Materials Literature
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The thermal decomposition process of zirconium sulphate tetrahydrate has been studied. Dehydration, which takes place via a crystalline monohydrate phase, is accompanied by the loss of small amounts of sulphuric acid apparently resulting from internal hydrolysis of the compound. This process gives a non-stoicheiometri…
Abstract Aromatic polysulfonamides have been prepared by solution polycondensation of aromatic disulfonyl chlorides and aromatic diamines with a suitable acid acceptor in such solvents as N , N ‐dimethylacetamide and tetramethylenesulfone. The highest molecular weight polymers were obtained by using 2,6‐dimethylpyridi…
Internal stresses of dislocations interact in ferromagnetic crystals with the spontaneous magnetization through the magnetoelastic coupling energy. The magnetic free energy (MFE) of a straight dislocation line is calculated by means of Brown's micromagnetic equations. This energy corresponds to a magnetostrictive cont…
Stripe domains have been observed in Ni–Fe films having positive, zero, or negative magnetostriction and with either tensile or compressive stress. By using the model of Saito et al. and assuming their anisotropy constant K is attributed to both the shape anisotropy K0 and the magnetostrictively induced anisotropy Ks,…
Abstract Developments in the rubber reclaiming industry are closely related to those in the rubber industry in general. The vulcanized rubber produced by the latter becomes in time the raw material used by the former. Although not superficially obvious, there has been considerable change in the reclaiming industry in…
The feasibility of optical beam-operated magnetic storage systems is assessed. Recent advances in laser technology and in transparent magnetic materials are described along with methods for writing and reading information. In the writing process, thermomagnetic recording on thin films is considered and the writing spe…
Single crystals of Ni1−pZnpFe2O4 (p=0.20 and 0.65) were prepared from a melt in a PbO:B2O3 flux. The anisotropy constant K1 was deduced from torque measurements in a (100) plane. | K1 | increases linearly with p at low temperatures. Combining the results with data on p=0 and p=0.33 from the literature, one can represe…
The effect of composition on the first-order transformation from triangular into collinear antiferromagnetic structure (AF-AF transformation) occurring in ordered Mn3Pt has been investigated on ternary Mn3Pt1−xRhx and binary Mn3+yPt1−y alloys using x-ray and neutron-diffraction methods. On increasing the concentration…
The ion-binding capacity of highly purified reconstituted calf-skin collagen, and the effects of these ions on the precipitation and solubility of the collagen, were studied with a variety of salt solutions at ionic strength 0.16 and pH7.4. Only a small percentage of the total theoretically available anionic and catio…
In the hydrostatic theory of liquid crystals, we characterize those orientation patterns which may occur, in the absence of externally applied body forces, no matter what the form of the stored energy function may be. It turns out that there are three types of such patterns. In one, the orientation vector is perpendic…
Abstract A study was made of the influence of selected chain modifiers on both the molecular weight of grafted polyacrylonitrile and the grafting frequency of the starch–polyacrylo‐nitrile graft copolymer. Gelatinized wheat starch was used with ceric ammonium nitrate as the initiator. The organic chain modifiers inves…
In dc cables the resistivity of the insulation is a very important parameter, as it determines the stress distribution and the power losses in the insulation. This paper gives the results of several tests on plane capacitors, from which the steady-state resistivity of four different kinds of paper and impregnants appe…
Abstract Elastomer processing operations are discussed and classified as unit operations. The theory of nonlinear viscoelasticity is applied to processing unvulcanized amorphous rubber and the significance of the maximum relaxation time τ m is emphasized.
Pronounced temperature-dependent transfer of excitation from the Er3+ laser pump levels to lower levels of Er3+ was observed in CaF2:ErF3 single crystals at ErF3 concentrations exceeding 12.5 wt %. Transfer of excitation from Er3+ to Tm3+ occurred when TmF3 was included as a second active constituent of the crystals.…
The reactions of the OH radical with H 2 S and SH ⊖ are very fast (k = 1.1·10 10 and 5.4·10 9 mole -1 liter sec -1 , respectively). The hydrated electron reacts with H 2 S (1.1·10 10 ) but does not react with SH ⊖ . The rate constant of the reaction CNS+SH ⊖ CNS ⊖ +SH was found to be equal to 9.8·10 8 . Species absorb…
We have investigated the temperature-dependence of the magnetic moment of Cr3P, Mn3P, Fe3P and Ni3P including solid solutions of these compounds with each other. These measurements indicate Ni3P and Cr3P have a temperature-independent Pauli-type paramagnetism. Mn3P is antiferromagnetic (TN≈115°K) with a moment of 1.68…
Abstract The rhizospheric activity of coniferous and deciduous tree seedlings grown for a period of 13 months in sand cultures containing biotite (50 to 2µ) as the only source of K and Mg, effected the transformation of biotite to kaolinite. The identity of the kaolinite was established by means of X‐ray diffraction a…
The thermal conductivity of KH 2 PO 4 , KD 2 PO 4 and KH 2 AsO 4 single crystals was measured in the temperature range from 4.5 to 300°K. For all the samples critical changes of the thermal conductivity are found at the Curie temperatures. The conductivity decreases gradually with falling temperature in the paraelectr…
Abstract The infrared absorption spectra of selected crystalline and noncrystalline bands were studied in bulk‐crystallized specimens of linear polyethylene which encompassed the extremely wide density range of 0.92–0.99 g./cm. 3 . The analysis of the data obtained at room temperature yield degrees of crystallinity by…
SUMMARY Three distinct species of the genus Nitzschia, lacking chloroplasts and therefore obligately heterotrophic, were isolated in pure culture from various marine shores. The organisms reproduced rapidly in a defined medium based on an artificial sea water supplemented with mineral nutrients, thiamine and cobalamin…