group C2/m. This structure is analogous to that of the mineral thortveitite and the high temperature forms of the pyrophospha…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Optical Properties of Alkali-Halide Crystals

Giancarlo Baldini、Bruno Bosacchi1968-02-15Physical Review

Reflectivity data from single crystals of alkali halides have been obtained in the ultraviolet region of the spectrum where excitonic and low interband transitions occur. Following recent calculations for the band structure of KC1 and KI and basing our analysis on the experimental data, it has been possible to predict…

Solid-state spectroscopy and crystallographyAdvanced Chemical Physics StudiesLuminescence Properties of Advanced Materials

Multipacting Discharges between Coaxial Electrodes

Richard Woo1968-02-15Journal of Applied Physics

Experimental evidence is presented to demonstrate the scaling relations of the similarity principle for multipacting as applied to coaxial electrodes with b/a (b and a are the radii of the outer and inner electrodes, respectively) varying between 2.3 and 18.26. The two field configurations considered are: (1) rf volta…

Analytical Chemistry and SensorsPower Transformer Diagnostics and InsulationHigh voltage insulation and dielectric phenomena

Thermopower in Thin-Film Copper—Constantan Couples

K. L. Chopra、S. K. Bahl、M. R. Randlett1968-02-15Journal of Applied Physics

The thickness dependence of the thermal emf of thin-film copper—constantan thermocouples at room temperature and above shows nearly bulklike behavior when the thickness of both elements comprising the thermocouple is greater than ∼1200 Å. The thermal response time of the thermocouples as measured with a pulsed laser b…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Temperature Dependence of Dispersed Barrier Hardening

Kanji Ono1968-02-15Journal of Applied Physics

This paper examines the temperature dependence predicted by theories of dispersed barrier hardening. Most of interaction potentials employed in the theories are similar. It is not possible to select one of several interaction potentials on the basis of an experimentally obtained stress-temperature relationship. This p…

Thermal properties of materialsBoron and Carbon Nanomaterials ResearchDiamond and Carbon-based Materials Research

Diffraction Pattern and Structure of Liquid Benzene

A. H. Narten1968-02-15The Journal of Chemical Physics

The scattering of x rays from the free surface of liquid benzene has been analyzed at 25°C. The diffractometer used was specially designed for the study of liquid structure. Intensity and radial distribution functions have been computed for a model structure and compared to those derived from experiment. The model ass…

Thermodynamic properties of mixturesChemical Thermodynamics and Molecular StructureMaterial Dynamics and Properties

Magnetic and Crystallographic Properties of Some Rare Earth Cobalt Compounds with CaZn5 Structure

W. A. J. J. Velge、K.H.J. Buschow1968-02-15Journal of Applied Physics

The magnetic and crystallographic properties of CaZn5-type intermetallic compounds of cobalt and rare-earth elements (including Th) have been investigated. Strong deviations from 1:5 stoichiometry are observed when the rare-earth radius becomes relatively small. Both the saturation magnetizations (4πIs=2360–12 300 G)…

Metallurgical and Alloy ProcessesRare-earth and actinide compoundsMagnetic Properties of Alloys