Materials Literature
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A theory of the electrode potential of nonstoichiometric electron conductive metal oxides on a foreign metal is presented. When the oxygen ions of the oxide are in equilibrium with the electrolyte the oxide electrode potential is p H with the free enthalpy for the reaction as a function of the degree of oxidation n. T…
The electrical resistivity of Na x WO 3, Li x WO 3, and K x WO 3 has been measured at 300° K. The range of x values was 0.25 < x < 0.9. All resistivities were characteristic of a metal and lie on a single curve. Extrapolation of the conductivity curve to zero conductivity indicated that the tungsten bronzes should be…
G. I. Harris, J. Chem. Soc., 1963, 5978 DOI: 10.1039/JR9630005978
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Abstract The products obtained by sublimation or radiation of trioxane byhigh energy radiations have been examined by X‐ray diffraction analysis. It have been possible to demonstrate that they consist of twinned crystals of hexagonal polyoxymethylene. By using rotating and WEISSENBERG photographs, the geometric correl…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMetal Complexation of the Tetracycline HydrochloridesJames T. Doluisio and Alfred N. MartinCite this: J. Med. Chem. 1963, 6, 1, 16–20Publication Date (Print):January 1, 1963Publication History Published online1 May 2002Published inissue 1 January 1963https://pubs.acs.org/doi…
The room-temperature reflectivity of single-crystal KTa${\mathrm{O}}_{3}$ has been measured from 5000 to 77 ${\mathrm{cm}}^{\ensuremath{-}1}$. These data have been analyzed by a Kramers-Kronig relation and by classical dispersion theory. The three infrared-active fundamental vibrations allowed by the lattice symmetry…
R. J. H. Clark, J. Chem. Soc., 1963, 1377 DOI: 10.1039/JR9630001377
Crosslinking, or polymerization, and cleavage are the chief radiation effects on organic compounds. In a study of lubricants, the stability of the base oil was the most important as pect of radiation resistance. Polyphenyl ethers and alkyl aromatics were the chief lubricants studied. The success of the organic cooland…
Abstract Analysis of thermogravimetric weight loss data from the literature indicated correlations between the overall energietics of decomposition and characteristics of the thermogravimetric curves for measurements made under nitrogen. Such correlations provide a means for comparing relative thermal stabilities of p…
Abstract The size of the crystallites in nylon 66, polytetrafluoroethylene, and polyethylene correlates with the degree of crystallinity. This supports the suggestion that the amorphous content of partially crystallized polymers can be attributed to chain folds and other regions directly related to the crystalline str…
Abstract Zwei der drei ultrarotaktiven Eigenfrequenzen von Titanaten können angenähert beschrieben werden als verursacht durch eine antisymmetrische Schwingung einer OTiO‐Kette und durch eine Schwingung des Erdalkaliatoms gegen acht seiner zwölf nächsten O‐Nachbarn. Aus den beobachteten Spektren werden folgende Kraf…
Abstract An investigation is made of the process by which the activator Mn is incorporated in CaS and SrS, by studying its dependence on activator concentration, flux addition and firing atmosphere. The dependence of the amount of Mn incorporated during the firing on that present before firing was investigated using a…
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Abstract The heterogeneous polymerization of acrylonitrile in tetrahydrofuran by chain transfer catalysts: monosodium anthracene, disodium anthracene, sodium naphthalene, monolithium anthracene, and lithium naphthalene was investigated. The free radical formed in the initiation was found to participate in the polymeri…
B. R. Phillips and D. Taylor, J. Chem. Soc., 1963, 5583 DOI: 10.1039/JR9630005583
The paper gives the mathematical formulation, and indicates the mathematical solution, of the problem of the dynamic behaviour of a transformer winding under axial short-circuit forces, certain basic physical assumptions being made initially. Various practical tapping arrangements are considered so that there may be e…
Following a previous report “Studies of the Glass-formation Range of Borate Systems” (This Journal, 69, 282 (1961)), we studied the glass-formation range of silicate systems. Although silicate glasses have long been used, sufficient systematic studies of the glassformation ranges of silicate systems have not yet been…
C. Aaron and C. C. Barker, J. Chem. Soc., 1963, 2655 DOI: 10.1039/JR9630002655
On a mesuré les sections efficaces de formation des isotopes 224, 225, 226, 227, 228 de l'actinium dans le thorium 232 bombardé par des protons de 30 à 120 MeV. Dans le domaine de basses énergies (30 à 80 MeV) la formation des Ac est attribuable aux processus (p, αxn) .